125Te and 57Fe nuclear resonance vibrational spectroscopic characterization of intermediate spin state mixed-valent dimers

125Te and 57Fe nuclear resonance vibrational spectroscopic characterization of intermediate spin state mixed-valent dimers

Abstract Iron-sulfur clusters fulfill numerous roles throughout biology. The reduced [2Fe-2S]+ cluster offers unique electronic and magnetic properties due to its mixed-valent nature and can serve as an essential model for understanding electron transfer, electron delocalization, and accessible spin...

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Main Authors: Aleksa Radović, Justin T. Henthorn, Hongxin Wang, Deepak Prajapat, Ilya Sergeev, Nobumoto Nagasawa, Yoshitaka Yoda, Stephen P. Cramer, George E. Cutsail
Format: Article
Language:English
Published: Nature Portfolio 2025-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-62118-w
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