The Overlooked Role of Battery Cell Relaxation: How Reversible Effects Manipulate Accelerated Aging Characterization
Aging experiments are pivotal for car manufacturers to ensure the reliability of their battery cells. However, realistic aging methods are time-consuming and resource-intensive, necessitating accelerated aging techniques. While these techniques reduce testing time, they can also lead to distorted re...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-04-01
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| Series: | World Electric Vehicle Journal |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2032-6653/16/5/255 |
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| Summary: | Aging experiments are pivotal for car manufacturers to ensure the reliability of their battery cells. However, realistic aging methods are time-consuming and resource-intensive, necessitating accelerated aging techniques. While these techniques reduce testing time, they can also lead to distorted results due to the partially reversible nature of cell behavior, which stems from the inhomogenization and rehomogenization of conducting salt and lithium distribution in the electrode. To accurately capture these phenomena, cell relaxation must be incorporated into the test design. This work investigates the impact of the test procedure and several stress factors, namely depth of discharge and C- rate, on the formation and rehomogenization of cell inhomogeneities. The experimental results reveal increasing cell inhomogenization, leading to growing reversible capacity losses, particularly under conditions with shorter cycling interruptions (check ups and rest phases). These reversible capacity losses are associated with a significant reduction in cycle life performance of up to 400% under identical cycling conditions but shorter cycling interruptions. Similar trends are observed for increasing cycle depths and C-rates. Optimized recovery cycles effectively mitigate cell inhomogenization, doubling cycle stability without requiring considerable additional testing time. Furthermore, a clear correlation is found between increasing inhomogenization and cell failure, with lithium stripping confirming the occurrence of lithium plating shortly before failure. These findings emphasize the critical importance of considering cell relaxation in cycle aging studies to ensure reliable and accurate lifetime predictions. Under realistic conditions, substantially enhanced cycle stability is expected. |
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| ISSN: | 2032-6653 |