Influence of saline exposure and freeze-thaw effects on class C fly ash geopolymer mortars using the Taguchi method

This study investigates the durability performance of ambient-cured geopolymer mortars composed of Class C fly ash and silica fume when exposed to two aggressive conditions: freeze–thaw cycles and saline immersion. The Taguchi L₁₆ orthogonal array was employed to examine the effects of four key para...

Full description

Saved in:
Bibliographic Details
Main Author: Hasan Altawil
Format: Article
Language:English
Published: Elsevier 2025-09-01
Series:Results in Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590123025029007
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849225246678188032
author Hasan Altawil
author_facet Hasan Altawil
author_sort Hasan Altawil
collection DOAJ
description This study investigates the durability performance of ambient-cured geopolymer mortars composed of Class C fly ash and silica fume when exposed to two aggressive conditions: freeze–thaw cycles and saline immersion. The Taguchi L₁₆ orthogonal array was employed to examine the effects of four key parameters: sodium hydroxide (NaOH) molarity (10, 12, 14, and 16 M), alkaline activator-to-binder (AA/B) ratio (0.3, 0.35, 0.4, and 0.45), sodium silicate-to-sodium hydroxide (SS/SH) ratio (1.75, 2.0, 2.25, and 2.5), and water-to-geopolymer solids (W/GS) ratio (0.35, 0.45, 0.55, and 0.65). Durability was assessed based on compressive strength retention and mass loss. The results showed that the optimal mix under freeze–thaw cycles (10 M NaOH, W/GS = 0.35, SS/SH = 2.0, AA/B = 0.4) retained 96.39% of its initial strength, while the most resistant mix under saline conditions (10 M NaOH, W/GS = 0.35, SS/SH = 1.75, AA/B = 0.4) exhibited a 78.12% strength gain after NaCl exposure. ANOVA analysis confirmed that W/GS was the most influential factor under freeze–thaw conditions (52.11% contribution), while SS/SH was dominant under saline conditions (39.91%). The incorporation of silica fume improved pore refinement and overall durability in both scenarios. Although SEM/XRD analyses were not conducted, the study provides robust parametric insights into durability optimization using the Taguchi method. These findings support the use of ambient-cured geopolymer mortars as sustainable alternatives in cold and coastal environments.
format Article
id doaj-art-4ac2d440a5ab48c293d84ee9e84c6710
institution Kabale University
issn 2590-1230
language English
publishDate 2025-09-01
publisher Elsevier
record_format Article
series Results in Engineering
spelling doaj-art-4ac2d440a5ab48c293d84ee9e84c67102025-08-25T04:14:43ZengElsevierResults in Engineering2590-12302025-09-012710683610.1016/j.rineng.2025.106836Influence of saline exposure and freeze-thaw effects on class C fly ash geopolymer mortars using the Taguchi methodHasan Altawil0Department of Civil Engineering, Islamic University of Gaza, Rimal St, Gaza City, PalestineThis study investigates the durability performance of ambient-cured geopolymer mortars composed of Class C fly ash and silica fume when exposed to two aggressive conditions: freeze–thaw cycles and saline immersion. The Taguchi L₁₆ orthogonal array was employed to examine the effects of four key parameters: sodium hydroxide (NaOH) molarity (10, 12, 14, and 16 M), alkaline activator-to-binder (AA/B) ratio (0.3, 0.35, 0.4, and 0.45), sodium silicate-to-sodium hydroxide (SS/SH) ratio (1.75, 2.0, 2.25, and 2.5), and water-to-geopolymer solids (W/GS) ratio (0.35, 0.45, 0.55, and 0.65). Durability was assessed based on compressive strength retention and mass loss. The results showed that the optimal mix under freeze–thaw cycles (10 M NaOH, W/GS = 0.35, SS/SH = 2.0, AA/B = 0.4) retained 96.39% of its initial strength, while the most resistant mix under saline conditions (10 M NaOH, W/GS = 0.35, SS/SH = 1.75, AA/B = 0.4) exhibited a 78.12% strength gain after NaCl exposure. ANOVA analysis confirmed that W/GS was the most influential factor under freeze–thaw conditions (52.11% contribution), while SS/SH was dominant under saline conditions (39.91%). The incorporation of silica fume improved pore refinement and overall durability in both scenarios. Although SEM/XRD analyses were not conducted, the study provides robust parametric insights into durability optimization using the Taguchi method. These findings support the use of ambient-cured geopolymer mortars as sustainable alternatives in cold and coastal environments.http://www.sciencedirect.com/science/article/pii/S2590123025029007Geopolymer mortarClass C fly ashTaguchi methodFreeze–thaw resistanceSaline durability
spellingShingle Hasan Altawil
Influence of saline exposure and freeze-thaw effects on class C fly ash geopolymer mortars using the Taguchi method
Results in Engineering
Geopolymer mortar
Class C fly ash
Taguchi method
Freeze–thaw resistance
Saline durability
title Influence of saline exposure and freeze-thaw effects on class C fly ash geopolymer mortars using the Taguchi method
title_full Influence of saline exposure and freeze-thaw effects on class C fly ash geopolymer mortars using the Taguchi method
title_fullStr Influence of saline exposure and freeze-thaw effects on class C fly ash geopolymer mortars using the Taguchi method
title_full_unstemmed Influence of saline exposure and freeze-thaw effects on class C fly ash geopolymer mortars using the Taguchi method
title_short Influence of saline exposure and freeze-thaw effects on class C fly ash geopolymer mortars using the Taguchi method
title_sort influence of saline exposure and freeze thaw effects on class c fly ash geopolymer mortars using the taguchi method
topic Geopolymer mortar
Class C fly ash
Taguchi method
Freeze–thaw resistance
Saline durability
url http://www.sciencedirect.com/science/article/pii/S2590123025029007
work_keys_str_mv AT hasanaltawil influenceofsalineexposureandfreezethaweffectsonclasscflyashgeopolymermortarsusingthetaguchimethod