Unraveling Tissue‐Specific Fatty Acid Biosynthesis and Inter‐Tissue Crosstalk in Mice through Stable‐Isotope Tracing Metabolomics

Abstract Biosynthesis of free fatty acids (FFAs) in mammals is pivotal for metabolic homeostasis, yet a comprehensive understanding of tissue‐specific biosynthesis and inter‐tissue crosstalk of FFAs remains incomplete. In vivo stable‐isotope tracing metabolomics is utilized to comprehensively measur...

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Main Authors: Beizi Xing, Ruohong Wang, Tianzhang Kou, Wenbin Liu, Zheng‐Jiang Zhu
Format: Article
Language:English
Published: Wiley 2025-08-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202503662
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author Beizi Xing
Ruohong Wang
Tianzhang Kou
Wenbin Liu
Zheng‐Jiang Zhu
author_facet Beizi Xing
Ruohong Wang
Tianzhang Kou
Wenbin Liu
Zheng‐Jiang Zhu
author_sort Beizi Xing
collection DOAJ
description Abstract Biosynthesis of free fatty acids (FFAs) in mammals is pivotal for metabolic homeostasis, yet a comprehensive understanding of tissue‐specific biosynthesis and inter‐tissue crosstalk of FFAs remains incomplete. In vivo stable‐isotope tracing metabolomics is utilized to comprehensively measure FFA biosynthesis and inter‐tissue crosstalk in mice. Systematically assessing tissue‐specific biosynthesis of 13 FFAs across 15 tissues unveils dynamic spatial and temporal accumulation and redistribution of FFAs throughout the body. Employing an analytical framework to deconvolve mass isotopologue patterns, inter‐tissue crosstalk is explored for saturated, polyunsaturated, and monounsaturated FFAs, and quantify communications of FFA (16:0) and FFA (18:0) between the liver and other tissues. Then, a decline in fatty acid biosynthesis in peripheral tissues but not in the brain of aged mice is observed, particularly evident in palmitic acid and monounsaturated fatty acids. These findings illuminate the complex interplay between tissue‐specific fatty acid biosynthesis and the maintenance of metabolic homeostasis.
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spelling doaj-art-4a756a60e69f40cabee775ada2624f8c2025-08-23T14:14:06ZengWileyAdvanced Science2198-38442025-08-011231n/an/a10.1002/advs.202503662Unraveling Tissue‐Specific Fatty Acid Biosynthesis and Inter‐Tissue Crosstalk in Mice through Stable‐Isotope Tracing MetabolomicsBeizi Xing0Ruohong Wang1Tianzhang Kou2Wenbin Liu3Zheng‐Jiang Zhu4Interdisciplinary Research Center on Biology and Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 ChinaInterdisciplinary Research Center on Biology and Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 ChinaInterdisciplinary Research Center on Biology and Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 ChinaInterdisciplinary Research Center on Biology and Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 ChinaInterdisciplinary Research Center on Biology and Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 ChinaAbstract Biosynthesis of free fatty acids (FFAs) in mammals is pivotal for metabolic homeostasis, yet a comprehensive understanding of tissue‐specific biosynthesis and inter‐tissue crosstalk of FFAs remains incomplete. In vivo stable‐isotope tracing metabolomics is utilized to comprehensively measure FFA biosynthesis and inter‐tissue crosstalk in mice. Systematically assessing tissue‐specific biosynthesis of 13 FFAs across 15 tissues unveils dynamic spatial and temporal accumulation and redistribution of FFAs throughout the body. Employing an analytical framework to deconvolve mass isotopologue patterns, inter‐tissue crosstalk is explored for saturated, polyunsaturated, and monounsaturated FFAs, and quantify communications of FFA (16:0) and FFA (18:0) between the liver and other tissues. Then, a decline in fatty acid biosynthesis in peripheral tissues but not in the brain of aged mice is observed, particularly evident in palmitic acid and monounsaturated fatty acids. These findings illuminate the complex interplay between tissue‐specific fatty acid biosynthesis and the maintenance of metabolic homeostasis.https://doi.org/10.1002/advs.202503662fatty acid biosynthesisinter‐tissue crosstalkmass spectrometrymetabolomicsstable‐isotope tracing
spellingShingle Beizi Xing
Ruohong Wang
Tianzhang Kou
Wenbin Liu
Zheng‐Jiang Zhu
Unraveling Tissue‐Specific Fatty Acid Biosynthesis and Inter‐Tissue Crosstalk in Mice through Stable‐Isotope Tracing Metabolomics
Advanced Science
fatty acid biosynthesis
inter‐tissue crosstalk
mass spectrometry
metabolomics
stable‐isotope tracing
title Unraveling Tissue‐Specific Fatty Acid Biosynthesis and Inter‐Tissue Crosstalk in Mice through Stable‐Isotope Tracing Metabolomics
title_full Unraveling Tissue‐Specific Fatty Acid Biosynthesis and Inter‐Tissue Crosstalk in Mice through Stable‐Isotope Tracing Metabolomics
title_fullStr Unraveling Tissue‐Specific Fatty Acid Biosynthesis and Inter‐Tissue Crosstalk in Mice through Stable‐Isotope Tracing Metabolomics
title_full_unstemmed Unraveling Tissue‐Specific Fatty Acid Biosynthesis and Inter‐Tissue Crosstalk in Mice through Stable‐Isotope Tracing Metabolomics
title_short Unraveling Tissue‐Specific Fatty Acid Biosynthesis and Inter‐Tissue Crosstalk in Mice through Stable‐Isotope Tracing Metabolomics
title_sort unraveling tissue specific fatty acid biosynthesis and inter tissue crosstalk in mice through stable isotope tracing metabolomics
topic fatty acid biosynthesis
inter‐tissue crosstalk
mass spectrometry
metabolomics
stable‐isotope tracing
url https://doi.org/10.1002/advs.202503662
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