Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials

This paper reports the preparation of methacrylic acid-grafted nylon (MAA—nylon) by treating nylon-6,6 fibres with methacrylic acid (MAA) and the use of this modified polyamide as an ion-exchanger for the immobilization of pollutant basic dyes. The grafting of MAA onto nylon-6,6 was demonstrated bot...

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Main Authors: Mohamed Hassen V Baouab, Mohamed Khalfaoui, Aghleb Bartegi, Robert Gauthier
Format: Article
Language:English
Published: SAGE Publishing 2005-09-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361705775212439
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author Mohamed Hassen V Baouab
Mohamed Khalfaoui
Aghleb Bartegi
Robert Gauthier
author_facet Mohamed Hassen V Baouab
Mohamed Khalfaoui
Aghleb Bartegi
Robert Gauthier
author_sort Mohamed Hassen V Baouab
collection DOAJ
description This paper reports the preparation of methacrylic acid-grafted nylon (MAA—nylon) by treating nylon-6,6 fibres with methacrylic acid (MAA) and the use of this modified polyamide as an ion-exchanger for the immobilization of pollutant basic dyes. The grafting of MAA onto nylon-6,6 was demonstrated both by weight uptake and atomic force microscopy. The exchange capacity of MAA—nylon was evaluated by potentiometric titration of the acidic groups. Five MAA—nylon fibres with different degrees of grafting (20–80%) were tested for the adsorption of two basic dyes, viz. Basic Blue 3 and Basic Red 24. Such adsorption was monitored by visible spectroscopy. The adsorption capacity was found to depend on the degree of grafting and on the temperature. The experimental data were fitted using the Langmuir and Freundlich models. However, an improved fit could be obtained by using the Jossens model.
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institution Kabale University
issn 0263-6174
2048-4038
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publishDate 2005-09-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-4936c8a2de914eea9febb6d213606aff2025-01-02T22:38:06ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382005-09-012310.1260/026361705775212439Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger MaterialsMohamed Hassen V Baouab0Mohamed Khalfaoui1Aghleb Bartegi2Robert Gauthier3 Laboratoire de Biochimie et Environnement, Institut Supérieur de Biotechnologie, 5019 Monastir, Tunisia Laboratoire de Physique Quantique, Faculté des Sciences de Monastir, 5019 Monastir, Tunisia Laboratoire de Biochimie et Environnement, Institut Supérieur de Biotechnologie, 5019 Monastir, Tunisia Laboratoire des Matériaux Polymères et Biomatériaux, UMR CNRS No. 5627, UCB Lyon 1, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne-Cedex, FranceThis paper reports the preparation of methacrylic acid-grafted nylon (MAA—nylon) by treating nylon-6,6 fibres with methacrylic acid (MAA) and the use of this modified polyamide as an ion-exchanger for the immobilization of pollutant basic dyes. The grafting of MAA onto nylon-6,6 was demonstrated both by weight uptake and atomic force microscopy. The exchange capacity of MAA—nylon was evaluated by potentiometric titration of the acidic groups. Five MAA—nylon fibres with different degrees of grafting (20–80%) were tested for the adsorption of two basic dyes, viz. Basic Blue 3 and Basic Red 24. Such adsorption was monitored by visible spectroscopy. The adsorption capacity was found to depend on the degree of grafting and on the temperature. The experimental data were fitted using the Langmuir and Freundlich models. However, an improved fit could be obtained by using the Jossens model.https://doi.org/10.1260/026361705775212439
spellingShingle Mohamed Hassen V Baouab
Mohamed Khalfaoui
Aghleb Bartegi
Robert Gauthier
Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials
Adsorption Science & Technology
title Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials
title_full Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials
title_fullStr Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials
title_full_unstemmed Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials
title_short Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials
title_sort immobilization of residual basic dyes onto polyamide ion exchanger materials
url https://doi.org/10.1260/026361705775212439
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AT aghlebbartegi immobilizationofresidualbasicdyesontopolyamideionexchangermaterials
AT robertgauthier immobilizationofresidualbasicdyesontopolyamideionexchangermaterials