Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials
This paper reports the preparation of methacrylic acid-grafted nylon (MAA—nylon) by treating nylon-6,6 fibres with methacrylic acid (MAA) and the use of this modified polyamide as an ion-exchanger for the immobilization of pollutant basic dyes. The grafting of MAA onto nylon-6,6 was demonstrated bot...
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Format: | Article |
Language: | English |
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SAGE Publishing
2005-09-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/026361705775212439 |
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author | Mohamed Hassen V Baouab Mohamed Khalfaoui Aghleb Bartegi Robert Gauthier |
author_facet | Mohamed Hassen V Baouab Mohamed Khalfaoui Aghleb Bartegi Robert Gauthier |
author_sort | Mohamed Hassen V Baouab |
collection | DOAJ |
description | This paper reports the preparation of methacrylic acid-grafted nylon (MAA—nylon) by treating nylon-6,6 fibres with methacrylic acid (MAA) and the use of this modified polyamide as an ion-exchanger for the immobilization of pollutant basic dyes. The grafting of MAA onto nylon-6,6 was demonstrated both by weight uptake and atomic force microscopy. The exchange capacity of MAA—nylon was evaluated by potentiometric titration of the acidic groups. Five MAA—nylon fibres with different degrees of grafting (20–80%) were tested for the adsorption of two basic dyes, viz. Basic Blue 3 and Basic Red 24. Such adsorption was monitored by visible spectroscopy. The adsorption capacity was found to depend on the degree of grafting and on the temperature. The experimental data were fitted using the Langmuir and Freundlich models. However, an improved fit could be obtained by using the Jossens model. |
format | Article |
id | doaj-art-4936c8a2de914eea9febb6d213606aff |
institution | Kabale University |
issn | 0263-6174 2048-4038 |
language | English |
publishDate | 2005-09-01 |
publisher | SAGE Publishing |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj-art-4936c8a2de914eea9febb6d213606aff2025-01-02T22:38:06ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382005-09-012310.1260/026361705775212439Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger MaterialsMohamed Hassen V Baouab0Mohamed Khalfaoui1Aghleb Bartegi2Robert Gauthier3 Laboratoire de Biochimie et Environnement, Institut Supérieur de Biotechnologie, 5019 Monastir, Tunisia Laboratoire de Physique Quantique, Faculté des Sciences de Monastir, 5019 Monastir, Tunisia Laboratoire de Biochimie et Environnement, Institut Supérieur de Biotechnologie, 5019 Monastir, Tunisia Laboratoire des Matériaux Polymères et Biomatériaux, UMR CNRS No. 5627, UCB Lyon 1, 43 Boulevard du 11 Novembre 1918, 69622 Villeurbanne-Cedex, FranceThis paper reports the preparation of methacrylic acid-grafted nylon (MAA—nylon) by treating nylon-6,6 fibres with methacrylic acid (MAA) and the use of this modified polyamide as an ion-exchanger for the immobilization of pollutant basic dyes. The grafting of MAA onto nylon-6,6 was demonstrated both by weight uptake and atomic force microscopy. The exchange capacity of MAA—nylon was evaluated by potentiometric titration of the acidic groups. Five MAA—nylon fibres with different degrees of grafting (20–80%) were tested for the adsorption of two basic dyes, viz. Basic Blue 3 and Basic Red 24. Such adsorption was monitored by visible spectroscopy. The adsorption capacity was found to depend on the degree of grafting and on the temperature. The experimental data were fitted using the Langmuir and Freundlich models. However, an improved fit could be obtained by using the Jossens model.https://doi.org/10.1260/026361705775212439 |
spellingShingle | Mohamed Hassen V Baouab Mohamed Khalfaoui Aghleb Bartegi Robert Gauthier Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials Adsorption Science & Technology |
title | Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials |
title_full | Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials |
title_fullStr | Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials |
title_full_unstemmed | Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials |
title_short | Immobilization of Residual Basic Dyes onto Polyamide Ion-Exchanger Materials |
title_sort | immobilization of residual basic dyes onto polyamide ion exchanger materials |
url | https://doi.org/10.1260/026361705775212439 |
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