Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)]
A layered cobalt coordination polymer containing both 4-(2-carboxylatoethyl)benzoate (ceb) and 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligands, [Co(C10H8O4)(C16H20N4)(H2O)2]n or [Co(ceb)(3-bpmp)(H2O)2]n, was isolated and structurally characterized by single-crystal X-ray diffraction. Chain-like...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2024-12-01
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| Series: | IUCrData |
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| Online Access: | https://journals.iucr.org/paper?S2414314624012252 |
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| author | Frederick C. Ezenyilimba Robert L. LaDuca |
| author_facet | Frederick C. Ezenyilimba Robert L. LaDuca |
| author_sort | Frederick C. Ezenyilimba |
| collection | DOAJ |
| description | A layered cobalt coordination polymer containing both 4-(2-carboxylatoethyl)benzoate (ceb) and 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligands, [Co(C10H8O4)(C16H20N4)(H2O)2]n or [Co(ceb)(3-bpmp)(H2O)2]n, was isolated and structurally characterized by single-crystal X-ray diffraction. Chain-like [Co(ceb)(H2O)2]n units are oriented parallel to [101]. These are connected into (4,4)-grid coordination polymer layers by tethering 3-bpmp ligands. The layer motifs stack in an AAA pattern mediated by O—H...N hydrogen-bonding interactions between the aqua ligands in one layer and 3-bpmp piperazinyl N atoms in the abutting layer. |
| format | Article |
| id | doaj-art-479fa9cb0e514023a5b50e7be1b94fba |
| institution | Kabale University |
| issn | 2414-3146 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-479fa9cb0e514023a5b50e7be1b94fba2025-01-06T09:23:34ZengInternational Union of CrystallographyIUCrData2414-31462024-12-01912x24122510.1107/S2414314624012252pk4046Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)]Frederick C. Ezenyilimba0Robert L. LaDuca1E-35 Holmes Hall, Michigan State University, Lyman Briggs College, 919 E. Shaw Lane, East Lansing, MI 48825, USAE-35 Holmes Hall, Michigan State University, Lyman Briggs College, 919 E. Shaw Lane, East Lansing, MI 48825, USAA layered cobalt coordination polymer containing both 4-(2-carboxylatoethyl)benzoate (ceb) and 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligands, [Co(C10H8O4)(C16H20N4)(H2O)2]n or [Co(ceb)(3-bpmp)(H2O)2]n, was isolated and structurally characterized by single-crystal X-ray diffraction. Chain-like [Co(ceb)(H2O)2]n units are oriented parallel to [101]. These are connected into (4,4)-grid coordination polymer layers by tethering 3-bpmp ligands. The layer motifs stack in an AAA pattern mediated by O—H...N hydrogen-bonding interactions between the aqua ligands in one layer and 3-bpmp piperazinyl N atoms in the abutting layer.https://journals.iucr.org/paper?S2414314624012252crystal structurelayered coordination polymercobalt |
| spellingShingle | Frederick C. Ezenyilimba Robert L. LaDuca Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)] IUCrData crystal structure layered coordination polymer cobalt |
| title | Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)] |
| title_full | Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)] |
| title_fullStr | Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)] |
| title_full_unstemmed | Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)] |
| title_short | Poly[diaqua[μ2-1,4-bis(pyridin-3-ylmethyl)piperazine][μ2-4-(2-carboxylatoethyl)benzoato]cobalt(II)] |
| title_sort | poly diaqua μ2 1 4 bis pyridin 3 ylmethyl piperazine μ2 4 2 carboxylatoethyl benzoato cobalt ii |
| topic | crystal structure layered coordination polymer cobalt |
| url | https://journals.iucr.org/paper?S2414314624012252 |
| work_keys_str_mv | AT frederickcezenyilimba polydiaquam214bispyridin3ylmethylpiperazinem242carboxylatoethylbenzoatocobaltii AT robertlladuca polydiaquam214bispyridin3ylmethylpiperazinem242carboxylatoethylbenzoatocobaltii |