Analysis of Bio-Sorption of Cr(VI) onto Raw Rice Husk by a Hybrid Theoretical Model Using Results of Batch Experiments

In this study, batch adsorption experiments are conducted for removing Cr(VI) from its aqueous solution using raw rice husk after its characterization by scanning electron microscopy, BET and Fourier transform infrared spectroscopy analyses. The effects of different operating parameters are investig...

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Main Authors: Debasish Sarkar, Sudip K Das, Amitava Bandyopadhyay
Format: Article
Language:English
Published: SAGE Publishing 2013-08-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.31.8.747
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author Debasish Sarkar
Sudip K Das
Amitava Bandyopadhyay
author_facet Debasish Sarkar
Sudip K Das
Amitava Bandyopadhyay
author_sort Debasish Sarkar
collection DOAJ
description In this study, batch adsorption experiments are conducted for removing Cr(VI) from its aqueous solution using raw rice husk after its characterization by scanning electron microscopy, BET and Fourier transform infrared spectroscopy analyses. The effects of different operating parameters are investigated and optimized. The maximum percentage of removal observed was 99% under optimal operating conditions. Experimental results follow the Langmuir adsorption isotherm reasonably well. A hybrid mathematical model that takes into account the shrinking core approach coupled with the well-known progressive conversion model has been proposed to simulate the dynamic behaviour of the present system using the results obtained from the batch adsorption experiments. The proposed model can also be potentially applicable to any similar other solid–liquid adsorption–diffusion system. Based on the experimental findings and theoretical analyses carried out in this study, several recommendations are holistically put forward for developing the understanding of the adsorptive removal of heavy metals including Cr(VI) and other pollutants.
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institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2013-08-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-454b7a36187643d58ef3d9596ed219272025-01-02T22:37:33ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382013-08-013110.1260/0263-6174.31.8.747Analysis of Bio-Sorption of Cr(VI) onto Raw Rice Husk by a Hybrid Theoretical Model Using Results of Batch ExperimentsDebasish SarkarSudip K DasAmitava BandyopadhyayIn this study, batch adsorption experiments are conducted for removing Cr(VI) from its aqueous solution using raw rice husk after its characterization by scanning electron microscopy, BET and Fourier transform infrared spectroscopy analyses. The effects of different operating parameters are investigated and optimized. The maximum percentage of removal observed was 99% under optimal operating conditions. Experimental results follow the Langmuir adsorption isotherm reasonably well. A hybrid mathematical model that takes into account the shrinking core approach coupled with the well-known progressive conversion model has been proposed to simulate the dynamic behaviour of the present system using the results obtained from the batch adsorption experiments. The proposed model can also be potentially applicable to any similar other solid–liquid adsorption–diffusion system. Based on the experimental findings and theoretical analyses carried out in this study, several recommendations are holistically put forward for developing the understanding of the adsorptive removal of heavy metals including Cr(VI) and other pollutants.https://doi.org/10.1260/0263-6174.31.8.747
spellingShingle Debasish Sarkar
Sudip K Das
Amitava Bandyopadhyay
Analysis of Bio-Sorption of Cr(VI) onto Raw Rice Husk by a Hybrid Theoretical Model Using Results of Batch Experiments
Adsorption Science & Technology
title Analysis of Bio-Sorption of Cr(VI) onto Raw Rice Husk by a Hybrid Theoretical Model Using Results of Batch Experiments
title_full Analysis of Bio-Sorption of Cr(VI) onto Raw Rice Husk by a Hybrid Theoretical Model Using Results of Batch Experiments
title_fullStr Analysis of Bio-Sorption of Cr(VI) onto Raw Rice Husk by a Hybrid Theoretical Model Using Results of Batch Experiments
title_full_unstemmed Analysis of Bio-Sorption of Cr(VI) onto Raw Rice Husk by a Hybrid Theoretical Model Using Results of Batch Experiments
title_short Analysis of Bio-Sorption of Cr(VI) onto Raw Rice Husk by a Hybrid Theoretical Model Using Results of Batch Experiments
title_sort analysis of bio sorption of cr vi onto raw rice husk by a hybrid theoretical model using results of batch experiments
url https://doi.org/10.1260/0263-6174.31.8.747
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AT amitavabandyopadhyay analysisofbiosorptionofcrviontorawricehuskbyahybridtheoreticalmodelusingresultsofbatchexperiments