Structural features and properties of the Sn-Zn-Si-Al system alloys obtained by the method of rapid solidification from the melt

The article presents the results of studying the microstructure of rapidly solidified foil of Sn55,18Zn44,50Si0,23Al0,09 alloy. The phase composition of rapidly solidified foil was studied. A uniform distribution of alloying silicon and aluminum in tin in the form of a solid solution was established...

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Main Authors: D.A. Zernitsa, V.G. Shepelevich
Format: Article
Language:Russian
Published: Tver State University 2024-12-01
Series:Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
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Online Access:https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-110/?lang=en
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author D.A. Zernitsa
V.G. Shepelevich
author_facet D.A. Zernitsa
V.G. Shepelevich
author_sort D.A. Zernitsa
collection DOAJ
description The article presents the results of studying the microstructure of rapidly solidified foil of Sn55,18Zn44,50Si0,23Al0,09 alloy. The phase composition of rapidly solidified foil was studied. A uniform distribution of alloying silicon and aluminum in tin in the form of a solid solution was established. The formation of the (100) texture of tin and (1010) of zinc was revealed, associated with the predominant growth of crystallites, in which the close-packed planes of tin and zinc are perpendicular to the direction of heat removal during crystallization. An analysis of the structure and properties of the foil during isothermal annealing and natural aging was performed, with a description of the processes occurring. Formation of a dispersed structure due to high degree of supercooling of liquid phase with increase of degree of dispersion of zinc during isothermal annealing (average chord d on sections of zinc phases is 1,24 μm before heat treatment and 0,42 μm after isothermal annealing for 170 min at 150°C) along with invariance of texture during heat treatment is established. Change of the microhardness of foil during natural aging, noticeable formation of large number of clusters of precipitations of tin and zinc phases due to their supersaturation, as well as reinforcing action of alloying elements (Si, Al) are explained. During heat treatment zinc dissolves in the matrix phase, with decrease of its volume, while share of softening phase of tin increases which leads to a decrease in the microhardness.
format Article
id doaj-art-44f5e3a359324ca5adef6d26a26fe12a
institution Kabale University
issn 2226-4442
2658-4360
language Russian
publishDate 2024-12-01
publisher Tver State University
record_format Article
series Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
spelling doaj-art-44f5e3a359324ca5adef6d26a26fe12a2024-12-25T15:04:53ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602024-12-011611011810.26456/pcascnn/2024.16.110Structural features and properties of the Sn-Zn-Si-Al system alloys obtained by the method of rapid solidification from the meltD.A. Zernitsa0V.G. Shepelevich1Mozyr State Pedagogical University named after I.P. ShamyakinBelarusian State UniversityThe article presents the results of studying the microstructure of rapidly solidified foil of Sn55,18Zn44,50Si0,23Al0,09 alloy. The phase composition of rapidly solidified foil was studied. A uniform distribution of alloying silicon and aluminum in tin in the form of a solid solution was established. The formation of the (100) texture of tin and (1010) of zinc was revealed, associated with the predominant growth of crystallites, in which the close-packed planes of tin and zinc are perpendicular to the direction of heat removal during crystallization. An analysis of the structure and properties of the foil during isothermal annealing and natural aging was performed, with a description of the processes occurring. Formation of a dispersed structure due to high degree of supercooling of liquid phase with increase of degree of dispersion of zinc during isothermal annealing (average chord d on sections of zinc phases is 1,24 μm before heat treatment and 0,42 μm after isothermal annealing for 170 min at 150°C) along with invariance of texture during heat treatment is established. Change of the microhardness of foil during natural aging, noticeable formation of large number of clusters of precipitations of tin and zinc phases due to their supersaturation, as well as reinforcing action of alloying elements (Si, Al) are explained. During heat treatment zinc dissolves in the matrix phase, with decrease of its volume, while share of softening phase of tin increases which leads to a decrease in the microhardness. https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-110/?lang=enrapidly solidified structuresmulticomponent alloyzinctinsupersaturated solutionstructureisothermal annealingsiliconaluminum
spellingShingle D.A. Zernitsa
V.G. Shepelevich
Structural features and properties of the Sn-Zn-Si-Al system alloys obtained by the method of rapid solidification from the melt
Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
rapidly solidified structures
multicomponent alloy
zinc
tin
supersaturated solution
structure
isothermal annealing
silicon
aluminum
title Structural features and properties of the Sn-Zn-Si-Al system alloys obtained by the method of rapid solidification from the melt
title_full Structural features and properties of the Sn-Zn-Si-Al system alloys obtained by the method of rapid solidification from the melt
title_fullStr Structural features and properties of the Sn-Zn-Si-Al system alloys obtained by the method of rapid solidification from the melt
title_full_unstemmed Structural features and properties of the Sn-Zn-Si-Al system alloys obtained by the method of rapid solidification from the melt
title_short Structural features and properties of the Sn-Zn-Si-Al system alloys obtained by the method of rapid solidification from the melt
title_sort structural features and properties of the sn zn si al system alloys obtained by the method of rapid solidification from the melt
topic rapidly solidified structures
multicomponent alloy
zinc
tin
supersaturated solution
structure
isothermal annealing
silicon
aluminum
url https://physchemaspects.ru/2024/doi-10-26456-pcascnn-2024-16-110/?lang=en
work_keys_str_mv AT dazernitsa structuralfeaturesandpropertiesofthesnznsialsystemalloysobtainedbythemethodofrapidsolidificationfromthemelt
AT vgshepelevich structuralfeaturesandpropertiesofthesnznsialsystemalloysobtainedbythemethodofrapidsolidificationfromthemelt