Elucidating the Changes in Activated Carbon Pore Structure as a Result of -Butylbenzene Adsorption and its Desorption by Means of Supercritical Carbon Dioxide
Inverse gas chromatography was applied to characterize the changes in pore structure of activated carbon samples (commercial, de-ashed, and de-ashed and oxidized) before and after the adsorption of tert -butylbenzene, and after its desorption by means of supercritical carbon dioxide. The slit-like m...
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Language: | English |
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SAGE Publishing
2001-05-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/0263617011494196 |
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author | Henryk Grajek |
author_facet | Henryk Grajek |
author_sort | Henryk Grajek |
collection | DOAJ |
description | Inverse gas chromatography was applied to characterize the changes in pore structure of activated carbon samples (commercial, de-ashed, and de-ashed and oxidized) before and after the adsorption of tert -butylbenzene, and after its desorption by means of supercritical carbon dioxide. The slit-like micropore model was used for the description of the pore structure. It was shown that tert -butylbenzene was desorbed with greater difficulty from samples containing basic impurities. Changes in the amounts of surface groups (acidic and basic) during the desorption process were not significant. |
format | Article |
id | doaj-art-43d967e490d042a6a00c7d3b4cc5444e |
institution | Kabale University |
issn | 0263-6174 2048-4038 |
language | English |
publishDate | 2001-05-01 |
publisher | SAGE Publishing |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj-art-43d967e490d042a6a00c7d3b4cc5444e2025-01-03T01:20:01ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382001-05-011910.1260/0263617011494196Elucidating the Changes in Activated Carbon Pore Structure as a Result of -Butylbenzene Adsorption and its Desorption by Means of Supercritical Carbon DioxideHenryk GrajekInverse gas chromatography was applied to characterize the changes in pore structure of activated carbon samples (commercial, de-ashed, and de-ashed and oxidized) before and after the adsorption of tert -butylbenzene, and after its desorption by means of supercritical carbon dioxide. The slit-like micropore model was used for the description of the pore structure. It was shown that tert -butylbenzene was desorbed with greater difficulty from samples containing basic impurities. Changes in the amounts of surface groups (acidic and basic) during the desorption process were not significant.https://doi.org/10.1260/0263617011494196 |
spellingShingle | Henryk Grajek Elucidating the Changes in Activated Carbon Pore Structure as a Result of -Butylbenzene Adsorption and its Desorption by Means of Supercritical Carbon Dioxide Adsorption Science & Technology |
title | Elucidating the Changes in Activated Carbon Pore Structure as a Result of -Butylbenzene Adsorption and its Desorption by Means of Supercritical Carbon Dioxide |
title_full | Elucidating the Changes in Activated Carbon Pore Structure as a Result of -Butylbenzene Adsorption and its Desorption by Means of Supercritical Carbon Dioxide |
title_fullStr | Elucidating the Changes in Activated Carbon Pore Structure as a Result of -Butylbenzene Adsorption and its Desorption by Means of Supercritical Carbon Dioxide |
title_full_unstemmed | Elucidating the Changes in Activated Carbon Pore Structure as a Result of -Butylbenzene Adsorption and its Desorption by Means of Supercritical Carbon Dioxide |
title_short | Elucidating the Changes in Activated Carbon Pore Structure as a Result of -Butylbenzene Adsorption and its Desorption by Means of Supercritical Carbon Dioxide |
title_sort | elucidating the changes in activated carbon pore structure as a result of butylbenzene adsorption and its desorption by means of supercritical carbon dioxide |
url | https://doi.org/10.1260/0263617011494196 |
work_keys_str_mv | AT henrykgrajek elucidatingthechangesinactivatedcarbonporestructureasaresultofbutylbenzeneadsorptionanditsdesorptionbymeansofsupercriticalcarbondioxide |