Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of Alkynes
Herein, we report the first example of molybdenum-catalyzed (<i>E</i>)-Selective anti-Markovnikov hydrosilylation of alkynes. The reaction operates effectively with the utilization of minute amounts of the inexpensive, bench-stable pre-catalyst and ligand under mild conditions. Moreover,...
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-12-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/29/24/5952 |
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| author | Feihua Ye Zhaoyang Huang Jiahao Li Qiumin Wang Lihuan Wu Xiang Li |
| author_facet | Feihua Ye Zhaoyang Huang Jiahao Li Qiumin Wang Lihuan Wu Xiang Li |
| author_sort | Feihua Ye |
| collection | DOAJ |
| description | Herein, we report the first example of molybdenum-catalyzed (<i>E</i>)-Selective anti-Markovnikov hydrosilylation of alkynes. The reaction operates effectively with the utilization of minute amounts of the inexpensive, bench-stable pre-catalyst and ligand under mild conditions. Moreover, this molybdenum-catalyzed hydrosilylation process features the advantages of simple operation, excellent selectivity, and broad functional groups tolerance. |
| format | Article |
| id | doaj-art-4278da82713e4dba91f4c31425d62077 |
| institution | Kabale University |
| issn | 1420-3049 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-4278da82713e4dba91f4c31425d620772024-12-27T14:42:45ZengMDPI AGMolecules1420-30492024-12-012924595210.3390/molecules29245952Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of AlkynesFeihua Ye0Zhaoyang Huang1Jiahao Li2Qiumin Wang3Lihuan Wu4Xiang Li5School of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaHerein, we report the first example of molybdenum-catalyzed (<i>E</i>)-Selective anti-Markovnikov hydrosilylation of alkynes. The reaction operates effectively with the utilization of minute amounts of the inexpensive, bench-stable pre-catalyst and ligand under mild conditions. Moreover, this molybdenum-catalyzed hydrosilylation process features the advantages of simple operation, excellent selectivity, and broad functional groups tolerance.https://www.mdpi.com/1420-3049/29/24/5952(<i>E</i>)-vinysilaneshydrosilylationalkynesmolybdenum catalystsynthetic method |
| spellingShingle | Feihua Ye Zhaoyang Huang Jiahao Li Qiumin Wang Lihuan Wu Xiang Li Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of Alkynes Molecules (<i>E</i>)-vinysilanes hydrosilylation alkynes molybdenum catalyst synthetic method |
| title | Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of Alkynes |
| title_full | Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of Alkynes |
| title_fullStr | Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of Alkynes |
| title_full_unstemmed | Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of Alkynes |
| title_short | Molybdenum-Catalyzed (<i>E</i>)-Selective Anti-Markovnikov Hydrosilylation of Alkynes |
| title_sort | molybdenum catalyzed i e i selective anti markovnikov hydrosilylation of alkynes |
| topic | (<i>E</i>)-vinysilanes hydrosilylation alkynes molybdenum catalyst synthetic method |
| url | https://www.mdpi.com/1420-3049/29/24/5952 |
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