All-solid-state batteries designed for operation under extreme cold conditions
Abstract A pressing need for enhancing lithium-ion battery (LIB) performance exists, particularly in ensuring reliable operation under extreme cold conditions. All-solid-state batteries (ASSBs) offer a promising solution to the challenges posed by conventional LIBs with liquid electrolytes in low-te...
Saved in:
| Main Authors: | , , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-01-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-024-55154-5 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841559275532451840 |
|---|---|
| author | Bolong Hong Lei Gao Changping Li Genming Lai Jinlong Zhu Dubin Huang Yunxing Zuo Wen Yin Mengyu Sun Shusen Zhao Jiaxin Zheng Songbai Han Ruqiang Zou |
| author_facet | Bolong Hong Lei Gao Changping Li Genming Lai Jinlong Zhu Dubin Huang Yunxing Zuo Wen Yin Mengyu Sun Shusen Zhao Jiaxin Zheng Songbai Han Ruqiang Zou |
| author_sort | Bolong Hong |
| collection | DOAJ |
| description | Abstract A pressing need for enhancing lithium-ion battery (LIB) performance exists, particularly in ensuring reliable operation under extreme cold conditions. All-solid-state batteries (ASSBs) offer a promising solution to the challenges posed by conventional LIBs with liquid electrolytes in low-temperature environments. In this study, leveraging the benefits of amorphous solid-state electrolytes (SSEs) xLi3N-TaCl5 (1 ≤ 3x ≤ 2), we develop ASSBs capable of functioning effectively under extreme cold conditions. The designed ASSBs, employing LiCoO2 positive electrode with a mass loading of 4.46 mg cm‒2 and a Li-In negative electrode, demonstrate initial discharge capacities of 183.19, 164.8 and 143.78 mAh g‒1 under 18 mA g‒1 at ‒10, ‒30, and ‒40 °C, respectively, and exhibit a final discharge capacity of 137.6 mAh g‒1 at 18 mA g‒1 and ‒30 °C in the 100th cycle. Moreover, the ASSBs demonstrate an initial discharge capacity of 51.94 mAh g‒1 at 18 mA g‒1 and ‒60 °C with cycling over 200 h. |
| format | Article |
| id | doaj-art-3d183ed880b542e2858ef45ed4bdf7eb |
| institution | Kabale University |
| issn | 2041-1723 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj-art-3d183ed880b542e2858ef45ed4bdf7eb2025-01-05T12:38:25ZengNature PortfolioNature Communications2041-17232025-01-011611910.1038/s41467-024-55154-5All-solid-state batteries designed for operation under extreme cold conditionsBolong Hong0Lei Gao1Changping Li2Genming Lai3Jinlong Zhu4Dubin Huang5Yunxing Zuo6Wen Yin7Mengyu Sun8Shusen Zhao9Jiaxin Zheng10Songbai Han11Ruqiang Zou12Department of Physics, Southern University of Science and TechnologySchool of Advanced Materials, Peking University, Shenzhen Graduate SchoolResearch Center for Eco-Environmental Engineering, Dongguan University of TechnologySchool of Advanced Materials, Peking University, Shenzhen Graduate SchoolDepartment of Physics, Southern University of Science and TechnologyPeking University-Golden Feather Joint Advanced Battery CenterEACOMPInstitute of High Energy Physics, Chinese Academy of SciencesNational Center for Applied Mathematics Shenzhen (NCAMS)National Center for Applied Mathematics Shenzhen (NCAMS)School of Advanced Materials, Peking University, Shenzhen Graduate SchoolShenzhen Key Laboratory of Solid State Batteries, Southern University of Science and TechnologySchool of Advanced Materials, Peking University, Shenzhen Graduate SchoolAbstract A pressing need for enhancing lithium-ion battery (LIB) performance exists, particularly in ensuring reliable operation under extreme cold conditions. All-solid-state batteries (ASSBs) offer a promising solution to the challenges posed by conventional LIBs with liquid electrolytes in low-temperature environments. In this study, leveraging the benefits of amorphous solid-state electrolytes (SSEs) xLi3N-TaCl5 (1 ≤ 3x ≤ 2), we develop ASSBs capable of functioning effectively under extreme cold conditions. The designed ASSBs, employing LiCoO2 positive electrode with a mass loading of 4.46 mg cm‒2 and a Li-In negative electrode, demonstrate initial discharge capacities of 183.19, 164.8 and 143.78 mAh g‒1 under 18 mA g‒1 at ‒10, ‒30, and ‒40 °C, respectively, and exhibit a final discharge capacity of 137.6 mAh g‒1 at 18 mA g‒1 and ‒30 °C in the 100th cycle. Moreover, the ASSBs demonstrate an initial discharge capacity of 51.94 mAh g‒1 at 18 mA g‒1 and ‒60 °C with cycling over 200 h.https://doi.org/10.1038/s41467-024-55154-5 |
| spellingShingle | Bolong Hong Lei Gao Changping Li Genming Lai Jinlong Zhu Dubin Huang Yunxing Zuo Wen Yin Mengyu Sun Shusen Zhao Jiaxin Zheng Songbai Han Ruqiang Zou All-solid-state batteries designed for operation under extreme cold conditions Nature Communications |
| title | All-solid-state batteries designed for operation under extreme cold conditions |
| title_full | All-solid-state batteries designed for operation under extreme cold conditions |
| title_fullStr | All-solid-state batteries designed for operation under extreme cold conditions |
| title_full_unstemmed | All-solid-state batteries designed for operation under extreme cold conditions |
| title_short | All-solid-state batteries designed for operation under extreme cold conditions |
| title_sort | all solid state batteries designed for operation under extreme cold conditions |
| url | https://doi.org/10.1038/s41467-024-55154-5 |
| work_keys_str_mv | AT bolonghong allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT leigao allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT changpingli allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT genminglai allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT jinlongzhu allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT dubinhuang allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT yunxingzuo allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT wenyin allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT mengyusun allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT shusenzhao allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT jiaxinzheng allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT songbaihan allsolidstatebatteriesdesignedforoperationunderextremecoldconditions AT ruqiangzou allsolidstatebatteriesdesignedforoperationunderextremecoldconditions |