Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons

The adsorption of manganese(II) ions from aqueous solution onto three different granular activated carbons treated with ethylenediamine tetraacetic acid (EDTA) and its sodium salt was investigated. Characterization of the chelate-treated carbons showed that EDTA altered the physical and chemical pro...

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Main Authors: Ameena Y. Khan, David W. Mazyck
Format: Article
Language:English
Published: SAGE Publishing 2009-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361709789625289
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author Ameena Y. Khan
David W. Mazyck
author_facet Ameena Y. Khan
David W. Mazyck
author_sort Ameena Y. Khan
collection DOAJ
description The adsorption of manganese(II) ions from aqueous solution onto three different granular activated carbons treated with ethylenediamine tetraacetic acid (EDTA) and its sodium salt was investigated. Characterization of the chelate-treated carbons showed that EDTA altered the physical and chemical properties of the sorbents relative to their untreated counterparts. Furthermore, the modified sorbents exhibited a heightened capacity towards the adsorption of Mn(II) ions from aqueous media. Manganese(II) ion removal increased from 0 to 6.5 mg/g for the lignite coal-based sorbent, from 3.5 to 14.7 mg/g for the wood-based sorbent and from 1.3 to 7.9 mg/g for the bituminous coal-based sorbent. The increased removal is attributed, in part, to the creation of Lewis base sites that participate in covalent interactions and hydrolysis reactions.
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record_format Article
series Adsorption Science & Technology
spelling doaj-art-3b6d6daee8ba485fb40a1592788951952025-01-03T01:23:10ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382009-03-012710.1260/026361709789625289Adsorption of Manganese(II) Ions by EDTA-treated Activated CarbonsAmeena Y. Khan0David W. Mazyck1 Jones Edmunds and Associates, 730 NE Waldo Rd., Gainesville, FL 32641, U.S.A. Department of Environmental Engineering Sciences, University of Florida, 312 AP Black Hall, P.O. Box 116450, Gainesville, FL 32611, U.S.A.The adsorption of manganese(II) ions from aqueous solution onto three different granular activated carbons treated with ethylenediamine tetraacetic acid (EDTA) and its sodium salt was investigated. Characterization of the chelate-treated carbons showed that EDTA altered the physical and chemical properties of the sorbents relative to their untreated counterparts. Furthermore, the modified sorbents exhibited a heightened capacity towards the adsorption of Mn(II) ions from aqueous media. Manganese(II) ion removal increased from 0 to 6.5 mg/g for the lignite coal-based sorbent, from 3.5 to 14.7 mg/g for the wood-based sorbent and from 1.3 to 7.9 mg/g for the bituminous coal-based sorbent. The increased removal is attributed, in part, to the creation of Lewis base sites that participate in covalent interactions and hydrolysis reactions.https://doi.org/10.1260/026361709789625289
spellingShingle Ameena Y. Khan
David W. Mazyck
Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons
Adsorption Science & Technology
title Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons
title_full Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons
title_fullStr Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons
title_full_unstemmed Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons
title_short Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons
title_sort adsorption of manganese ii ions by edta treated activated carbons
url https://doi.org/10.1260/026361709789625289
work_keys_str_mv AT ameenaykhan adsorptionofmanganeseiiionsbyedtatreatedactivatedcarbons
AT davidwmazyck adsorptionofmanganeseiiionsbyedtatreatedactivatedcarbons