Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons
The adsorption of manganese(II) ions from aqueous solution onto three different granular activated carbons treated with ethylenediamine tetraacetic acid (EDTA) and its sodium salt was investigated. Characterization of the chelate-treated carbons showed that EDTA altered the physical and chemical pro...
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SAGE Publishing
2009-03-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/026361709789625289 |
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author | Ameena Y. Khan David W. Mazyck |
author_facet | Ameena Y. Khan David W. Mazyck |
author_sort | Ameena Y. Khan |
collection | DOAJ |
description | The adsorption of manganese(II) ions from aqueous solution onto three different granular activated carbons treated with ethylenediamine tetraacetic acid (EDTA) and its sodium salt was investigated. Characterization of the chelate-treated carbons showed that EDTA altered the physical and chemical properties of the sorbents relative to their untreated counterparts. Furthermore, the modified sorbents exhibited a heightened capacity towards the adsorption of Mn(II) ions from aqueous media. Manganese(II) ion removal increased from 0 to 6.5 mg/g for the lignite coal-based sorbent, from 3.5 to 14.7 mg/g for the wood-based sorbent and from 1.3 to 7.9 mg/g for the bituminous coal-based sorbent. The increased removal is attributed, in part, to the creation of Lewis base sites that participate in covalent interactions and hydrolysis reactions. |
format | Article |
id | doaj-art-3b6d6daee8ba485fb40a159278895195 |
institution | Kabale University |
issn | 0263-6174 2048-4038 |
language | English |
publishDate | 2009-03-01 |
publisher | SAGE Publishing |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj-art-3b6d6daee8ba485fb40a1592788951952025-01-03T01:23:10ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382009-03-012710.1260/026361709789625289Adsorption of Manganese(II) Ions by EDTA-treated Activated CarbonsAmeena Y. Khan0David W. Mazyck1 Jones Edmunds and Associates, 730 NE Waldo Rd., Gainesville, FL 32641, U.S.A. Department of Environmental Engineering Sciences, University of Florida, 312 AP Black Hall, P.O. Box 116450, Gainesville, FL 32611, U.S.A.The adsorption of manganese(II) ions from aqueous solution onto three different granular activated carbons treated with ethylenediamine tetraacetic acid (EDTA) and its sodium salt was investigated. Characterization of the chelate-treated carbons showed that EDTA altered the physical and chemical properties of the sorbents relative to their untreated counterparts. Furthermore, the modified sorbents exhibited a heightened capacity towards the adsorption of Mn(II) ions from aqueous media. Manganese(II) ion removal increased from 0 to 6.5 mg/g for the lignite coal-based sorbent, from 3.5 to 14.7 mg/g for the wood-based sorbent and from 1.3 to 7.9 mg/g for the bituminous coal-based sorbent. The increased removal is attributed, in part, to the creation of Lewis base sites that participate in covalent interactions and hydrolysis reactions.https://doi.org/10.1260/026361709789625289 |
spellingShingle | Ameena Y. Khan David W. Mazyck Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons Adsorption Science & Technology |
title | Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons |
title_full | Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons |
title_fullStr | Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons |
title_full_unstemmed | Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons |
title_short | Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons |
title_sort | adsorption of manganese ii ions by edta treated activated carbons |
url | https://doi.org/10.1260/026361709789625289 |
work_keys_str_mv | AT ameenaykhan adsorptionofmanganeseiiionsbyedtatreatedactivatedcarbons AT davidwmazyck adsorptionofmanganeseiiionsbyedtatreatedactivatedcarbons |