Spherical hard carbon/graphite anode for high performance lithium ion batteries.
The issue of long charging time for electric vehicles has been a matter of serious concern, and the problem is mainly stemmed from the graphite anode. The slow kinetics of pure graphite can lead to the formation of the lithium metal during fast charging, which triggers cycle degradation and safety i...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Public Library of Science (PLoS)
2024-01-01
|
| Series: | PLoS ONE |
| Online Access: | https://doi.org/10.1371/journal.pone.0311943 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841555447297867776 |
|---|---|
| author | Xingqun Liao Dalin Hu Lijuan Yu Bin Li Feng Xiao Shanxing Wang |
| author_facet | Xingqun Liao Dalin Hu Lijuan Yu Bin Li Feng Xiao Shanxing Wang |
| author_sort | Xingqun Liao |
| collection | DOAJ |
| description | The issue of long charging time for electric vehicles has been a matter of serious concern, and the problem is mainly stemmed from the graphite anode. The slow kinetics of pure graphite can lead to the formation of the lithium metal during fast charging, which triggers cycle degradation and safety issues of electric vehicles. In order to ameliorate the fast charging issue, a spherical hard carbon/graphite porous electrode is devised. Based on this, the discharge capacity ratio at 3C shows an improvement of about 40% at 25°C and at 1C shows an improvement of about 18% at 0°C. Additionally, the 300-cycle capacity retentions exhibit increases of 12% and 14% at temperature of 25°C and 50°C, respectively. Generally, the analysis shows that the spherical hard carbon/graphite porous electrode has more uniform porous structure, shorter transport path, less nano-scale powder and a certain voltage buffer ability compared to the pure graphite powder system, which enhance the ion transport kinetics, and reduce the side reactions under the high temperature, so as to effectively improve the fast charging performance and cycle life of the LIBs. It is also proved that the kinetics improvement is not only attributed to the high kinetics inherited from the instinct of hard carbon, but also the porous electrode structures constructed by the two-size powder system of graphite and hard carbon. |
| format | Article |
| id | doaj-art-3ad69c7c82b343d7a74430214ea8b4ff |
| institution | Kabale University |
| issn | 1932-6203 |
| language | English |
| publishDate | 2024-01-01 |
| publisher | Public Library of Science (PLoS) |
| record_format | Article |
| series | PLoS ONE |
| spelling | doaj-art-3ad69c7c82b343d7a74430214ea8b4ff2025-01-08T05:32:56ZengPublic Library of Science (PLoS)PLoS ONE1932-62032024-01-011912e031194310.1371/journal.pone.0311943Spherical hard carbon/graphite anode for high performance lithium ion batteries.Xingqun LiaoDalin HuLijuan YuBin LiFeng XiaoShanxing WangThe issue of long charging time for electric vehicles has been a matter of serious concern, and the problem is mainly stemmed from the graphite anode. The slow kinetics of pure graphite can lead to the formation of the lithium metal during fast charging, which triggers cycle degradation and safety issues of electric vehicles. In order to ameliorate the fast charging issue, a spherical hard carbon/graphite porous electrode is devised. Based on this, the discharge capacity ratio at 3C shows an improvement of about 40% at 25°C and at 1C shows an improvement of about 18% at 0°C. Additionally, the 300-cycle capacity retentions exhibit increases of 12% and 14% at temperature of 25°C and 50°C, respectively. Generally, the analysis shows that the spherical hard carbon/graphite porous electrode has more uniform porous structure, shorter transport path, less nano-scale powder and a certain voltage buffer ability compared to the pure graphite powder system, which enhance the ion transport kinetics, and reduce the side reactions under the high temperature, so as to effectively improve the fast charging performance and cycle life of the LIBs. It is also proved that the kinetics improvement is not only attributed to the high kinetics inherited from the instinct of hard carbon, but also the porous electrode structures constructed by the two-size powder system of graphite and hard carbon.https://doi.org/10.1371/journal.pone.0311943 |
| spellingShingle | Xingqun Liao Dalin Hu Lijuan Yu Bin Li Feng Xiao Shanxing Wang Spherical hard carbon/graphite anode for high performance lithium ion batteries. PLoS ONE |
| title | Spherical hard carbon/graphite anode for high performance lithium ion batteries. |
| title_full | Spherical hard carbon/graphite anode for high performance lithium ion batteries. |
| title_fullStr | Spherical hard carbon/graphite anode for high performance lithium ion batteries. |
| title_full_unstemmed | Spherical hard carbon/graphite anode for high performance lithium ion batteries. |
| title_short | Spherical hard carbon/graphite anode for high performance lithium ion batteries. |
| title_sort | spherical hard carbon graphite anode for high performance lithium ion batteries |
| url | https://doi.org/10.1371/journal.pone.0311943 |
| work_keys_str_mv | AT xingqunliao sphericalhardcarbongraphiteanodeforhighperformancelithiumionbatteries AT dalinhu sphericalhardcarbongraphiteanodeforhighperformancelithiumionbatteries AT lijuanyu sphericalhardcarbongraphiteanodeforhighperformancelithiumionbatteries AT binli sphericalhardcarbongraphiteanodeforhighperformancelithiumionbatteries AT fengxiao sphericalhardcarbongraphiteanodeforhighperformancelithiumionbatteries AT shanxingwang sphericalhardcarbongraphiteanodeforhighperformancelithiumionbatteries |