Tris(2,2'-bipyridine-4,4'-dicarboxylic acid)ruthenium(II), a Redox Sensitizer Affording Water Oxidation to Oxygen in the Absence of Heterogeneous Catalyst
Oxygen is generated under visible light illumination of highly acidic (0.5 M H2SO4) aqueous solutions of tris(2,2-bipyridine-4,4'-dicarboxylic acid)ruthenium(II) containing S2O82⊖ as electron acceptor in the absence of heterogeneous redox catalyst. An autocatalytic reaction mechanism is propos...
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| Main Authors: | Jean Desilvestro, Dung Duonghong, Mieke Kleijn, Michael Grätzel |
|---|---|
| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1985-04-01
|
| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9657 |
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