Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal salts
The growing and relatively large market share of 1,2-pentanediol (1,2-PeD) has attracted attention of researchers to find effective and economically viable catalysts. One type of catalyst that can be used for synthesizing this compound is transition-metal-based catalysts, employed in the hydrogenoly...
Saved in:
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Komunitas Ilmuwan dan Profesional Muslim Indonesia
2024-12-01
|
| Series: | Communications in Science and Technology |
| Subjects: | |
| Online Access: | https://cst.kipmi.or.id/journal/article/view/1549 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841560548433461248 |
|---|---|
| author | Muhammad Rafi Pratama Istifhamy Irnanda Hendra Julius Situmorang Yessi Permana Siti Hartinah Qurbayni Husni Wahyu Wijaya Ubed Sonai Fahruddin Arrozi |
| author_facet | Muhammad Rafi Pratama Istifhamy Irnanda Hendra Julius Situmorang Yessi Permana Siti Hartinah Qurbayni Husni Wahyu Wijaya Ubed Sonai Fahruddin Arrozi |
| author_sort | Muhammad Rafi Pratama |
| collection | DOAJ |
| description | The growing and relatively large market share of 1,2-pentanediol (1,2-PeD) has attracted attention of researchers to find effective and economically viable catalysts. One type of catalyst that can be used for synthesizing this compound is transition-metal-based catalysts, employed in the hydrogenolysis of furfuryl alcohol (FOL). In this study, the hydrogenolysis of furfuryl alcohol were performed with 2-propanol as the hydrogen source and transition metal salts as the catalysts. The used catalysts include first-row early and late transition metals, i.e., ZrOCl2·8H2O, VOSO4·H2O, FeSO4·7H2O, CuSO4·5H2O, NiCl2, Al(NO3)3·H2O, CoCl2, FeCl3·6H2O, and Zn(NO3)2·6H2O. It was found that ZrOCl2·8H2O, VOSO4·H2O, and FeCl3·6H2O demonstrated superior catalytic activity compared to the other catalysts. Optimal reaction conditions for these three catalysts were achieved at 150 °C for 1 hour, using 2-propanol as the hydrogen source. Under these reaction conditions, the ZrOCl?·8H?O catalyst achieved 95.5% conversion of FOL and 30.3% yield of 1,2-PeD, while the VOSO?·H?O catalyst attained 80.5% conversion of FOL and 36.9% yield of 1,2-PeD. Both results were obtained with a low catalyst concentration of 0.6 mmol%. Meanwhile, the FeCl3·6H2O catalyst converted 94.9% of FOL and yielded 30.9% of 1,2-PeD, using a lower catalyst concentration of 0.4 mmol%. Kinetic studies suggested that the reactions likely follow pseudo-first-order kinetics with experimental activation energies (Ea) of 65 kJ/mol, 55 kJ/mol, and 37 kJ/mol for ZrOCl?·8H?O, VOSO?·H?O, and FeCl?·6H?O catalysts, respectively. These findings highlight the potential of transition-metal-based catalysts in achieving high efficiency with low loading, emphasizing their suitability for industrial applications. |
| format | Article |
| id | doaj-art-3a788afe341246d9a4a190795ed0586e |
| institution | Kabale University |
| issn | 2502-9258 2502-9266 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Komunitas Ilmuwan dan Profesional Muslim Indonesia |
| record_format | Article |
| series | Communications in Science and Technology |
| spelling | doaj-art-3a788afe341246d9a4a190795ed0586e2025-01-04T01:17:06ZengKomunitas Ilmuwan dan Profesional Muslim IndonesiaCommunications in Science and Technology2502-92582502-92662024-12-019242142910.21924/cst.9.2.2024.15491549Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal saltsMuhammad Rafi Pratama0Istifhamy Irnanda1Hendra Julius Situmorang2Yessi Permana3Siti Hartinah Qurbayni4Husni Wahyu Wijaya5Ubed Sonai Fahruddin Arrozi6Department of Chemistry, State University of Malang, Malang 65145, IndonesiaDepartment of Chemistry, State University of Malang, Malang 65145, IndonesiaDepartment of Chemistry, State University of Malang, Malang 65145, IndonesiaInorganic and Physical Chemistry Research Division, Institut Teknologi Bandung, Bandung 40132, IndonesiaInorganic and Physical Chemistry Research Division, Institut Teknologi Bandung, Bandung 40132, IndonesiaDepartment of Chemistry, State University of Malang, Malang 65145, Indonesia; Centre of Advanced Material for Renewable Energy, Universitas Negeri Malang, Malang 65145, IndonesiaDepartment of Chemistry, State University of Malang, Malang 65145, IndonesiaThe growing and relatively large market share of 1,2-pentanediol (1,2-PeD) has attracted attention of researchers to find effective and economically viable catalysts. One type of catalyst that can be used for synthesizing this compound is transition-metal-based catalysts, employed in the hydrogenolysis of furfuryl alcohol (FOL). In this study, the hydrogenolysis of furfuryl alcohol were performed with 2-propanol as the hydrogen source and transition metal salts as the catalysts. The used catalysts include first-row early and late transition metals, i.e., ZrOCl2·8H2O, VOSO4·H2O, FeSO4·7H2O, CuSO4·5H2O, NiCl2, Al(NO3)3·H2O, CoCl2, FeCl3·6H2O, and Zn(NO3)2·6H2O. It was found that ZrOCl2·8H2O, VOSO4·H2O, and FeCl3·6H2O demonstrated superior catalytic activity compared to the other catalysts. Optimal reaction conditions for these three catalysts were achieved at 150 °C for 1 hour, using 2-propanol as the hydrogen source. Under these reaction conditions, the ZrOCl?·8H?O catalyst achieved 95.5% conversion of FOL and 30.3% yield of 1,2-PeD, while the VOSO?·H?O catalyst attained 80.5% conversion of FOL and 36.9% yield of 1,2-PeD. Both results were obtained with a low catalyst concentration of 0.6 mmol%. Meanwhile, the FeCl3·6H2O catalyst converted 94.9% of FOL and yielded 30.9% of 1,2-PeD, using a lower catalyst concentration of 0.4 mmol%. Kinetic studies suggested that the reactions likely follow pseudo-first-order kinetics with experimental activation energies (Ea) of 65 kJ/mol, 55 kJ/mol, and 37 kJ/mol for ZrOCl?·8H?O, VOSO?·H?O, and FeCl?·6H?O catalysts, respectively. These findings highlight the potential of transition-metal-based catalysts in achieving high efficiency with low loading, emphasizing their suitability for industrial applications.https://cst.kipmi.or.id/journal/article/view/1549zrocl\(_2\).8h\(_2\)ovoso\(_4\).h\(_2\)ofecl\(_3\).6h\(_2\)o1,2-pentanadiol, hydrogenolysisfurfuryl alcohol |
| spellingShingle | Muhammad Rafi Pratama Istifhamy Irnanda Hendra Julius Situmorang Yessi Permana Siti Hartinah Qurbayni Husni Wahyu Wijaya Ubed Sonai Fahruddin Arrozi Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal salts Communications in Science and Technology zrocl\(_2\).8h\(_2\)o voso\(_4\).h\(_2\)o fecl\(_3\).6h\(_2\)o 1,2-pentanadiol, hydrogenolysis furfuryl alcohol |
| title | Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal salts |
| title_full | Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal salts |
| title_fullStr | Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal salts |
| title_full_unstemmed | Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal salts |
| title_short | Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol catalyzed by first row transition metal salts |
| title_sort | hydrogenolysis of furfuryl alcohol to 1 2 pentanediol catalyzed by first row transition metal salts |
| topic | zrocl\(_2\).8h\(_2\)o voso\(_4\).h\(_2\)o fecl\(_3\).6h\(_2\)o 1,2-pentanadiol, hydrogenolysis furfuryl alcohol |
| url | https://cst.kipmi.or.id/journal/article/view/1549 |
| work_keys_str_mv | AT muhammadrafipratama hydrogenolysisoffurfurylalcoholto12pentanediolcatalyzedbyfirstrowtransitionmetalsalts AT istifhamyirnanda hydrogenolysisoffurfurylalcoholto12pentanediolcatalyzedbyfirstrowtransitionmetalsalts AT hendrajuliussitumorang hydrogenolysisoffurfurylalcoholto12pentanediolcatalyzedbyfirstrowtransitionmetalsalts AT yessipermana hydrogenolysisoffurfurylalcoholto12pentanediolcatalyzedbyfirstrowtransitionmetalsalts AT sitihartinahqurbayni hydrogenolysisoffurfurylalcoholto12pentanediolcatalyzedbyfirstrowtransitionmetalsalts AT husniwahyuwijaya hydrogenolysisoffurfurylalcoholto12pentanediolcatalyzedbyfirstrowtransitionmetalsalts AT ubedsonaifahruddinarrozi hydrogenolysisoffurfurylalcoholto12pentanediolcatalyzedbyfirstrowtransitionmetalsalts |