The Jäntti Approach to Adsorption with Increasing Gas Pressure
Jäntti introduced a method of calculating equilibrium adsorption from measurements where the pressure of the gas was varied in a stepwise manner. His aim was to shorten the time necessary for a given measurement. The method was applied to gas/solid systems in which simple adsorption processes occurr...
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SAGE Publishing
2002-12-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/026361702321705230 |
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author | Johannes A. Poulis Carel H. Massen Erich Robens |
author_facet | Johannes A. Poulis Carel H. Massen Erich Robens |
author_sort | Johannes A. Poulis |
collection | DOAJ |
description | Jäntti introduced a method of calculating equilibrium adsorption from measurements where the pressure of the gas was varied in a stepwise manner. His aim was to shorten the time necessary for a given measurement. The method was applied to gas/solid systems in which simple adsorption processes occurred and where the number of adsorption sites was infinite. The present paper discusses the case where no adsorption is possible on an already occupied site (Langmuir isotherm) while the number of positions available for adsorption is considered limited. The advantages of using a gas pressure that increases linearly with time are evident for studies with this limitation. It is shown that such measurements can also be speeded up using Jäntti's method. |
format | Article |
id | doaj-art-30d117390d7b499e82db472e5deb0878 |
institution | Kabale University |
issn | 0263-6174 2048-4038 |
language | English |
publishDate | 2002-12-01 |
publisher | SAGE Publishing |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj-art-30d117390d7b499e82db472e5deb08782025-01-02T23:11:46ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382002-12-012010.1260/026361702321705230The Jäntti Approach to Adsorption with Increasing Gas PressureJohannes A. Poulis0Carel H. Massen1Erich Robens2 Faculty of Technical Physics, Technical University Eindhoven, Postbus 513, NL-5600 MB Eindhoven, The Netherlands Faculty of Technical Physics, Technical University Eindhoven, Postbus 513, NL-5600 MB Eindhoven, The Netherlands Institut für Anorganische Chemie der Johannes Gutenberg-Universität, Duesbergweg 10-14, D-55099 Mainz, GermanyJäntti introduced a method of calculating equilibrium adsorption from measurements where the pressure of the gas was varied in a stepwise manner. His aim was to shorten the time necessary for a given measurement. The method was applied to gas/solid systems in which simple adsorption processes occurred and where the number of adsorption sites was infinite. The present paper discusses the case where no adsorption is possible on an already occupied site (Langmuir isotherm) while the number of positions available for adsorption is considered limited. The advantages of using a gas pressure that increases linearly with time are evident for studies with this limitation. It is shown that such measurements can also be speeded up using Jäntti's method.https://doi.org/10.1260/026361702321705230 |
spellingShingle | Johannes A. Poulis Carel H. Massen Erich Robens The Jäntti Approach to Adsorption with Increasing Gas Pressure Adsorption Science & Technology |
title | The Jäntti Approach to Adsorption with Increasing Gas Pressure |
title_full | The Jäntti Approach to Adsorption with Increasing Gas Pressure |
title_fullStr | The Jäntti Approach to Adsorption with Increasing Gas Pressure |
title_full_unstemmed | The Jäntti Approach to Adsorption with Increasing Gas Pressure |
title_short | The Jäntti Approach to Adsorption with Increasing Gas Pressure |
title_sort | jantti approach to adsorption with increasing gas pressure |
url | https://doi.org/10.1260/026361702321705230 |
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