Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale Study
The CO2 mineralization pathway is considered a promising option for carbon capture usage and storage because the captured CO2 can be permanently stored, and secondly industrial waste (i.e., petrochemical refinery, lime, and cement kiln dust) can be recycled into value-added carbonate materials by co...
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Department of Chemistry, Universitas Gadjah Mada
2024-12-01
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| Series: | Indonesian Journal of Chemistry |
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| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/92169 |
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| author | Ellyta Sari Reni Desmiarti Zulhadjri Zulhadjri Matlal Fajri Alif Maulana Yusup Rosadi Syukri Arief |
| author_facet | Ellyta Sari Reni Desmiarti Zulhadjri Zulhadjri Matlal Fajri Alif Maulana Yusup Rosadi Syukri Arief |
| author_sort | Ellyta Sari |
| collection | DOAJ |
| description | The CO2 mineralization pathway is considered a promising option for carbon capture usage and storage because the captured CO2 can be permanently stored, and secondly industrial waste (i.e., petrochemical refinery, lime, and cement kiln dust) can be recycled into value-added carbonate materials by controlling the crystal polymorphs and properties of mineral carbonate. This study investigated the CO2 mineralization utilized for the synthesis of precipitated calcium carbonate (PCC) via low temperatures at 30 °C and 55 °C with the addition of 50 and 75 g/L of ammonium chloride (NH4Cl). The pilot scale of PCC production was established to simultaneously produce PCC with low energy demand by reporting the feasibility of economic analysis and to develop the mineral carbonation that can transform limestones and CO2, which was captured from the petrochemical refinery process into economically valuable PCC. It is found that the aragonite phase of PCC can be generated at a room temperature of 30 °C by adjusting the CO2 flow rate. In addition, the use of NH4Cl, which transformed into ammonium carbonate ((NH4)2CO3) during the calcination process, can maintain the stable aragonite phase by varying the NH4Cl concentration. |
| format | Article |
| id | doaj-art-2ffb66f98eae4e9bb8ecbf0b2f56d700 |
| institution | Kabale University |
| issn | 1411-9420 2460-1578 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj-art-2ffb66f98eae4e9bb8ecbf0b2f56d7002024-12-02T08:18:18ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782024-12-012461650166010.22146/ijc.9216936425Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale StudyEllyta Sari0Reni Desmiarti1Zulhadjri Zulhadjri2Matlal Fajri Alif3Maulana Yusup Rosadi4Syukri Arief5Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Bung Hatta, Jl. Gajah Mada No. 19, Padang 25173, IndonesiaDepartment of Chemical Engineering, Faculty of Industrial Technology, Universitas Bung Hatta, Jl. Gajah Mada No. 19, Padang 25173, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Limau Manis Campus, Padang 25163, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Limau Manis Campus, Padang 25163, IndonesiaDepartment of Civil Engineering, Faculty of Engineering, Universitas Borobudur, Jl. Kali Malang No. 1, Jakarta 13620, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Limau Manis Campus, Padang 25163, IndonesiaThe CO2 mineralization pathway is considered a promising option for carbon capture usage and storage because the captured CO2 can be permanently stored, and secondly industrial waste (i.e., petrochemical refinery, lime, and cement kiln dust) can be recycled into value-added carbonate materials by controlling the crystal polymorphs and properties of mineral carbonate. This study investigated the CO2 mineralization utilized for the synthesis of precipitated calcium carbonate (PCC) via low temperatures at 30 °C and 55 °C with the addition of 50 and 75 g/L of ammonium chloride (NH4Cl). The pilot scale of PCC production was established to simultaneously produce PCC with low energy demand by reporting the feasibility of economic analysis and to develop the mineral carbonation that can transform limestones and CO2, which was captured from the petrochemical refinery process into economically valuable PCC. It is found that the aragonite phase of PCC can be generated at a room temperature of 30 °C by adjusting the CO2 flow rate. In addition, the use of NH4Cl, which transformed into ammonium carbonate ((NH4)2CO3) during the calcination process, can maintain the stable aragonite phase by varying the NH4Cl concentration.https://jurnal.ugm.ac.id/ijc/article/view/92169aragonitecarbon captureco2 mineralizationprecipitated calcium carbonate |
| spellingShingle | Ellyta Sari Reni Desmiarti Zulhadjri Zulhadjri Matlal Fajri Alif Maulana Yusup Rosadi Syukri Arief Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale Study Indonesian Journal of Chemistry aragonite carbon capture co2 mineralization precipitated calcium carbonate |
| title | Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale Study |
| title_full | Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale Study |
| title_fullStr | Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale Study |
| title_full_unstemmed | Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale Study |
| title_short | Synthesis of Aragonite from Precipitated Calcium Carbonate: A Pilot Scale Study |
| title_sort | synthesis of aragonite from precipitated calcium carbonate a pilot scale study |
| topic | aragonite carbon capture co2 mineralization precipitated calcium carbonate |
| url | https://jurnal.ugm.ac.id/ijc/article/view/92169 |
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