Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium salt

The effect of lithium perchlorate (LiClO4) on the transport and thermal properties of the ternary system consisting of N-methyl-N-propylpiperidinium perchlorate, highly dispersed γ-aluminum oxide (having the specific surface area of 200 m2 /g), and lithium perchlorate was investigated. It...

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Main Authors: Kyzlasova, Daria A., Ulihin, Artem S., Uvarov, Nikolai F.
Format: Article
Language:English
Published: Saratov State University 2024-12-01
Series:Электрохимическая энергетика
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Online Access:https://energetica.sgu.ru/sites/energetica.sgu.ru/files/text-pdf/2024/12/electro202404_4-216-220.pdf
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author Kyzlasova, Daria A.
Ulihin, Artem S.
Uvarov, Nikolai F.
author_facet Kyzlasova, Daria A.
Ulihin, Artem S.
Uvarov, Nikolai F.
author_sort Kyzlasova, Daria A.
collection DOAJ
description The effect of lithium perchlorate (LiClO4) on the transport and thermal properties of the ternary system consisting of N-methyl-N-propylpiperidinium perchlorate, highly dispersed γ-aluminum oxide (having the specific surface area of 200 m2 /g), and lithium perchlorate was investigated. It was shown that the obtained composites exhibited thermal stability up to at least 190°C. Using the impedance spectroscopy method, it was shown that the highest conductivity of solid electrolytes was ~10–5 S/cm at 40°C, x = 0.5, and 3·10–4 S/cm at x = 0.55 (T = 110°С).
format Article
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institution Kabale University
issn 1608-4039
1680-9505
language English
publishDate 2024-12-01
publisher Saratov State University
record_format Article
series Электрохимическая энергетика
spelling doaj-art-2f86851ec2344f62bc20b4fa5556a7572024-12-24T12:11:53ZengSaratov State UniversityЭлектрохимическая энергетика1608-40391680-95052024-12-0124421622010.18500/1608-4039-2024-24-4-216-220Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium saltKyzlasova, Daria A.0Ulihin, Artem S.1Uvarov, Nikolai F.2Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS, 18, Kutateladze St., Novosibirsk, 630128Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS, 18, Kutateladze St., Novosibirsk, 630128Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS, 18, Kutateladze St., Novosibirsk, 630128The effect of lithium perchlorate (LiClO4) on the transport and thermal properties of the ternary system consisting of N-methyl-N-propylpiperidinium perchlorate, highly dispersed γ-aluminum oxide (having the specific surface area of 200 m2 /g), and lithium perchlorate was investigated. It was shown that the obtained composites exhibited thermal stability up to at least 190°C. Using the impedance spectroscopy method, it was shown that the highest conductivity of solid electrolytes was ~10–5 S/cm at 40°C, x = 0.5, and 3·10–4 S/cm at x = 0.55 (T = 110°С).https://energetica.sgu.ru/sites/energetica.sgu.ru/files/text-pdf/2024/12/electro202404_4-216-220.pdflithium perchlorateorganic ionic plastic crystalscomposite solid electrolytes
spellingShingle Kyzlasova, Daria A.
Ulihin, Artem S.
Uvarov, Nikolai F.
Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium salt
Электрохимическая энергетика
lithium perchlorate
organic ionic plastic crystals
composite solid electrolytes
title Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium salt
title_full Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium salt
title_fullStr Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium salt
title_full_unstemmed Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium salt
title_short Composite solid electrolytes based on lithium doped N-methyl-N-propylpiperidinium salt
title_sort composite solid electrolytes based on lithium doped n methyl n propylpiperidinium salt
topic lithium perchlorate
organic ionic plastic crystals
composite solid electrolytes
url https://energetica.sgu.ru/sites/energetica.sgu.ru/files/text-pdf/2024/12/electro202404_4-216-220.pdf
work_keys_str_mv AT kyzlasovadariaa compositesolidelectrolytesbasedonlithiumdopednmethylnpropylpiperidiniumsalt
AT ulihinartems compositesolidelectrolytesbasedonlithiumdopednmethylnpropylpiperidiniumsalt
AT uvarovnikolaif compositesolidelectrolytesbasedonlithiumdopednmethylnpropylpiperidiniumsalt