Transition metal supported UiO-67 materials and their applications in catalysis
Metal-organic frameworks (MOFs) have emerged as promising platforms for heterogeneous catalysis due to their tunable structures and high specific surface areas. Results indicate that modified composite MOFs not only exhibit superior water stability but also demonstrate broader applicability in catal...
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Frontiers Media S.A.
2025-05-01
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| Series: | Frontiers in Chemistry |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fchem.2025.1596868/full |
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| author | Tingting Li Yan Li Jingxin Mao Jingxin Mao |
| author_facet | Tingting Li Yan Li Jingxin Mao Jingxin Mao |
| author_sort | Tingting Li |
| collection | DOAJ |
| description | Metal-organic frameworks (MOFs) have emerged as promising platforms for heterogeneous catalysis due to their tunable structures and high specific surface areas. Results indicate that modified composite MOFs not only exhibit superior water stability but also demonstrate broader applicability in catalysis, such as Fenton-like oxidation, Morita-Baylis-Hillman reactions, ethylene dimerization, and various photoelectrochemical processes. Among them, UiO-67, a zirconium-based MOF, has attracted extensive attention for its exceptional chemical stability, high catalytic activity, and well-defined microporous structure. This review introduces composites formed by different types of single and multi-metal loadings on UiO-67 and their demonstrated catalytic performance. It emphasizes the structure-performance relationships of these composites, highlighting how metal loading and spatial distribution influence their reactivity and stability. The current application status and existing challenges of UiO-67 series materials and their derivatives in catalysis are systematically reviewed. By integrating experimental results and mechanistic insights, this work underscores the transformative potential of UiO-67 series materials in meeting the demands of sustainable catalysis. |
| format | Article |
| id | doaj-art-2e2a5c3d1f8c4782b7e8011d5ffb8ab8 |
| institution | DOAJ |
| issn | 2296-2646 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj-art-2e2a5c3d1f8c4782b7e8011d5ffb8ab82025-08-20T03:21:47ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462025-05-011310.3389/fchem.2025.15968681596868Transition metal supported UiO-67 materials and their applications in catalysisTingting Li0Yan Li1Jingxin Mao2Jingxin Mao3Chongqing Key Laboratory of High Active Traditional Chinese Drug Delivery system, Chongqing Medical and Pharmaceutical College, Chongqing, ChinaChongqing Key Laboratory of High Active Traditional Chinese Drug Delivery system, Chongqing Medical and Pharmaceutical College, Chongqing, ChinaChongqing Key Laboratory of High Active Traditional Chinese Drug Delivery system, Chongqing Medical and Pharmaceutical College, Chongqing, ChinaCollege of Pharmaceutical Sciences, Southwest University, Chongqing, ChinaMetal-organic frameworks (MOFs) have emerged as promising platforms for heterogeneous catalysis due to their tunable structures and high specific surface areas. Results indicate that modified composite MOFs not only exhibit superior water stability but also demonstrate broader applicability in catalysis, such as Fenton-like oxidation, Morita-Baylis-Hillman reactions, ethylene dimerization, and various photoelectrochemical processes. Among them, UiO-67, a zirconium-based MOF, has attracted extensive attention for its exceptional chemical stability, high catalytic activity, and well-defined microporous structure. This review introduces composites formed by different types of single and multi-metal loadings on UiO-67 and their demonstrated catalytic performance. It emphasizes the structure-performance relationships of these composites, highlighting how metal loading and spatial distribution influence their reactivity and stability. The current application status and existing challenges of UiO-67 series materials and their derivatives in catalysis are systematically reviewed. By integrating experimental results and mechanistic insights, this work underscores the transformative potential of UiO-67 series materials in meeting the demands of sustainable catalysis.https://www.frontiersin.org/articles/10.3389/fchem.2025.1596868/fullUiO-67transition metalcatalystgreen chemistryMOFs |
| spellingShingle | Tingting Li Yan Li Jingxin Mao Jingxin Mao Transition metal supported UiO-67 materials and their applications in catalysis Frontiers in Chemistry UiO-67 transition metal catalyst green chemistry MOFs |
| title | Transition metal supported UiO-67 materials and their applications in catalysis |
| title_full | Transition metal supported UiO-67 materials and their applications in catalysis |
| title_fullStr | Transition metal supported UiO-67 materials and their applications in catalysis |
| title_full_unstemmed | Transition metal supported UiO-67 materials and their applications in catalysis |
| title_short | Transition metal supported UiO-67 materials and their applications in catalysis |
| title_sort | transition metal supported uio 67 materials and their applications in catalysis |
| topic | UiO-67 transition metal catalyst green chemistry MOFs |
| url | https://www.frontiersin.org/articles/10.3389/fchem.2025.1596868/full |
| work_keys_str_mv | AT tingtingli transitionmetalsupporteduio67materialsandtheirapplicationsincatalysis AT yanli transitionmetalsupporteduio67materialsandtheirapplicationsincatalysis AT jingxinmao transitionmetalsupporteduio67materialsandtheirapplicationsincatalysis AT jingxinmao transitionmetalsupporteduio67materialsandtheirapplicationsincatalysis |