Highly Stable Inverted Organic Solar Cell Structure Using Three Efficient Electron Transport Layers

The efficiency of organic solar cells (OSCs) is influenced by various factors, among which environmental temperature plays a significant role. Previous studies have shown that the thermal stability of these cells can be enhanced by incorporating a third component into their structure. Ternary organi...

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Main Authors: Mohamed El Amine Boudia, Zhao Cunlu
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/18/1/167
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author Mohamed El Amine Boudia
Zhao Cunlu
author_facet Mohamed El Amine Boudia
Zhao Cunlu
author_sort Mohamed El Amine Boudia
collection DOAJ
description The efficiency of organic solar cells (OSCs) is influenced by various factors, among which environmental temperature plays a significant role. Previous studies have shown that the thermal stability of these cells can be enhanced by incorporating a third component into their structure. Ternary organic solar cells, particularly, have shown promising results in improving thermal stability. A well-designed electron transport layer (ETL) can significantly bolster thermal stability by facilitating efficient charge transport and reducing charge recombination. In this study, we investigated the effect of temperature, ranging from 300 K to 400 K, on the efficiency of inverted ternary structures by using a one-dimension optoelectronic model on “Oghma-Nano 8.0.034” software. The structures examined include (S1) “FTO/SnO<sub>2</sub>/PM6:D18:L8-BO/PEDOT: PSS/Ag”, (S2): “FTO/C<sub>60</sub>/PM6:D18:L8-BO/PEDOT: PSS/Ag”, and (S3): “FTO/PC<sub>60</sub>BM/PM6:D18:L8-BO/PEDOT: PSS/Ag”. Simulations using three different ETLs—SnO<sub>2</sub>, C<sub>60</sub>, and PC<sub>60</sub>BM—at 340 K (66.85 °C) resulted in a main effect on open circuit voltage (<i>V</i><sub>oc</sub>) and fill factor (<i>FF</i>) values, in addition to an important <i>J</i><sub>sc</sub> value in terms of thermally stable devices. However, these structures retained 92% of their initial ~20% efficiency observed at 300 K, demonstrating significant thermal stability under high power conversion efficiency (<i>PCE</i>) conditions.
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spelling doaj-art-2d84a01c7da442e4a1905e59f3fc7cee2025-01-10T13:17:17ZengMDPI AGEnergies1996-10732025-01-0118116710.3390/en18010167Highly Stable Inverted Organic Solar Cell Structure Using Three Efficient Electron Transport LayersMohamed El Amine Boudia0Zhao Cunlu1MOE Key Laboratory of Thermo-Fluid Science and Engineering, School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, ChinaMOE Key Laboratory of Thermo-Fluid Science and Engineering, School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, ChinaThe efficiency of organic solar cells (OSCs) is influenced by various factors, among which environmental temperature plays a significant role. Previous studies have shown that the thermal stability of these cells can be enhanced by incorporating a third component into their structure. Ternary organic solar cells, particularly, have shown promising results in improving thermal stability. A well-designed electron transport layer (ETL) can significantly bolster thermal stability by facilitating efficient charge transport and reducing charge recombination. In this study, we investigated the effect of temperature, ranging from 300 K to 400 K, on the efficiency of inverted ternary structures by using a one-dimension optoelectronic model on “Oghma-Nano 8.0.034” software. The structures examined include (S1) “FTO/SnO<sub>2</sub>/PM6:D18:L8-BO/PEDOT: PSS/Ag”, (S2): “FTO/C<sub>60</sub>/PM6:D18:L8-BO/PEDOT: PSS/Ag”, and (S3): “FTO/PC<sub>60</sub>BM/PM6:D18:L8-BO/PEDOT: PSS/Ag”. Simulations using three different ETLs—SnO<sub>2</sub>, C<sub>60</sub>, and PC<sub>60</sub>BM—at 340 K (66.85 °C) resulted in a main effect on open circuit voltage (<i>V</i><sub>oc</sub>) and fill factor (<i>FF</i>) values, in addition to an important <i>J</i><sub>sc</sub> value in terms of thermally stable devices. However, these structures retained 92% of their initial ~20% efficiency observed at 300 K, demonstrating significant thermal stability under high power conversion efficiency (<i>PCE</i>) conditions.https://www.mdpi.com/1996-1073/18/1/167organic solar cellsternary structuresoperating temperatureelectron transport layerpower conversion efficiency
spellingShingle Mohamed El Amine Boudia
Zhao Cunlu
Highly Stable Inverted Organic Solar Cell Structure Using Three Efficient Electron Transport Layers
Energies
organic solar cells
ternary structures
operating temperature
electron transport layer
power conversion efficiency
title Highly Stable Inverted Organic Solar Cell Structure Using Three Efficient Electron Transport Layers
title_full Highly Stable Inverted Organic Solar Cell Structure Using Three Efficient Electron Transport Layers
title_fullStr Highly Stable Inverted Organic Solar Cell Structure Using Three Efficient Electron Transport Layers
title_full_unstemmed Highly Stable Inverted Organic Solar Cell Structure Using Three Efficient Electron Transport Layers
title_short Highly Stable Inverted Organic Solar Cell Structure Using Three Efficient Electron Transport Layers
title_sort highly stable inverted organic solar cell structure using three efficient electron transport layers
topic organic solar cells
ternary structures
operating temperature
electron transport layer
power conversion efficiency
url https://www.mdpi.com/1996-1073/18/1/167
work_keys_str_mv AT mohamedelamineboudia highlystableinvertedorganicsolarcellstructureusingthreeefficientelectrontransportlayers
AT zhaocunlu highlystableinvertedorganicsolarcellstructureusingthreeefficientelectrontransportlayers