Adsorption of Phenol from Aqueous Solution onto Fly Ash from a Thermal Power Plant

Phenol ranks as one of the most common hazardous pollutants present in water and industrial effluents. The object of the work describe herein was to assess the phenol adsorption capacity of fly ash under varying experimental conditions such as adsorbent dosage, pH, varying phenol concentration and c...

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Main Authors: Richa Sharan, Gurdeep Singh, Sunil K. Gupta
Format: Article
Language:English
Published: SAGE Publishing 2009-04-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361709789868875
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author Richa Sharan
Gurdeep Singh
Sunil K. Gupta
author_facet Richa Sharan
Gurdeep Singh
Sunil K. Gupta
author_sort Richa Sharan
collection DOAJ
description Phenol ranks as one of the most common hazardous pollutants present in water and industrial effluents. The object of the work describe herein was to assess the phenol adsorption capacity of fly ash under varying experimental conditions such as adsorbent dosage, pH, varying phenol concentration and contact time. The study showed that, at a phenol concentration of 100 mg/ℓ, the percentage removal of phenol was 95.69% at an optimum dosage of 7 g/ℓ fly ash. The effect of the initial phenol concentration indicated that the percentage phenol removal increased with increasing phenol concentration, being a maximum (98.08%) at a phenol concentration of 700 mg/ℓ. Further increase in phenol concentration (1000 mg/ℓ) resulted in a slight decrease in phenol removal. The adsorption of phenol also varied with the pH and was found to be a maximum at a pH value of 8. Adsorption equilibrium studies indicated that an equilibrium time of 2 h was necessary for the maximum removal of phenol. Isotherm studies showed that the adsorption of phenol onto fly ash was best described by the Langmuir isotherm relative to the Freundlich isotherm. Accordingly, the Langmuir adsorption coefficients, i.e. the maximum adsorption capacity (q 0 ) and the Langmuir adsorption constant (K L ) were evaluated and found to be 142.86 mg/g and 0.0199 ℓ/g, respectively. Analysis of the kinetic data indicated that the kinetics of phenol adsorption closely follow the pseudo-second-order model.
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spelling doaj-art-2be4b8f04a9748a8bb7a32a7a3dd87e02025-01-03T00:11:32ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382009-04-012710.1260/026361709789868875Adsorption of Phenol from Aqueous Solution onto Fly Ash from a Thermal Power PlantRicha SharanGurdeep SinghSunil K. GuptaPhenol ranks as one of the most common hazardous pollutants present in water and industrial effluents. The object of the work describe herein was to assess the phenol adsorption capacity of fly ash under varying experimental conditions such as adsorbent dosage, pH, varying phenol concentration and contact time. The study showed that, at a phenol concentration of 100 mg/ℓ, the percentage removal of phenol was 95.69% at an optimum dosage of 7 g/ℓ fly ash. The effect of the initial phenol concentration indicated that the percentage phenol removal increased with increasing phenol concentration, being a maximum (98.08%) at a phenol concentration of 700 mg/ℓ. Further increase in phenol concentration (1000 mg/ℓ) resulted in a slight decrease in phenol removal. The adsorption of phenol also varied with the pH and was found to be a maximum at a pH value of 8. Adsorption equilibrium studies indicated that an equilibrium time of 2 h was necessary for the maximum removal of phenol. Isotherm studies showed that the adsorption of phenol onto fly ash was best described by the Langmuir isotherm relative to the Freundlich isotherm. Accordingly, the Langmuir adsorption coefficients, i.e. the maximum adsorption capacity (q 0 ) and the Langmuir adsorption constant (K L ) were evaluated and found to be 142.86 mg/g and 0.0199 ℓ/g, respectively. Analysis of the kinetic data indicated that the kinetics of phenol adsorption closely follow the pseudo-second-order model.https://doi.org/10.1260/026361709789868875
spellingShingle Richa Sharan
Gurdeep Singh
Sunil K. Gupta
Adsorption of Phenol from Aqueous Solution onto Fly Ash from a Thermal Power Plant
Adsorption Science & Technology
title Adsorption of Phenol from Aqueous Solution onto Fly Ash from a Thermal Power Plant
title_full Adsorption of Phenol from Aqueous Solution onto Fly Ash from a Thermal Power Plant
title_fullStr Adsorption of Phenol from Aqueous Solution onto Fly Ash from a Thermal Power Plant
title_full_unstemmed Adsorption of Phenol from Aqueous Solution onto Fly Ash from a Thermal Power Plant
title_short Adsorption of Phenol from Aqueous Solution onto Fly Ash from a Thermal Power Plant
title_sort adsorption of phenol from aqueous solution onto fly ash from a thermal power plant
url https://doi.org/10.1260/026361709789868875
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AT sunilkgupta adsorptionofphenolfromaqueoussolutionontoflyashfromathermalpowerplant