Adsorptive Distillation Using Molecular Sieves and Low-Cost Biobased Adsorbents for the Break-up of the Isopropanol–Water Azeotrope

The separation of isopropanol from aqueous vapours near the azeotropic composition was investigated using fixed beds packed with type A molecular sieves and biobased adsorbents. Natural palm stones, oak and corncobs were used as new biobased adsorbents. It was possible to break the azeotrope up usin...

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Bibliographic Details
Main Authors: Fawzi Banat, Sameer Al-Asheh, Nasir Al-Lagtah
Format: Article
Language:English
Published: SAGE Publishing 2003-11-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/02636170360744074
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Summary:The separation of isopropanol from aqueous vapours near the azeotropic composition was investigated using fixed beds packed with type A molecular sieves and biobased adsorbents. Natural palm stones, oak and corncobs were used as new biobased adsorbents. It was possible to break the azeotrope up using any of the afore-mentioned adsorbents. However, in terms of the breakthrough time and the purity of isopropanol in the condensate, the 3 Å molecular sieve was the best followed by 4 Å, palm stones, natural corncobs, natural oak and 5 Å molecular sieves. Activated carbons prepared from the biobased adsorbents showed a lower performance than their natural precursors.
ISSN:0263-6174
2048-4038