Binary Mixtures of Chlorobenzene and Cyclohexane Vapours Adsorbed under Dynamic and Static Conditions by Activated Carbon Beds

The adsorption of mixtures of chlorobenzene (C 6 H 5 Cl) + cyclohexane (c-C 6 H 12 ) onto activated carbon U-03 has been examined at about room temperature. As shown by Stoeckli et al. (2002), combination of the Myers-Prausnitz-Dubinin theory (MPD) with the activity coefficients of the corresponding...

Full description

Saved in:
Bibliographic Details
Main Author: R.M. Sobota
Format: Article
Language:English
Published: SAGE Publishing 2008-02-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361708786035404
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1841561760223461376
author R.M. Sobota
author_facet R.M. Sobota
author_sort R.M. Sobota
collection DOAJ
description The adsorption of mixtures of chlorobenzene (C 6 H 5 Cl) + cyclohexane (c-C 6 H 12 ) onto activated carbon U-03 has been examined at about room temperature. As shown by Stoeckli et al. (2002), combination of the Myers-Prausnitz-Dubinin theory (MPD) with the activity coefficients of the corresponding solid-liquid equilibrium led to a good correlation between the calculated and experimental mole fractions for the adsorption of binary mixture vapours by microporous solids under static conditions. The present study demonstrates the approach, which is based on an ideal adsorbed state (IAS). This can be employed for binary vapour mixtures such as chlorobenzene + cyclohexane under dynamic conditions in PSA (Pressure Swing Adsorption) and dynamic breakthrough experiments.
format Article
id doaj-art-2b4b0e3547b14067a3c7ca00971d5c68
institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2008-02-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-2b4b0e3547b14067a3c7ca00971d5c682025-01-03T01:24:47ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382008-02-012610.1260/026361708786035404Binary Mixtures of Chlorobenzene and Cyclohexane Vapours Adsorbed under Dynamic and Static Conditions by Activated Carbon BedsR.M. SobotaThe adsorption of mixtures of chlorobenzene (C 6 H 5 Cl) + cyclohexane (c-C 6 H 12 ) onto activated carbon U-03 has been examined at about room temperature. As shown by Stoeckli et al. (2002), combination of the Myers-Prausnitz-Dubinin theory (MPD) with the activity coefficients of the corresponding solid-liquid equilibrium led to a good correlation between the calculated and experimental mole fractions for the adsorption of binary mixture vapours by microporous solids under static conditions. The present study demonstrates the approach, which is based on an ideal adsorbed state (IAS). This can be employed for binary vapour mixtures such as chlorobenzene + cyclohexane under dynamic conditions in PSA (Pressure Swing Adsorption) and dynamic breakthrough experiments.https://doi.org/10.1260/026361708786035404
spellingShingle R.M. Sobota
Binary Mixtures of Chlorobenzene and Cyclohexane Vapours Adsorbed under Dynamic and Static Conditions by Activated Carbon Beds
Adsorption Science & Technology
title Binary Mixtures of Chlorobenzene and Cyclohexane Vapours Adsorbed under Dynamic and Static Conditions by Activated Carbon Beds
title_full Binary Mixtures of Chlorobenzene and Cyclohexane Vapours Adsorbed under Dynamic and Static Conditions by Activated Carbon Beds
title_fullStr Binary Mixtures of Chlorobenzene and Cyclohexane Vapours Adsorbed under Dynamic and Static Conditions by Activated Carbon Beds
title_full_unstemmed Binary Mixtures of Chlorobenzene and Cyclohexane Vapours Adsorbed under Dynamic and Static Conditions by Activated Carbon Beds
title_short Binary Mixtures of Chlorobenzene and Cyclohexane Vapours Adsorbed under Dynamic and Static Conditions by Activated Carbon Beds
title_sort binary mixtures of chlorobenzene and cyclohexane vapours adsorbed under dynamic and static conditions by activated carbon beds
url https://doi.org/10.1260/026361708786035404
work_keys_str_mv AT rmsobota binarymixturesofchlorobenzeneandcyclohexanevapoursadsorbedunderdynamicandstaticconditionsbyactivatedcarbonbeds