4,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrate

In the title hydrated salt, (C10H10N2)[SnF2Cl4]·H2O, the dihedral angle between the pyridinium rings in the cation is 40.5 (4)° and the F atoms in the octahedral complex anion have a cis disposition [F—Sn—F = 85.32 (17)°]. In the extended structure, alternating cationic and anionic layers occur, lin...

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Main Authors: Amina Kemmouche, Rochdi Ghallab, Hocine Merazig
Format: Article
Language:English
Published: International Union of Crystallography 2025-07-01
Series:IUCrData
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Online Access:https://journals.iucr.org/paper?S2414314625005966
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author Amina Kemmouche
Rochdi Ghallab
Hocine Merazig
author_facet Amina Kemmouche
Rochdi Ghallab
Hocine Merazig
author_sort Amina Kemmouche
collection DOAJ
description In the title hydrated salt, (C10H10N2)[SnF2Cl4]·H2O, the dihedral angle between the pyridinium rings in the cation is 40.5 (4)° and the F atoms in the octahedral complex anion have a cis disposition [F—Sn—F = 85.32 (17)°]. In the extended structure, alternating cationic and anionic layers occur, linked by extensive hydrogen bonding, with water molecules inserted between the layers.
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institution Kabale University
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publisher International Union of Crystallography
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spelling doaj-art-2ac512314fae4470a2edf45fd03e79b82025-08-20T03:44:29ZengInternational Union of CrystallographyIUCrData2414-31462025-07-01107x25059610.1107/S2414314625005966hb45214,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrateAmina Kemmouche0Rochdi Ghallab1Hocine Merazig2Ecole Nationale Superieure de Biotechnologie de Constantine, AlgeriaLaboratoire de Technologie des Materiaux Avances, Ecole Nationale Polytechnique de Constantine, AlgeriaUnite De Recherche Chimie De L'Environnement Et Moleculaire Structurale, URCHEMS, University of Constantine 1-Mentouri Brothers, AlgeriaIn the title hydrated salt, (C10H10N2)[SnF2Cl4]·H2O, the dihedral angle between the pyridinium rings in the cation is 40.5 (4)° and the F atoms in the octahedral complex anion have a cis disposition [F—Sn—F = 85.32 (17)°]. In the extended structure, alternating cationic and anionic layers occur, linked by extensive hydrogen bonding, with water molecules inserted between the layers.https://journals.iucr.org/paper?S2414314625005966crystal structurestannate(iv)bipyridiniumx-ray diffraction
spellingShingle Amina Kemmouche
Rochdi Ghallab
Hocine Merazig
4,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrate
IUCrData
crystal structure
stannate(iv)
bipyridinium
x-ray diffraction
title 4,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrate
title_full 4,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrate
title_fullStr 4,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrate
title_full_unstemmed 4,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrate
title_short 4,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrate
title_sort 4 4 bipyridine 1 1 diium tetrachloridodifluoridostannate iv monohydrate
topic crystal structure
stannate(iv)
bipyridinium
x-ray diffraction
url https://journals.iucr.org/paper?S2414314625005966
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AT hocinemerazig 44bipyridine11diiumtetrachloridodifluoridostannateivmonohydrate