4,4′-Bipyridine-1,1′-diium tetrachloridodifluoridostannate(IV) monohydrate

In the title hydrated salt, (C10H10N2)[SnF2Cl4]·H2O, the dihedral angle between the pyridinium rings in the cation is 40.5 (4)° and the F atoms in the octahedral complex anion have a cis disposition [F—Sn—F = 85.32 (17)°]. In the extended structure, alternating cationic and anionic layers occur, lin...

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Bibliographic Details
Main Authors: Amina Kemmouche, Rochdi Ghallab, Hocine Merazig
Format: Article
Language:English
Published: International Union of Crystallography 2025-07-01
Series:IUCrData
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Online Access:https://journals.iucr.org/paper?S2414314625005966
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Summary:In the title hydrated salt, (C10H10N2)[SnF2Cl4]·H2O, the dihedral angle between the pyridinium rings in the cation is 40.5 (4)° and the F atoms in the octahedral complex anion have a cis disposition [F—Sn—F = 85.32 (17)°]. In the extended structure, alternating cationic and anionic layers occur, linked by extensive hydrogen bonding, with water molecules inserted between the layers.
ISSN:2414-3146