Effect of Carbon Deposits on the Structure of Hybrid C/TiO/SiO Adsorbents
The structural characteristics of pyrocarbon/X (X = fumed silica, mesoporous silica gel, fumed titania/silica, CVD-TiO 2 /fumed silica, CVD-TiO 2 /silica gel) prepared using several precursors [CH 2 Cl 2 , cyclohexene and TiO(AcAc) 2 , where Ac = acetylacetonate] were studied using the nitrogen adso...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
SAGE Publishing
2001-06-01
|
| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263617011494259 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841563125975875584 |
|---|---|
| author | R. Leboda V.M. Gun'ko M. Marciniak W. Grzegorczyk J. Skubiszewska-Zięba |
| author_facet | R. Leboda V.M. Gun'ko M. Marciniak W. Grzegorczyk J. Skubiszewska-Zięba |
| author_sort | R. Leboda |
| collection | DOAJ |
| description | The structural characteristics of pyrocarbon/X (X = fumed silica, mesoporous silica gel, fumed titania/silica, CVD-TiO 2 /fumed silica, CVD-TiO 2 /silica gel) prepared using several precursors [CH 2 Cl 2 , cyclohexene and TiO(AcAc) 2 , where Ac = acetylacetonate] were studied using the nitrogen adsorption/desorption method and an improved technique to allow the calculation of pore size distributions applying regularization procedures. Various pore models were used for the carbon phase. The pyrocarbon structure and distribution on the TiO 2 /SiO 2 supports depends primarily on the structural features of the titania phase which exhibits catalytic activity in the pyrolysis of organic materials. The formation of relatively large concentrations of pyrocarbon typically reduces the porosity and specific surface area of the hybrid adsorbents produced. |
| format | Article |
| id | doaj-art-2823811f18754e3888dd3b2aa7466740 |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2001-06-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-2823811f18754e3888dd3b2aa74667402025-01-03T00:11:56ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382001-06-011910.1260/0263617011494259Effect of Carbon Deposits on the Structure of Hybrid C/TiO/SiO AdsorbentsR. Leboda0V.M. Gun'ko1M. Marciniak2W. Grzegorczyk3J. Skubiszewska-Zięba4 Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 17 General Naumov Str., 03164 Kiev, Ukraine Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 3, 20-031 Lublin, PolandThe structural characteristics of pyrocarbon/X (X = fumed silica, mesoporous silica gel, fumed titania/silica, CVD-TiO 2 /fumed silica, CVD-TiO 2 /silica gel) prepared using several precursors [CH 2 Cl 2 , cyclohexene and TiO(AcAc) 2 , where Ac = acetylacetonate] were studied using the nitrogen adsorption/desorption method and an improved technique to allow the calculation of pore size distributions applying regularization procedures. Various pore models were used for the carbon phase. The pyrocarbon structure and distribution on the TiO 2 /SiO 2 supports depends primarily on the structural features of the titania phase which exhibits catalytic activity in the pyrolysis of organic materials. The formation of relatively large concentrations of pyrocarbon typically reduces the porosity and specific surface area of the hybrid adsorbents produced.https://doi.org/10.1260/0263617011494259 |
| spellingShingle | R. Leboda V.M. Gun'ko M. Marciniak W. Grzegorczyk J. Skubiszewska-Zięba Effect of Carbon Deposits on the Structure of Hybrid C/TiO/SiO Adsorbents Adsorption Science & Technology |
| title | Effect of Carbon Deposits on the Structure of Hybrid C/TiO/SiO Adsorbents |
| title_full | Effect of Carbon Deposits on the Structure of Hybrid C/TiO/SiO Adsorbents |
| title_fullStr | Effect of Carbon Deposits on the Structure of Hybrid C/TiO/SiO Adsorbents |
| title_full_unstemmed | Effect of Carbon Deposits on the Structure of Hybrid C/TiO/SiO Adsorbents |
| title_short | Effect of Carbon Deposits on the Structure of Hybrid C/TiO/SiO Adsorbents |
| title_sort | effect of carbon deposits on the structure of hybrid c tio sio adsorbents |
| url | https://doi.org/10.1260/0263617011494259 |
| work_keys_str_mv | AT rleboda effectofcarbondepositsonthestructureofhybridctiosioadsorbents AT vmgunko effectofcarbondepositsonthestructureofhybridctiosioadsorbents AT mmarciniak effectofcarbondepositsonthestructureofhybridctiosioadsorbents AT wgrzegorczyk effectofcarbondepositsonthestructureofhybridctiosioadsorbents AT jskubiszewskazieba effectofcarbondepositsonthestructureofhybridctiosioadsorbents |