Magnetically Induced Anisotropic Microstructures on Polyethylene Glycol Hydrogel Facilitate BMSC Alignment and Osteogenic Differentiation

Many tissues exhibit structural anisotropy, which imparts orientation-specific properties and functions. However, recapitulating the cellular patterns found in anisotropic tissues presents a remarkable challenge, particularly when using soft and wet hydrogels. Herein, we develop self-assembled aniso...

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Main Authors: Hua Zhang, Yang Luo, Rong Xu, Xu Cao, Guanrong Li, Shang Chen
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Gels
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Online Access:https://www.mdpi.com/2310-2861/10/12/814
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author Hua Zhang
Yang Luo
Rong Xu
Xu Cao
Guanrong Li
Shang Chen
author_facet Hua Zhang
Yang Luo
Rong Xu
Xu Cao
Guanrong Li
Shang Chen
author_sort Hua Zhang
collection DOAJ
description Many tissues exhibit structural anisotropy, which imparts orientation-specific properties and functions. However, recapitulating the cellular patterns found in anisotropic tissues presents a remarkable challenge, particularly when using soft and wet hydrogels. Herein, we develop self-assembled anisotropic magnetic Fe<sub>3</sub>O<sub>4</sub> micropatterns on polyethylene glycol hydrogels utilizing dipole–dipole interactions. Under the influence of a static magnetic field, Fe<sub>3</sub>O<sub>4</sub> nanoparticles align into highly ordered structures with a height of 400–600 nm and a width of 8–10 μm. Furthermore, our layer-by-layer assembly technique enables the creation of oriented micropatterns with varying densities and heights, which can be further manipulated to form three-dimensional structures by adjusting the angle of the magnetic field. These anisotropic magnetic Fe<sub>3</sub>O<sub>4</sub> micropatterns can be applied to various substrates, including treated glass slides, standard glass slides, silicon wafers, and polydimethylsiloxane. The patterned Fe<sub>3</sub>O<sub>4</sub> scaffolds, modified with gold coating, effectively enhance cellular adhesion, orientation, and osteogenic differentiation of bone marrow-derived stem cells, which is crucial for effective tissue repair. Overall, this study presents an efficient strategy for constructing anisotropic Fe<sub>3</sub>O<sub>4</sub> micropattern hydrogels, providing a bioactive platform that significantly enhances cellular functions.
format Article
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institution Kabale University
issn 2310-2861
language English
publishDate 2024-12-01
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spelling doaj-art-273ee73e146b4f139810fe62fe01c36c2024-12-27T14:27:57ZengMDPI AGGels2310-28612024-12-01101281410.3390/gels10120814Magnetically Induced Anisotropic Microstructures on Polyethylene Glycol Hydrogel Facilitate BMSC Alignment and Osteogenic DifferentiationHua Zhang0Yang Luo1Rong Xu2Xu Cao3Guanrong Li4Shang Chen5Research Institute of Smart Medicine and Biological Engineering, Health Science Center, Ningbo University, Ningbo 315211, ChinaResearch Institute of Smart Medicine and Biological Engineering, Health Science Center, Ningbo University, Ningbo 315211, ChinaResearch Institute of Smart Medicine and Biological Engineering, Health Science Center, Ningbo University, Ningbo 315211, ChinaResearch Institute of Smart Medicine and Biological Engineering, Health Science Center, Ningbo University, Ningbo 315211, ChinaResearch Institute of Smart Medicine and Biological Engineering, Health Science Center, Ningbo University, Ningbo 315211, ChinaResearch Institute of Smart Medicine and Biological Engineering, Health Science Center, Ningbo University, Ningbo 315211, ChinaMany tissues exhibit structural anisotropy, which imparts orientation-specific properties and functions. However, recapitulating the cellular patterns found in anisotropic tissues presents a remarkable challenge, particularly when using soft and wet hydrogels. Herein, we develop self-assembled anisotropic magnetic Fe<sub>3</sub>O<sub>4</sub> micropatterns on polyethylene glycol hydrogels utilizing dipole–dipole interactions. Under the influence of a static magnetic field, Fe<sub>3</sub>O<sub>4</sub> nanoparticles align into highly ordered structures with a height of 400–600 nm and a width of 8–10 μm. Furthermore, our layer-by-layer assembly technique enables the creation of oriented micropatterns with varying densities and heights, which can be further manipulated to form three-dimensional structures by adjusting the angle of the magnetic field. These anisotropic magnetic Fe<sub>3</sub>O<sub>4</sub> micropatterns can be applied to various substrates, including treated glass slides, standard glass slides, silicon wafers, and polydimethylsiloxane. The patterned Fe<sub>3</sub>O<sub>4</sub> scaffolds, modified with gold coating, effectively enhance cellular adhesion, orientation, and osteogenic differentiation of bone marrow-derived stem cells, which is crucial for effective tissue repair. Overall, this study presents an efficient strategy for constructing anisotropic Fe<sub>3</sub>O<sub>4</sub> micropattern hydrogels, providing a bioactive platform that significantly enhances cellular functions.https://www.mdpi.com/2310-2861/10/12/814magnetic field inductionFe<sub>3</sub>O<sub>4</sub> micropatternsoriented cytoskeletonosteogenic differentiation
spellingShingle Hua Zhang
Yang Luo
Rong Xu
Xu Cao
Guanrong Li
Shang Chen
Magnetically Induced Anisotropic Microstructures on Polyethylene Glycol Hydrogel Facilitate BMSC Alignment and Osteogenic Differentiation
Gels
magnetic field induction
Fe<sub>3</sub>O<sub>4</sub> micropatterns
oriented cytoskeleton
osteogenic differentiation
title Magnetically Induced Anisotropic Microstructures on Polyethylene Glycol Hydrogel Facilitate BMSC Alignment and Osteogenic Differentiation
title_full Magnetically Induced Anisotropic Microstructures on Polyethylene Glycol Hydrogel Facilitate BMSC Alignment and Osteogenic Differentiation
title_fullStr Magnetically Induced Anisotropic Microstructures on Polyethylene Glycol Hydrogel Facilitate BMSC Alignment and Osteogenic Differentiation
title_full_unstemmed Magnetically Induced Anisotropic Microstructures on Polyethylene Glycol Hydrogel Facilitate BMSC Alignment and Osteogenic Differentiation
title_short Magnetically Induced Anisotropic Microstructures on Polyethylene Glycol Hydrogel Facilitate BMSC Alignment and Osteogenic Differentiation
title_sort magnetically induced anisotropic microstructures on polyethylene glycol hydrogel facilitate bmsc alignment and osteogenic differentiation
topic magnetic field induction
Fe<sub>3</sub>O<sub>4</sub> micropatterns
oriented cytoskeleton
osteogenic differentiation
url https://www.mdpi.com/2310-2861/10/12/814
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AT yangluo magneticallyinducedanisotropicmicrostructuresonpolyethyleneglycolhydrogelfacilitatebmscalignmentandosteogenicdifferentiation
AT rongxu magneticallyinducedanisotropicmicrostructuresonpolyethyleneglycolhydrogelfacilitatebmscalignmentandosteogenicdifferentiation
AT xucao magneticallyinducedanisotropicmicrostructuresonpolyethyleneglycolhydrogelfacilitatebmscalignmentandosteogenicdifferentiation
AT guanrongli magneticallyinducedanisotropicmicrostructuresonpolyethyleneglycolhydrogelfacilitatebmscalignmentandosteogenicdifferentiation
AT shangchen magneticallyinducedanisotropicmicrostructuresonpolyethyleneglycolhydrogelfacilitatebmscalignmentandosteogenicdifferentiation