Bar Adsorbent Microextraction with Carbon-Based Sorbent Layers for the Identification of Pharmaceutic Substances
Thirteen carbon materials were tested as sorbent layers in bar adsorbent microextraction (BAμE) to monitor hint amounts of 10 common pharmaceutical compounds (PhCs) in surface and groundwater matrices such as surface and groundwater, saltwater, spring water, and sewage. The persistence of trace amou...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2023-01-01
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| Series: | Adsorption Science & Technology |
| Online Access: | http://dx.doi.org/10.1155/2023/6153630 |
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| author | S. Thenmozhi V. Gowri K. S. Vinayaka Ravindra Pratap Singh V. M. Vel Kareem Yusuf Ahmed muteb Aljuwayid Md Ataul Islam Abdi Diriba |
| author_facet | S. Thenmozhi V. Gowri K. S. Vinayaka Ravindra Pratap Singh V. M. Vel Kareem Yusuf Ahmed muteb Aljuwayid Md Ataul Islam Abdi Diriba |
| author_sort | S. Thenmozhi |
| collection | DOAJ |
| description | Thirteen carbon materials were tested as sorbent layers in bar adsorbent microextraction (BAμE) to monitor hint amounts of 10 common pharmaceutical compounds (PhCs) in surface and groundwater matrices such as surface and groundwater, saltwater, spring water, and sewage. The persistence of trace amounts of three organophosphate insect repellent and cis and trans permethrin (PERM) in water quality matrices is suggested using bar adsorptive microextraction in conjunction with microliquid dissolution accompanied by significant volume injection-gas chromatography-mass spectroscopic analysis able to operate in the particular ion monitoring acquisition mode. Using BAμE to compare several sorbent coatings (five porous carbon and six polymers), it was discovered that activated carbon (AC2) was the optimum compromise among specificity and effectiveness. 17-estradiol, estrone, sulfamethoxazole, diclofenac, triclosan, gemfibrozil, 17-ethinylestradiol, mefenamic acid, and clofibric acid were chosen as system drugs to represent different treatment groups. Despite their lower porosity, statistics revealed that low-T-activated hydrochars, made from carbohydrates and a eutectic salt mixture at constant temperature (e.g., 180°C) and autogenerated pressures, could compete at the top level commercially carbonaceous materials in this purpose. These L-T-activated hydrochars had the best overall recovery (between 21.8 and 83.5 percent) for the simultaneous analysis of ten targeted PhCs with very different physical and chemical possessions, utilizing higher-efficiency liquid chromatography diode array identification. |
| format | Article |
| id | doaj-art-26e24ae486524d57bed90a5ea45e541f |
| institution | Kabale University |
| issn | 2048-4038 |
| language | English |
| publishDate | 2023-01-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-26e24ae486524d57bed90a5ea45e541f2025-01-02T21:31:35ZengSAGE PublishingAdsorption Science & Technology2048-40382023-01-01202310.1155/2023/6153630Bar Adsorbent Microextraction with Carbon-Based Sorbent Layers for the Identification of Pharmaceutic SubstancesS. Thenmozhi0V. Gowri1K. S. Vinayaka2Ravindra Pratap Singh3V. M. Vel4Kareem Yusuf5Ahmed muteb Aljuwayid6Md Ataul Islam7Abdi Diriba8Department of Civil EngineeringDepartment of Civil EngineeringDepartment of BotanyDepartment of Mechanical EngineeringDepartment of Mechanical EngineeringDepartment of ChemistryDepartment of ChemistrySchool of Health SciencesDepartment of Mechanical EngineeringThirteen carbon materials were tested as sorbent layers in bar adsorbent microextraction (BAμE) to monitor hint amounts of 10 common pharmaceutical compounds (PhCs) in surface and groundwater matrices such as surface and groundwater, saltwater, spring water, and sewage. The persistence of trace amounts of three organophosphate insect repellent and cis and trans permethrin (PERM) in water quality matrices is suggested using bar adsorptive microextraction in conjunction with microliquid dissolution accompanied by significant volume injection-gas chromatography-mass spectroscopic analysis able to operate in the particular ion monitoring acquisition mode. Using BAμE to compare several sorbent coatings (five porous carbon and six polymers), it was discovered that activated carbon (AC2) was the optimum compromise among specificity and effectiveness. 17-estradiol, estrone, sulfamethoxazole, diclofenac, triclosan, gemfibrozil, 17-ethinylestradiol, mefenamic acid, and clofibric acid were chosen as system drugs to represent different treatment groups. Despite their lower porosity, statistics revealed that low-T-activated hydrochars, made from carbohydrates and a eutectic salt mixture at constant temperature (e.g., 180°C) and autogenerated pressures, could compete at the top level commercially carbonaceous materials in this purpose. These L-T-activated hydrochars had the best overall recovery (between 21.8 and 83.5 percent) for the simultaneous analysis of ten targeted PhCs with very different physical and chemical possessions, utilizing higher-efficiency liquid chromatography diode array identification.http://dx.doi.org/10.1155/2023/6153630 |
| spellingShingle | S. Thenmozhi V. Gowri K. S. Vinayaka Ravindra Pratap Singh V. M. Vel Kareem Yusuf Ahmed muteb Aljuwayid Md Ataul Islam Abdi Diriba Bar Adsorbent Microextraction with Carbon-Based Sorbent Layers for the Identification of Pharmaceutic Substances Adsorption Science & Technology |
| title | Bar Adsorbent Microextraction with Carbon-Based Sorbent Layers for the Identification of Pharmaceutic Substances |
| title_full | Bar Adsorbent Microextraction with Carbon-Based Sorbent Layers for the Identification of Pharmaceutic Substances |
| title_fullStr | Bar Adsorbent Microextraction with Carbon-Based Sorbent Layers for the Identification of Pharmaceutic Substances |
| title_full_unstemmed | Bar Adsorbent Microextraction with Carbon-Based Sorbent Layers for the Identification of Pharmaceutic Substances |
| title_short | Bar Adsorbent Microextraction with Carbon-Based Sorbent Layers for the Identification of Pharmaceutic Substances |
| title_sort | bar adsorbent microextraction with carbon based sorbent layers for the identification of pharmaceutic substances |
| url | http://dx.doi.org/10.1155/2023/6153630 |
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