Estimation of Activation Energy of Desorption of n-Hexanol from Activated Carbons by the TPD Technique

Activated carbon and five kinds of metal-ion-substituted activated carbons, viz. Ag + -activated carbon, Cu 2+ -activated carbon, Fe 3+ -activated carbon, Ba 2+ -activated carbon and Ca 2+ -activated carbon, were prepared. A model for estimating the activation energy of desorption was established. T...

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Bibliographic Details
Main Authors: Zhong Li, Hongjuan Wang, Hongxia Xi, Qibin Xia, Jinglei Han, Lingai Luo
Format: Article
Language:English
Published: SAGE Publishing 2003-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361703769013862
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Summary:Activated carbon and five kinds of metal-ion-substituted activated carbons, viz. Ag + -activated carbon, Cu 2+ -activated carbon, Fe 3+ -activated carbon, Ba 2+ -activated carbon and Ca 2+ -activated carbon, were prepared. A model for estimating the activation energy of desorption was established. Temperature-programmed desorption (TPD) experiments were conducted to measure the TPD curves of n-hexanol and hence estimate the activation energy for n-hexanol desorption from the various activated carbons. The results showed that the activation energies for n-hexanol desorption from the Ag + -activated carbon, the Cu 2+ -activated carbon and the Fe 3+ -activated carbon were higher than those from the unsubstituted activated carbon, the Ca 2+ -activated carbon and the Ba 2+ -activated carbon.
ISSN:0263-6174
2048-4038