Effect of Functional Groups in Coal on the Depth of Adsorption Potential Well
Due to the complexity of the internal structure of natural coal and its characteristic of multicomponent, the depth of its methane adsorption potential well is nonuniform, which makes it difficult to accurately evaluate the adsorption capacity of coal. Besides, in order to find out the factors affec...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
SAGE Publishing
2021-01-01
|
| Series: | Adsorption Science & Technology |
| Online Access: | http://dx.doi.org/10.1155/2021/3820762 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841564299253776384 |
|---|---|
| author | Chen Wang Zengchao Feng Xing Wang |
| author_facet | Chen Wang Zengchao Feng Xing Wang |
| author_sort | Chen Wang |
| collection | DOAJ |
| description | Due to the complexity of the internal structure of natural coal and its characteristic of multicomponent, the depth of its methane adsorption potential well is nonuniform, which makes it difficult to accurately evaluate the adsorption capacity of coal. Besides, in order to find out the factors affecting the depth distribution of potential wells in natural coal, this paper calculated the depth and number of potential wells during methane adsorption in coal according to the Langmuir adsorption kinetics process. Coal samples with different metamorphic degrees were tested and analyzed by infrared spectroscopy diffraction technology. The relationship between the structural parameters of functional groups in coal samples with different metamorphic degrees and the distribution of different depths of adsorption potential wells in coal samples was studied. Some main conclusions are as follows: The number of adsorption potential wells at different depths in natural coal with different metamorphic degrees has multipeak distribution characteristics. With the increase of the metamorphic degree of coal sample, the structures such as aliphatic branched chain structure and oxygen-containing functional groups in coal structure break, fall off, and deoxygenate. The relative content of aliphatic hydrocarbons is significantly reduced and condensed into aromatic hydrocarbons and aromatic ring structures. The different types and quantities of functional groups on the surface of coal samples lead to different forces between coal molecules and methane gas molecules, thus affecting the distribution of different depths of adsorption potential wells in coal samples. |
| format | Article |
| id | doaj-art-21cf68956e4e420dbc4a8f990a3bdebe |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2021-01-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-21cf68956e4e420dbc4a8f990a3bdebe2025-01-02T22:54:09ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382021-01-01202110.1155/2021/38207623820762Effect of Functional Groups in Coal on the Depth of Adsorption Potential WellChen Wang0Zengchao Feng1Xing Wang2Key Laboratory of In-Situ Property Improving Mining of Ministry of Education, Taiyuan University of Technology, Shanxi Taiyuan 030024, ChinaKey Laboratory of In-Situ Property Improving Mining of Ministry of Education, Taiyuan University of Technology, Shanxi Taiyuan 030024, ChinaKey Laboratory of In-Situ Property Improving Mining of Ministry of Education, Taiyuan University of Technology, Shanxi Taiyuan 030024, ChinaDue to the complexity of the internal structure of natural coal and its characteristic of multicomponent, the depth of its methane adsorption potential well is nonuniform, which makes it difficult to accurately evaluate the adsorption capacity of coal. Besides, in order to find out the factors affecting the depth distribution of potential wells in natural coal, this paper calculated the depth and number of potential wells during methane adsorption in coal according to the Langmuir adsorption kinetics process. Coal samples with different metamorphic degrees were tested and analyzed by infrared spectroscopy diffraction technology. The relationship between the structural parameters of functional groups in coal samples with different metamorphic degrees and the distribution of different depths of adsorption potential wells in coal samples was studied. Some main conclusions are as follows: The number of adsorption potential wells at different depths in natural coal with different metamorphic degrees has multipeak distribution characteristics. With the increase of the metamorphic degree of coal sample, the structures such as aliphatic branched chain structure and oxygen-containing functional groups in coal structure break, fall off, and deoxygenate. The relative content of aliphatic hydrocarbons is significantly reduced and condensed into aromatic hydrocarbons and aromatic ring structures. The different types and quantities of functional groups on the surface of coal samples lead to different forces between coal molecules and methane gas molecules, thus affecting the distribution of different depths of adsorption potential wells in coal samples.http://dx.doi.org/10.1155/2021/3820762 |
| spellingShingle | Chen Wang Zengchao Feng Xing Wang Effect of Functional Groups in Coal on the Depth of Adsorption Potential Well Adsorption Science & Technology |
| title | Effect of Functional Groups in Coal on the Depth of Adsorption Potential Well |
| title_full | Effect of Functional Groups in Coal on the Depth of Adsorption Potential Well |
| title_fullStr | Effect of Functional Groups in Coal on the Depth of Adsorption Potential Well |
| title_full_unstemmed | Effect of Functional Groups in Coal on the Depth of Adsorption Potential Well |
| title_short | Effect of Functional Groups in Coal on the Depth of Adsorption Potential Well |
| title_sort | effect of functional groups in coal on the depth of adsorption potential well |
| url | http://dx.doi.org/10.1155/2021/3820762 |
| work_keys_str_mv | AT chenwang effectoffunctionalgroupsincoalonthedepthofadsorptionpotentialwell AT zengchaofeng effectoffunctionalgroupsincoalonthedepthofadsorptionpotentialwell AT xingwang effectoffunctionalgroupsincoalonthedepthofadsorptionpotentialwell |