A Novel Method for Preparation of Zn-Doped CuInS2 Solar Cells and Their Photovoltaic Performance

In this study, a novel method was proposed to synthesize high quality Zn-doped CuInS2 nanocrystals under high frequency magnetic field at ambient conditions. The magnetic Zn-doping gave superparamagnetic heating of the resulting nanocrystals via magnetic induction, causing an accelerating growth rat...

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Main Authors: Cheng-Hsiung Peng, Chyi-Ching Hwang
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1155/2013/798713
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author Cheng-Hsiung Peng
Chyi-Ching Hwang
author_facet Cheng-Hsiung Peng
Chyi-Ching Hwang
author_sort Cheng-Hsiung Peng
collection DOAJ
description In this study, a novel method was proposed to synthesize high quality Zn-doped CuInS2 nanocrystals under high frequency magnetic field at ambient conditions. The magnetic Zn-doping gave superparamagnetic heating of the resulting nanocrystals via magnetic induction, causing an accelerating growth rate of the doped CuInS2 under ambient conditions faster than conventional autoclave synthesis. Shape evolution of the Zn-doped CuInS2 nanocrystals from initially spherical to pyramidal, to cubic, and finally to a bar geometry was detected as a function of time of exposure to magnetic induction. These colloidal solvents with different shaped nanocrystals were further used as “nanoink” to fabricate a simple thin film solar device; the best efficiency we obtained of these crystals was 1.01% with a 1.012 μm thickness absorber layer (bar geometry). The efficiency could be promoted to 1.44% after the absorber was thickened to 2.132 μm.
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publisher Wiley
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series The Scientific World Journal
spelling doaj-art-20d6e98c05c34791893ba83431ebf0862025-02-03T05:43:38ZengWileyThe Scientific World Journal1537-744X2013-01-01201310.1155/2013/798713798713A Novel Method for Preparation of Zn-Doped CuInS2 Solar Cells and Their Photovoltaic PerformanceCheng-Hsiung Peng0Chyi-Ching Hwang1Department of Chemical and Materials Engineering, Minghsin University of Science and Technology, Hsinfeng, Hsinchu 304, TaiwanWeapon System Center, Chung Cheng Institute of Technology, NDU, Daxi, Taoyuan 335, TaiwanIn this study, a novel method was proposed to synthesize high quality Zn-doped CuInS2 nanocrystals under high frequency magnetic field at ambient conditions. The magnetic Zn-doping gave superparamagnetic heating of the resulting nanocrystals via magnetic induction, causing an accelerating growth rate of the doped CuInS2 under ambient conditions faster than conventional autoclave synthesis. Shape evolution of the Zn-doped CuInS2 nanocrystals from initially spherical to pyramidal, to cubic, and finally to a bar geometry was detected as a function of time of exposure to magnetic induction. These colloidal solvents with different shaped nanocrystals were further used as “nanoink” to fabricate a simple thin film solar device; the best efficiency we obtained of these crystals was 1.01% with a 1.012 μm thickness absorber layer (bar geometry). The efficiency could be promoted to 1.44% after the absorber was thickened to 2.132 μm.http://dx.doi.org/10.1155/2013/798713
spellingShingle Cheng-Hsiung Peng
Chyi-Ching Hwang
A Novel Method for Preparation of Zn-Doped CuInS2 Solar Cells and Their Photovoltaic Performance
The Scientific World Journal
title A Novel Method for Preparation of Zn-Doped CuInS2 Solar Cells and Their Photovoltaic Performance
title_full A Novel Method for Preparation of Zn-Doped CuInS2 Solar Cells and Their Photovoltaic Performance
title_fullStr A Novel Method for Preparation of Zn-Doped CuInS2 Solar Cells and Their Photovoltaic Performance
title_full_unstemmed A Novel Method for Preparation of Zn-Doped CuInS2 Solar Cells and Their Photovoltaic Performance
title_short A Novel Method for Preparation of Zn-Doped CuInS2 Solar Cells and Their Photovoltaic Performance
title_sort novel method for preparation of zn doped cuins2 solar cells and their photovoltaic performance
url http://dx.doi.org/10.1155/2013/798713
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