trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II)
The title compound, [Fe(C8H3N4O)2(C9H8N2)2], was synthesized solvothermally. The complex exhibits a distorted octahedral coordination geometry. The Fe2+ ion is located on an inversion centre. The octahedral FeN6 coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites w...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2024-12-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | https://journals.iucr.org/paper?S2414314624012197 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1841557889774256128 |
|---|---|
| author | Fatima Setifi Zouaoui Setifi Uwe Böhme Mohammad Hadi Al-Douh Achouak Satour |
| author_facet | Fatima Setifi Zouaoui Setifi Uwe Böhme Mohammad Hadi Al-Douh Achouak Satour |
| author_sort | Fatima Setifi |
| collection | DOAJ |
| description | The title compound, [Fe(C8H3N4O)2(C9H8N2)2], was synthesized solvothermally. The complex exhibits a distorted octahedral coordination geometry. The Fe2+ ion is located on an inversion centre. The octahedral FeN6 coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetracyano-2-methoxypropenide anions. The crystal structure features hydrogen bonds parallel to the crystallographic b axis and parallel to (110). |
| format | Article |
| id | doaj-art-2005df2ba4e64eb2b4bbc2d52def110f |
| institution | Kabale University |
| issn | 2414-3146 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj-art-2005df2ba4e64eb2b4bbc2d52def110f2025-01-06T09:23:34ZengInternational Union of CrystallographyIUCrData2414-31462024-12-01912x24121910.1107/S2414314624012197zl4078trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II)Fatima Setifi0Zouaoui Setifi1Uwe Böhme2Mohammad Hadi Al-Douh3Achouak Satour4Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, AlgeriaLaboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, AlgeriaInstitut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyChemistry Department, Faculty of Science, Hadhramout University, Mukalla, Hadhramout, YemenLaboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, AlgeriaThe title compound, [Fe(C8H3N4O)2(C9H8N2)2], was synthesized solvothermally. The complex exhibits a distorted octahedral coordination geometry. The Fe2+ ion is located on an inversion centre. The octahedral FeN6 coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetracyano-2-methoxypropenide anions. The crystal structure features hydrogen bonds parallel to the crystallographic b axis and parallel to (110).https://journals.iucr.org/paper?S2414314624012197crystal structureiron(ii) complexquinoline-8-amine1,1,3,3-tetracyano-2-methoxypropenide |
| spellingShingle | Fatima Setifi Zouaoui Setifi Uwe Böhme Mohammad Hadi Al-Douh Achouak Satour trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II) IUCrData crystal structure iron(ii) complex quinoline-8-amine 1,1,3,3-tetracyano-2-methoxypropenide |
| title | trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II) |
| title_full | trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II) |
| title_fullStr | trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II) |
| title_full_unstemmed | trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II) |
| title_short | trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II) |
| title_sort | trans bis quinoline 8 amine κ2n n bis 1 1 3 3 tetracyano 2 methoxypropenido κn iron ii |
| topic | crystal structure iron(ii) complex quinoline-8-amine 1,1,3,3-tetracyano-2-methoxypropenide |
| url | https://journals.iucr.org/paper?S2414314624012197 |
| work_keys_str_mv | AT fatimasetifi transbisquinoline8aminek2nnbis1133tetracyano2methoxypropenidoknironii AT zouaouisetifi transbisquinoline8aminek2nnbis1133tetracyano2methoxypropenidoknironii AT uwebohme transbisquinoline8aminek2nnbis1133tetracyano2methoxypropenidoknironii AT mohammadhadialdouh transbisquinoline8aminek2nnbis1133tetracyano2methoxypropenidoknironii AT achouaksatour transbisquinoline8aminek2nnbis1133tetracyano2methoxypropenidoknironii |