trans-Bis(quinoline-8-amine-κ2N,N′)bis(1,1,3,3-tetracyano-2-methoxypropenido-κN)iron(II)

The title compound, [Fe(C8H3N4O)2(C9H8N2)2], was synthesized solvothermally. The complex exhibits a distorted octahedral coordination geometry. The Fe2+ ion is located on an inversion centre. The octahedral FeN6 coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites w...

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Bibliographic Details
Main Authors: Fatima Setifi, Zouaoui Setifi, Uwe Böhme, Mohammad Hadi Al-Douh, Achouak Satour
Format: Article
Language:English
Published: International Union of Crystallography 2024-12-01
Series:IUCrData
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Online Access:https://journals.iucr.org/paper?S2414314624012197
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Summary:The title compound, [Fe(C8H3N4O)2(C9H8N2)2], was synthesized solvothermally. The complex exhibits a distorted octahedral coordination geometry. The Fe2+ ion is located on an inversion centre. The octahedral FeN6 coordination sphere is composed of bidentate quinoline-8-amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetracyano-2-methoxypropenide anions. The crystal structure features hydrogen bonds parallel to the crystallographic b axis and parallel to (110).
ISSN:2414-3146