Adsorption Isotherms of Caffeine and Theophylline on Metal-Organic Frameworks

The adsorption behaviours of caffeine and theophylline on different metal-organic frameworks were examined by comparing their adsorption isotherms. Among C 18 , UIO-66, UIO-66-NH 2 and MIL-125-NH 2 , UIO-66 showed the highest amount of adsorption of target compounds (i.e. caffeine and theophylline)....

Full description

Saved in:
Bibliographic Details
Main Authors: Yu Ri Lee, Minglei Tian, Se-Na Kim, Wha-Seung Ahn, Kyung Ho Row
Format: Article
Language:English
Published: SAGE Publishing 2014-09-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.32.9.725
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1841564445449388032
author Yu Ri Lee
Minglei Tian
Se-Na Kim
Wha-Seung Ahn
Kyung Ho Row
author_facet Yu Ri Lee
Minglei Tian
Se-Na Kim
Wha-Seung Ahn
Kyung Ho Row
author_sort Yu Ri Lee
collection DOAJ
description The adsorption behaviours of caffeine and theophylline on different metal-organic frameworks were examined by comparing their adsorption isotherms. Among C 18 , UIO-66, UIO-66-NH 2 and MIL-125-NH 2 , UIO-66 showed the highest amount of adsorption of target compounds (i.e. caffeine and theophylline). The maximum adsorbed amounts of caffeine and theophylline on UIO-66 were 0.451 and 0.392 mg, respectively. The experimental parameters in the equilibrium isotherms were estimated by linear and non-linear regression analyses. The adsorption equilibrium data of caffeine and theophylline were investigated using the following four models: linear, Langmuir, Freundlich and Langmuir–Freundlich models. Of these models, the Langmuir–Freundlich model showed the best fit. The regression coefficients (r 2 ) of the Langmuir–Freundlich model for adsorption of caffeine and theophylline on UIO-66 were 0.976 and 0.989, respectively.
format Article
id doaj-art-1e79c417c83d47f2af7786577bdb7afa
institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2014-09-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-1e79c417c83d47f2af7786577bdb7afa2025-01-02T22:38:05ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382014-09-013210.1260/0263-6174.32.9.725Adsorption Isotherms of Caffeine and Theophylline on Metal-Organic FrameworksYu Ri LeeMinglei TianSe-Na KimWha-Seung AhnKyung Ho RowThe adsorption behaviours of caffeine and theophylline on different metal-organic frameworks were examined by comparing their adsorption isotherms. Among C 18 , UIO-66, UIO-66-NH 2 and MIL-125-NH 2 , UIO-66 showed the highest amount of adsorption of target compounds (i.e. caffeine and theophylline). The maximum adsorbed amounts of caffeine and theophylline on UIO-66 were 0.451 and 0.392 mg, respectively. The experimental parameters in the equilibrium isotherms were estimated by linear and non-linear regression analyses. The adsorption equilibrium data of caffeine and theophylline were investigated using the following four models: linear, Langmuir, Freundlich and Langmuir–Freundlich models. Of these models, the Langmuir–Freundlich model showed the best fit. The regression coefficients (r 2 ) of the Langmuir–Freundlich model for adsorption of caffeine and theophylline on UIO-66 were 0.976 and 0.989, respectively.https://doi.org/10.1260/0263-6174.32.9.725
spellingShingle Yu Ri Lee
Minglei Tian
Se-Na Kim
Wha-Seung Ahn
Kyung Ho Row
Adsorption Isotherms of Caffeine and Theophylline on Metal-Organic Frameworks
Adsorption Science & Technology
title Adsorption Isotherms of Caffeine and Theophylline on Metal-Organic Frameworks
title_full Adsorption Isotherms of Caffeine and Theophylline on Metal-Organic Frameworks
title_fullStr Adsorption Isotherms of Caffeine and Theophylline on Metal-Organic Frameworks
title_full_unstemmed Adsorption Isotherms of Caffeine and Theophylline on Metal-Organic Frameworks
title_short Adsorption Isotherms of Caffeine and Theophylline on Metal-Organic Frameworks
title_sort adsorption isotherms of caffeine and theophylline on metal organic frameworks
url https://doi.org/10.1260/0263-6174.32.9.725
work_keys_str_mv AT yurilee adsorptionisothermsofcaffeineandtheophyllineonmetalorganicframeworks
AT mingleitian adsorptionisothermsofcaffeineandtheophyllineonmetalorganicframeworks
AT senakim adsorptionisothermsofcaffeineandtheophyllineonmetalorganicframeworks
AT whaseungahn adsorptionisothermsofcaffeineandtheophyllineonmetalorganicframeworks
AT kyunghorow adsorptionisothermsofcaffeineandtheophyllineonmetalorganicframeworks