Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance

The purpose of this research is to develop a sustainable and organic energy storage system from oil palm lignin waste-derived Laser Scribed Graphene embedded with molybdenum disulfide (LSG/MoS2). In this study, LSG/MoS2 hybrids were fabricated to overcome the graphene zero band gap, restacking issue...

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Main Authors: Mugashini Vasudevan, Aiswarya Kanesan, Sathaniswarman Remesh, Veeradasan Perumal, Pandian Raja, Mohamad Nasir Mohamad Ibrahim, Saravanan Karuppanan, Subash Gopinath, Mark Ovinis
Format: Article
Language:English
Published: Iranian Environmental Mutagen Society 2023-06-01
Series:Journal of Water and Environmental Nanotechnology
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Online Access:https://www.jwent.net/article_705281_6a09c52633d7edd301a5a5e0d39c4c3a.pdf
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author Mugashini Vasudevan
Aiswarya Kanesan
Sathaniswarman Remesh
Veeradasan Perumal
Pandian Raja
Mohamad Nasir Mohamad Ibrahim
Saravanan Karuppanan
Subash Gopinath
Mark Ovinis
author_facet Mugashini Vasudevan
Aiswarya Kanesan
Sathaniswarman Remesh
Veeradasan Perumal
Pandian Raja
Mohamad Nasir Mohamad Ibrahim
Saravanan Karuppanan
Subash Gopinath
Mark Ovinis
author_sort Mugashini Vasudevan
collection DOAJ
description The purpose of this research is to develop a sustainable and organic energy storage system from oil palm lignin waste-derived Laser Scribed Graphene embedded with molybdenum disulfide (LSG/MoS2). In this study, LSG/MoS2 hybrids were fabricated to overcome the graphene zero band gap, restacking issues of molybdenum disulfide and to induce the electrical conductivity. Therefore, various amounts of LSG (0.1,0.5,1.0 g) were added in MoS2 precursor to produce nanoscale LSG/MoS2 hybrid nanostructure via the hydrothermal method. To justify the findings of LSG/MoS2 hybrid nanostructures, Raman spectroscopy, FESEM, TEM, and XRD were conducted. The D, G and 2D bands found in LSG confirm the formation of graphene from lignin. The morphology of LSG/MoS2 hybrids is porous and has a large surface area anchored with 3D MoS2 nanoflower on LSG. TEM has proved that LSG was wrapped with MoS2, where the presence of lattice spacing of 0.62 and 0.27nm, which corresponded to the (002) and (100) planes of MoS2 was observed. The electrochemical performance of the hybrids was conducted through Electrochemical Impedance Spectroscopy (EIS) demonstrated that increment in LSG in MoS2 precursor effects the impedance and resistances performances.
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institution Kabale University
issn 2476-7204
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publishDate 2023-06-01
publisher Iranian Environmental Mutagen Society
record_format Article
series Journal of Water and Environmental Nanotechnology
spelling doaj-art-1c28c77bba774b198089d59ab774e6bf2025-01-12T09:33:54ZengIranian Environmental Mutagen SocietyJournal of Water and Environmental Nanotechnology2476-72042476-66152023-06-018213715010.22090/jwent.2023.02.004705281Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performanceMugashini Vasudevan0Aiswarya Kanesan1Sathaniswarman Remesh2Veeradasan Perumal3Pandian Raja4Mohamad Nasir Mohamad Ibrahim5Saravanan Karuppanan6Subash Gopinath7Mark Ovinis8Centre of Innovative Nanostructures and Nanodevices (COINN), Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaDepartment of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaCentre of Innovative Nanostructures and Nanodevices (COINN), Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaCentre of Innovative Nanostructures and Nanodevices (COINN), Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaSchool of Chemical Sciences, Universiti Sains Malaysia, 11800, Penang, MalaysiaSchool of Chemical Sciences, Universiti Sains Malaysia, 11800, Penang, MalaysiaDepartment of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaInstitute of Nano Electronic Engineering, Kangar 01000 & Faculty of Chemical Engineering & Technology, Arau 02600, Universiti Malaysia Perlis (UniMAP), Perlis, MalaysiaSchool of Engineering and the Built Environment, Faculty of Computing, Engineering, and the Built Environment, Birmingham City University, B4 7XG, UKThe purpose of this research is to develop a sustainable and organic energy storage system from oil palm lignin waste-derived Laser Scribed Graphene embedded with molybdenum disulfide (LSG/MoS2). In this study, LSG/MoS2 hybrids were fabricated to overcome the graphene zero band gap, restacking issues of molybdenum disulfide and to induce the electrical conductivity. Therefore, various amounts of LSG (0.1,0.5,1.0 g) were added in MoS2 precursor to produce nanoscale LSG/MoS2 hybrid nanostructure via the hydrothermal method. To justify the findings of LSG/MoS2 hybrid nanostructures, Raman spectroscopy, FESEM, TEM, and XRD were conducted. The D, G and 2D bands found in LSG confirm the formation of graphene from lignin. The morphology of LSG/MoS2 hybrids is porous and has a large surface area anchored with 3D MoS2 nanoflower on LSG. TEM has proved that LSG was wrapped with MoS2, where the presence of lattice spacing of 0.62 and 0.27nm, which corresponded to the (002) and (100) planes of MoS2 was observed. The electrochemical performance of the hybrids was conducted through Electrochemical Impedance Spectroscopy (EIS) demonstrated that increment in LSG in MoS2 precursor effects the impedance and resistances performances.https://www.jwent.net/article_705281_6a09c52633d7edd301a5a5e0d39c4c3a.pdfoil palm ligninmolybdenum disulfidemorphologicalstructuralsupercapacitor
spellingShingle Mugashini Vasudevan
Aiswarya Kanesan
Sathaniswarman Remesh
Veeradasan Perumal
Pandian Raja
Mohamad Nasir Mohamad Ibrahim
Saravanan Karuppanan
Subash Gopinath
Mark Ovinis
Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance
Journal of Water and Environmental Nanotechnology
oil palm lignin
molybdenum disulfide
morphological
structural
supercapacitor
title Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance
title_full Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance
title_fullStr Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance
title_full_unstemmed Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance
title_short Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance
title_sort characterizations of synthesized laser scribed graphene molybdenum disulfide lsg mos2 hybrids for supercapacitor performance
topic oil palm lignin
molybdenum disulfide
morphological
structural
supercapacitor
url https://www.jwent.net/article_705281_6a09c52633d7edd301a5a5e0d39c4c3a.pdf
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