Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance
The purpose of this research is to develop a sustainable and organic energy storage system from oil palm lignin waste-derived Laser Scribed Graphene embedded with molybdenum disulfide (LSG/MoS2). In this study, LSG/MoS2 hybrids were fabricated to overcome the graphene zero band gap, restacking issue...
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Iranian Environmental Mutagen Society
2023-06-01
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Series: | Journal of Water and Environmental Nanotechnology |
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Online Access: | https://www.jwent.net/article_705281_6a09c52633d7edd301a5a5e0d39c4c3a.pdf |
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author | Mugashini Vasudevan Aiswarya Kanesan Sathaniswarman Remesh Veeradasan Perumal Pandian Raja Mohamad Nasir Mohamad Ibrahim Saravanan Karuppanan Subash Gopinath Mark Ovinis |
author_facet | Mugashini Vasudevan Aiswarya Kanesan Sathaniswarman Remesh Veeradasan Perumal Pandian Raja Mohamad Nasir Mohamad Ibrahim Saravanan Karuppanan Subash Gopinath Mark Ovinis |
author_sort | Mugashini Vasudevan |
collection | DOAJ |
description | The purpose of this research is to develop a sustainable and organic energy storage system from oil palm lignin waste-derived Laser Scribed Graphene embedded with molybdenum disulfide (LSG/MoS2). In this study, LSG/MoS2 hybrids were fabricated to overcome the graphene zero band gap, restacking issues of molybdenum disulfide and to induce the electrical conductivity. Therefore, various amounts of LSG (0.1,0.5,1.0 g) were added in MoS2 precursor to produce nanoscale LSG/MoS2 hybrid nanostructure via the hydrothermal method. To justify the findings of LSG/MoS2 hybrid nanostructures, Raman spectroscopy, FESEM, TEM, and XRD were conducted. The D, G and 2D bands found in LSG confirm the formation of graphene from lignin. The morphology of LSG/MoS2 hybrids is porous and has a large surface area anchored with 3D MoS2 nanoflower on LSG. TEM has proved that LSG was wrapped with MoS2, where the presence of lattice spacing of 0.62 and 0.27nm, which corresponded to the (002) and (100) planes of MoS2 was observed. The electrochemical performance of the hybrids was conducted through Electrochemical Impedance Spectroscopy (EIS) demonstrated that increment in LSG in MoS2 precursor effects the impedance and resistances performances. |
format | Article |
id | doaj-art-1c28c77bba774b198089d59ab774e6bf |
institution | Kabale University |
issn | 2476-7204 2476-6615 |
language | English |
publishDate | 2023-06-01 |
publisher | Iranian Environmental Mutagen Society |
record_format | Article |
series | Journal of Water and Environmental Nanotechnology |
spelling | doaj-art-1c28c77bba774b198089d59ab774e6bf2025-01-12T09:33:54ZengIranian Environmental Mutagen SocietyJournal of Water and Environmental Nanotechnology2476-72042476-66152023-06-018213715010.22090/jwent.2023.02.004705281Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performanceMugashini Vasudevan0Aiswarya Kanesan1Sathaniswarman Remesh2Veeradasan Perumal3Pandian Raja4Mohamad Nasir Mohamad Ibrahim5Saravanan Karuppanan6Subash Gopinath7Mark Ovinis8Centre of Innovative Nanostructures and Nanodevices (COINN), Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaDepartment of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaCentre of Innovative Nanostructures and Nanodevices (COINN), Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaCentre of Innovative Nanostructures and Nanodevices (COINN), Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaSchool of Chemical Sciences, Universiti Sains Malaysia, 11800, Penang, MalaysiaSchool of Chemical Sciences, Universiti Sains Malaysia, 11800, Penang, MalaysiaDepartment of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610 Seri Iskandar, Perak Darul Ridzuan, MalaysiaInstitute of Nano Electronic Engineering, Kangar 01000 & Faculty of Chemical Engineering & Technology, Arau 02600, Universiti Malaysia Perlis (UniMAP), Perlis, MalaysiaSchool of Engineering and the Built Environment, Faculty of Computing, Engineering, and the Built Environment, Birmingham City University, B4 7XG, UKThe purpose of this research is to develop a sustainable and organic energy storage system from oil palm lignin waste-derived Laser Scribed Graphene embedded with molybdenum disulfide (LSG/MoS2). In this study, LSG/MoS2 hybrids were fabricated to overcome the graphene zero band gap, restacking issues of molybdenum disulfide and to induce the electrical conductivity. Therefore, various amounts of LSG (0.1,0.5,1.0 g) were added in MoS2 precursor to produce nanoscale LSG/MoS2 hybrid nanostructure via the hydrothermal method. To justify the findings of LSG/MoS2 hybrid nanostructures, Raman spectroscopy, FESEM, TEM, and XRD were conducted. The D, G and 2D bands found in LSG confirm the formation of graphene from lignin. The morphology of LSG/MoS2 hybrids is porous and has a large surface area anchored with 3D MoS2 nanoflower on LSG. TEM has proved that LSG was wrapped with MoS2, where the presence of lattice spacing of 0.62 and 0.27nm, which corresponded to the (002) and (100) planes of MoS2 was observed. The electrochemical performance of the hybrids was conducted through Electrochemical Impedance Spectroscopy (EIS) demonstrated that increment in LSG in MoS2 precursor effects the impedance and resistances performances.https://www.jwent.net/article_705281_6a09c52633d7edd301a5a5e0d39c4c3a.pdfoil palm ligninmolybdenum disulfidemorphologicalstructuralsupercapacitor |
spellingShingle | Mugashini Vasudevan Aiswarya Kanesan Sathaniswarman Remesh Veeradasan Perumal Pandian Raja Mohamad Nasir Mohamad Ibrahim Saravanan Karuppanan Subash Gopinath Mark Ovinis Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance Journal of Water and Environmental Nanotechnology oil palm lignin molybdenum disulfide morphological structural supercapacitor |
title | Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance |
title_full | Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance |
title_fullStr | Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance |
title_full_unstemmed | Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance |
title_short | Characterizations of synthesized laser scribed graphene/molybdenum disulfide (LSG/MoS2) hybrids for supercapacitor performance |
title_sort | characterizations of synthesized laser scribed graphene molybdenum disulfide lsg mos2 hybrids for supercapacitor performance |
topic | oil palm lignin molybdenum disulfide morphological structural supercapacitor |
url | https://www.jwent.net/article_705281_6a09c52633d7edd301a5a5e0d39c4c3a.pdf |
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