Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real Samples
A simple and selective method was developed for the determination of platinum(IV) with n-octylaniline in toluene. In present study, the use of n-octylaniline in toluene for the extraction of platinum(IV) from ascorbate media was carried out. The effect of various parameters, such as pH, equilibrium...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/103192 |
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| author | Ashwini P. Gaikwad Ganesh S. Kamble Sanjay S. Kolekar Mansing A. Anuse |
| author_facet | Ashwini P. Gaikwad Ganesh S. Kamble Sanjay S. Kolekar Mansing A. Anuse |
| author_sort | Ashwini P. Gaikwad |
| collection | DOAJ |
| description | A simple and selective method was developed for the determination of platinum(IV) with n-octylaniline in toluene. In present study, the use of n-octylaniline in toluene for the extraction of platinum(IV) from ascorbate media was carried out. The effect of various parameters, such as pH, equilibrium time, extractant concentration, and organic solvent on the extraction has been discussed. The back extraction of platinum(IV) has been performed. On the basis of slope analysis, the composition of the extracted species was determined as [RR′NH2+ Pt(Succinate)2−](org). The interfering effects of various cations and anions were also studied, and the selectivity of the method is enhanced by using suitable masking agents. The proposed method is rapid, reproducible and successfully applied for the determination of platinum(IV) in binary and synthetic mixtures. The separation of pt(IV) from other associated metals has been studied. Comparison of the results with those obtained using an atomic absorption spectrophotometer also tested the validity of the method. |
| format | Article |
| id | doaj-art-1b1aad2dfdce4d0b8cf0029bf9108b51 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-1b1aad2dfdce4d0b8cf0029bf9108b512025-08-20T03:54:24ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/103192103192Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real SamplesAshwini P. Gaikwad0Ganesh S. Kamble1Sanjay S. Kolekar2Mansing A. Anuse3Analytical Chemistry Laboratory, Department of Chemistry, Shivaji University, Kolhapur, Maharashtra 416 004, IndiaAnalytical Chemistry Laboratory, Department of Chemistry, Shivaji University, Kolhapur, Maharashtra 416 004, IndiaAnalytical Chemistry Laboratory, Department of Chemistry, Shivaji University, Kolhapur, Maharashtra 416 004, IndiaAnalytical Chemistry Laboratory, Department of Chemistry, Shivaji University, Kolhapur, Maharashtra 416 004, IndiaA simple and selective method was developed for the determination of platinum(IV) with n-octylaniline in toluene. In present study, the use of n-octylaniline in toluene for the extraction of platinum(IV) from ascorbate media was carried out. The effect of various parameters, such as pH, equilibrium time, extractant concentration, and organic solvent on the extraction has been discussed. The back extraction of platinum(IV) has been performed. On the basis of slope analysis, the composition of the extracted species was determined as [RR′NH2+ Pt(Succinate)2−](org). The interfering effects of various cations and anions were also studied, and the selectivity of the method is enhanced by using suitable masking agents. The proposed method is rapid, reproducible and successfully applied for the determination of platinum(IV) in binary and synthetic mixtures. The separation of pt(IV) from other associated metals has been studied. Comparison of the results with those obtained using an atomic absorption spectrophotometer also tested the validity of the method.http://dx.doi.org/10.1155/2013/103192 |
| spellingShingle | Ashwini P. Gaikwad Ganesh S. Kamble Sanjay S. Kolekar Mansing A. Anuse Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real Samples Journal of Chemistry |
| title | Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real Samples |
| title_full | Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real Samples |
| title_fullStr | Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real Samples |
| title_full_unstemmed | Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real Samples |
| title_short | Liquid Anion Exchange Chromatographic Extraction and Separation of Platinum(IV) with n-Octylaniline as a Metallurgical Reagent: Analysis of Real Samples |
| title_sort | liquid anion exchange chromatographic extraction and separation of platinum iv with n octylaniline as a metallurgical reagent analysis of real samples |
| url | http://dx.doi.org/10.1155/2013/103192 |
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