Accelerated TLPD bonding of reliable IMCs micro joints using Cu–8Ni substrate under thermal gradient: Experiments and theoretical calculations

With the rapid development of the third-generation semiconductor power device towards high density, high performance, miniaturization and high temperature resistance, it is now urgent to develop a transient liquid phase diffusion (TLPD) bonding method with short bonding time and high reliability. In...

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Main Authors: Yanqing Lai, Mingjie Wang, Donghui Zheng, Meiping Liu, Bao Chen, Jinmei Lv, Ning Zhao
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425000572
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author Yanqing Lai
Mingjie Wang
Donghui Zheng
Meiping Liu
Bao Chen
Jinmei Lv
Ning Zhao
author_facet Yanqing Lai
Mingjie Wang
Donghui Zheng
Meiping Liu
Bao Chen
Jinmei Lv
Ning Zhao
author_sort Yanqing Lai
collection DOAJ
description With the rapid development of the third-generation semiconductor power device towards high density, high performance, miniaturization and high temperature resistance, it is now urgent to develop a transient liquid phase diffusion (TLPD) bonding method with short bonding time and high reliability. In this study, a novel TLPD bonding method under thermal gradient (TG) with Cu–8Ni alloy as the substrate on the one side of Cu/Sn(40 μm)/Cu–8Ni micro joints was designed. Additionally, the microstructure, elemental characteristics, grain features and shear strengths of the bonded and aged micro joints were systematically investigated. The results indicated that the IMCs micro joints mainly consisted of fine and non-preferred orientation (Cu,Ni)6Sn5 grains could be successfully achieved after TLPD bonding under TG (TG-TLPD bonding) at 260 °C for only 9 min. The formed IMCs micro joints was mainly composed of fine (Cu,Ni)6Sn5 grains, which showed good heat-resistant abilities. Moreover, the shear strength of the formed IMCs micro joints was tested to be 58.69 MPa, which exhibited a slight reduction to 47.34 MPa following aging. Furthermore, the study of Ni-free Cu6Sn5 and Ni doped Cu6Sn5 crystals by theoretical analysis showed that the Young's, shear and bulk modulus of Ni doped Cu6Sn5 were slightly larger than those of Ni-free Cu6Sn5. Ni doping can promote the physical properties and crystal stability of Cu6Sn5 to a certain extent. The proposed Cu/solder/Cu–8Ni interconnection structure using TG-TLPD bonding was demonstrated to be a prospective approach, which drastically shorten bonding duration and obtained the IMCs micro joints with a good thermostability for advanced power device packaging.
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publishDate 2025-03-01
publisher Elsevier
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spelling doaj-art-1a6f67b9ec394f849ad009866f4be67f2025-01-15T04:11:41ZengElsevierJournal of Materials Research and Technology2238-78542025-03-0135545557Accelerated TLPD bonding of reliable IMCs micro joints using Cu–8Ni substrate under thermal gradient: Experiments and theoretical calculationsYanqing Lai0Mingjie Wang1Donghui Zheng2Meiping Liu3Bao Chen4Jinmei Lv5Ning Zhao6School of Intelligent Manufacturing, Huanghuai University, Zhumadian, 463000, China; Yunnan Tin New Material Co., LTD, Kunming, 650500, China; Corresponding author. School of Intelligent Manufacturing, Huanghuai University, Zhumadian, 463000, China.School of Intelligent Manufacturing, Huanghuai University, Zhumadian, 463000, ChinaSchool of Intelligent Manufacturing, Huanghuai University, Zhumadian, 463000, ChinaSchool of Intelligent Manufacturing, Huanghuai University, Zhumadian, 463000, ChinaSchool of Intelligent Manufacturing, Huanghuai University, Zhumadian, 463000, ChinaYunnan Tin New Material Co., LTD, Kunming, 650500, ChinaSchool of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, China; Corresponding author.With the rapid development of the third-generation semiconductor power device towards high density, high performance, miniaturization and high temperature resistance, it is now urgent to develop a transient liquid phase diffusion (TLPD) bonding method with short bonding time and high reliability. In this study, a novel TLPD bonding method under thermal gradient (TG) with Cu–8Ni alloy as the substrate on the one side of Cu/Sn(40 μm)/Cu–8Ni micro joints was designed. Additionally, the microstructure, elemental characteristics, grain features and shear strengths of the bonded and aged micro joints were systematically investigated. The results indicated that the IMCs micro joints mainly consisted of fine and non-preferred orientation (Cu,Ni)6Sn5 grains could be successfully achieved after TLPD bonding under TG (TG-TLPD bonding) at 260 °C for only 9 min. The formed IMCs micro joints was mainly composed of fine (Cu,Ni)6Sn5 grains, which showed good heat-resistant abilities. Moreover, the shear strength of the formed IMCs micro joints was tested to be 58.69 MPa, which exhibited a slight reduction to 47.34 MPa following aging. Furthermore, the study of Ni-free Cu6Sn5 and Ni doped Cu6Sn5 crystals by theoretical analysis showed that the Young's, shear and bulk modulus of Ni doped Cu6Sn5 were slightly larger than those of Ni-free Cu6Sn5. Ni doping can promote the physical properties and crystal stability of Cu6Sn5 to a certain extent. The proposed Cu/solder/Cu–8Ni interconnection structure using TG-TLPD bonding was demonstrated to be a prospective approach, which drastically shorten bonding duration and obtained the IMCs micro joints with a good thermostability for advanced power device packaging.http://www.sciencedirect.com/science/article/pii/S2238785425000572Power device packagingThermal gradientIntermetallic compoundsFirst-principles calculationsCu–Ni alloy
spellingShingle Yanqing Lai
Mingjie Wang
Donghui Zheng
Meiping Liu
Bao Chen
Jinmei Lv
Ning Zhao
Accelerated TLPD bonding of reliable IMCs micro joints using Cu–8Ni substrate under thermal gradient: Experiments and theoretical calculations
Journal of Materials Research and Technology
Power device packaging
Thermal gradient
Intermetallic compounds
First-principles calculations
Cu–Ni alloy
title Accelerated TLPD bonding of reliable IMCs micro joints using Cu–8Ni substrate under thermal gradient: Experiments and theoretical calculations
title_full Accelerated TLPD bonding of reliable IMCs micro joints using Cu–8Ni substrate under thermal gradient: Experiments and theoretical calculations
title_fullStr Accelerated TLPD bonding of reliable IMCs micro joints using Cu–8Ni substrate under thermal gradient: Experiments and theoretical calculations
title_full_unstemmed Accelerated TLPD bonding of reliable IMCs micro joints using Cu–8Ni substrate under thermal gradient: Experiments and theoretical calculations
title_short Accelerated TLPD bonding of reliable IMCs micro joints using Cu–8Ni substrate under thermal gradient: Experiments and theoretical calculations
title_sort accelerated tlpd bonding of reliable imcs micro joints using cu 8ni substrate under thermal gradient experiments and theoretical calculations
topic Power device packaging
Thermal gradient
Intermetallic compounds
First-principles calculations
Cu–Ni alloy
url http://www.sciencedirect.com/science/article/pii/S2238785425000572
work_keys_str_mv AT yanqinglai acceleratedtlpdbondingofreliableimcsmicrojointsusingcu8nisubstrateunderthermalgradientexperimentsandtheoreticalcalculations
AT mingjiewang acceleratedtlpdbondingofreliableimcsmicrojointsusingcu8nisubstrateunderthermalgradientexperimentsandtheoreticalcalculations
AT donghuizheng acceleratedtlpdbondingofreliableimcsmicrojointsusingcu8nisubstrateunderthermalgradientexperimentsandtheoreticalcalculations
AT meipingliu acceleratedtlpdbondingofreliableimcsmicrojointsusingcu8nisubstrateunderthermalgradientexperimentsandtheoreticalcalculations
AT baochen acceleratedtlpdbondingofreliableimcsmicrojointsusingcu8nisubstrateunderthermalgradientexperimentsandtheoreticalcalculations
AT jinmeilv acceleratedtlpdbondingofreliableimcsmicrojointsusingcu8nisubstrateunderthermalgradientexperimentsandtheoreticalcalculations
AT ningzhao acceleratedtlpdbondingofreliableimcsmicrojointsusingcu8nisubstrateunderthermalgradientexperimentsandtheoreticalcalculations