Temperature Dependence of the Isosteric Heat of Adsorption
Direct calorimetric measurements of the isosteric heats of adsorption of (a) pure CO 2 on a strongly heterogeneous adsorbent (silicalite with an alumina binder) and (b) pure N 2 on a mildly heterogeneous adsorbent (5A zeolite) at different temperatures and adsorbate loadings demonstrated the validit...
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| Format: | Article |
| Language: | English |
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SAGE Publishing
2001-12-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/0263617011494646 |
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| _version_ | 1841563122958073856 |
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| author | D.V. Cao S. Sircar |
| author_facet | D.V. Cao S. Sircar |
| author_sort | D.V. Cao |
| collection | DOAJ |
| description | Direct calorimetric measurements of the isosteric heats of adsorption of (a) pure CO 2 on a strongly heterogeneous adsorbent (silicalite with an alumina binder) and (b) pure N 2 on a mildly heterogeneous adsorbent (5A zeolite) at different temperatures and adsorbate loadings demonstrated the validity of the conventional assumption that isosteric heats are very weak functions of temperature. A simple thermodynamic model for the adsorption of a pure gas on an adsorbent containing two different energetic sites also validated the same assumption in the Henry's law region. |
| format | Article |
| id | doaj-art-1899d4453f1a47e6a001b6a90e74104b |
| institution | Kabale University |
| issn | 0263-6174 2048-4038 |
| language | English |
| publishDate | 2001-12-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj-art-1899d4453f1a47e6a001b6a90e74104b2025-01-03T00:11:13ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382001-12-011910.1260/0263617011494646Temperature Dependence of the Isosteric Heat of AdsorptionD.V. CaoS. SircarDirect calorimetric measurements of the isosteric heats of adsorption of (a) pure CO 2 on a strongly heterogeneous adsorbent (silicalite with an alumina binder) and (b) pure N 2 on a mildly heterogeneous adsorbent (5A zeolite) at different temperatures and adsorbate loadings demonstrated the validity of the conventional assumption that isosteric heats are very weak functions of temperature. A simple thermodynamic model for the adsorption of a pure gas on an adsorbent containing two different energetic sites also validated the same assumption in the Henry's law region.https://doi.org/10.1260/0263617011494646 |
| spellingShingle | D.V. Cao S. Sircar Temperature Dependence of the Isosteric Heat of Adsorption Adsorption Science & Technology |
| title | Temperature Dependence of the Isosteric Heat of Adsorption |
| title_full | Temperature Dependence of the Isosteric Heat of Adsorption |
| title_fullStr | Temperature Dependence of the Isosteric Heat of Adsorption |
| title_full_unstemmed | Temperature Dependence of the Isosteric Heat of Adsorption |
| title_short | Temperature Dependence of the Isosteric Heat of Adsorption |
| title_sort | temperature dependence of the isosteric heat of adsorption |
| url | https://doi.org/10.1260/0263617011494646 |
| work_keys_str_mv | AT dvcao temperaturedependenceoftheisostericheatofadsorption AT ssircar temperaturedependenceoftheisostericheatofadsorption |