Medium temperature sintered BaTiO3-based ceramics for X8R capacitors
The development of X8R BaTiO3-based dielectric materials is of great significance for the high-temperature application of MLCCs. Herein, a series of BaTiO3-based dielectric ceramics were prepared by the conventional solid-state method, and the effects of Bi4Ti3O12 and Mn3O4 on the properties of BaTi...
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Elsevier
2025-01-01
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Series: | Journal of Materiomics |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S235284782400039X |
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author | Xinyue Zhang Junlei Qi Yiqian Liu Jinghan Cai Yuan-hua Lin |
author_facet | Xinyue Zhang Junlei Qi Yiqian Liu Jinghan Cai Yuan-hua Lin |
author_sort | Xinyue Zhang |
collection | DOAJ |
description | The development of X8R BaTiO3-based dielectric materials is of great significance for the high-temperature application of MLCCs. Herein, a series of BaTiO3-based dielectric ceramics were prepared by the conventional solid-state method, and the effects of Bi4Ti3O12 and Mn3O4 on the properties of BaTiO3-based dielectric ceramics were studied. The SEM images show that the addition of Bi4Ti3O12 with a low melting point can densify the ceramics at a lower sintering temperature (1,150 °C). TEM images and EDS results indicate that the samples have a “core-shell” structure, which can be optimized by Bi4Ti3O12, resulting in phase transition dispersion and thus improving the temperature stability of the material. The addition of Mn can reduce the dielectric loss of ceramics at high temperatures. As a result, the optimal composition exhibits a high permittivity of 2,090, a low dielectric loss of 1.1%, and high temperature stability satisfying the X8R specification. |
format | Article |
id | doaj-art-1529d7f753e040db868e0d065f657f4a |
institution | Kabale University |
issn | 2352-8478 |
language | English |
publishDate | 2025-01-01 |
publisher | Elsevier |
record_format | Article |
series | Journal of Materiomics |
spelling | doaj-art-1529d7f753e040db868e0d065f657f4a2025-01-04T04:56:34ZengElsevierJournal of Materiomics2352-84782025-01-01111100845Medium temperature sintered BaTiO3-based ceramics for X8R capacitorsXinyue Zhang0Junlei Qi1Yiqian Liu2Jinghan Cai3Yuan-hua Lin4State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, ChinaState Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China; Innovation Team for New High Volumetric Efficient MLCC Materials and Devices, Foshan (Southern China) Institute for New Materials, Foshan, 528000, Guangdong, ChinaState Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, ChinaState Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, ChinaState Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China; Corresponding author.The development of X8R BaTiO3-based dielectric materials is of great significance for the high-temperature application of MLCCs. Herein, a series of BaTiO3-based dielectric ceramics were prepared by the conventional solid-state method, and the effects of Bi4Ti3O12 and Mn3O4 on the properties of BaTiO3-based dielectric ceramics were studied. The SEM images show that the addition of Bi4Ti3O12 with a low melting point can densify the ceramics at a lower sintering temperature (1,150 °C). TEM images and EDS results indicate that the samples have a “core-shell” structure, which can be optimized by Bi4Ti3O12, resulting in phase transition dispersion and thus improving the temperature stability of the material. The addition of Mn can reduce the dielectric loss of ceramics at high temperatures. As a result, the optimal composition exhibits a high permittivity of 2,090, a low dielectric loss of 1.1%, and high temperature stability satisfying the X8R specification.http://www.sciencedirect.com/science/article/pii/S235284782400039XBi4Ti3O12Core-shell structureDielectric propertiesX8R |
spellingShingle | Xinyue Zhang Junlei Qi Yiqian Liu Jinghan Cai Yuan-hua Lin Medium temperature sintered BaTiO3-based ceramics for X8R capacitors Journal of Materiomics Bi4Ti3O12 Core-shell structure Dielectric properties X8R |
title | Medium temperature sintered BaTiO3-based ceramics for X8R capacitors |
title_full | Medium temperature sintered BaTiO3-based ceramics for X8R capacitors |
title_fullStr | Medium temperature sintered BaTiO3-based ceramics for X8R capacitors |
title_full_unstemmed | Medium temperature sintered BaTiO3-based ceramics for X8R capacitors |
title_short | Medium temperature sintered BaTiO3-based ceramics for X8R capacitors |
title_sort | medium temperature sintered batio3 based ceramics for x8r capacitors |
topic | Bi4Ti3O12 Core-shell structure Dielectric properties X8R |
url | http://www.sciencedirect.com/science/article/pii/S235284782400039X |
work_keys_str_mv | AT xinyuezhang mediumtemperaturesinteredbatio3basedceramicsforx8rcapacitors AT junleiqi mediumtemperaturesinteredbatio3basedceramicsforx8rcapacitors AT yiqianliu mediumtemperaturesinteredbatio3basedceramicsforx8rcapacitors AT jinghancai mediumtemperaturesinteredbatio3basedceramicsforx8rcapacitors AT yuanhualin mediumtemperaturesinteredbatio3basedceramicsforx8rcapacitors |