Pt(II) and Pd(II) Complexes with 𝜷-Alanine
A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with 𝛽-aminopropionic acid (𝛽-alanine = 𝛽-AlaH) has been studied by the 195Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with 𝛽-alani...
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| Format: | Article |
| Language: | English |
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Wiley
2008-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2008/983725 |
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| author | L. F. Krylova L. M. Kovtunova G. V. Romanenko |
| author_facet | L. F. Krylova L. M. Kovtunova G. V. Romanenko |
| author_sort | L. F. Krylova |
| collection | DOAJ |
| description | A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with 𝛽-aminopropionic acid (𝛽-alanine = 𝛽-AlaH) has been studied by the 195Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with 𝛽-alanine as well as of the halide complexes of trans-[M(𝛽-AlaH)2Cl2] (M = Pt, Pd) and trans-K2[Pt(𝛽-Ala)2I2] types. The NMR spectroscopy and IR spectroscopy (in the nuclei of 195Pt,13C,1H) and X-ray diffraction analysis have been used to examine the structures of the synthesized compounds. |
| format | Article |
| id | doaj-art-14af4db17e164b4581e19bae8c8fb91c |
| institution | Kabale University |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2008-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-14af4db17e164b4581e19bae8c8fb91c2025-08-20T03:54:29ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2008-01-01200810.1155/2008/983725983725Pt(II) and Pd(II) Complexes with 𝜷-AlanineL. F. Krylova0L. M. Kovtunova1G. V. Romanenko2Novosibirsk State University, 2 Pirogova Street, Novosibirsk 630090, RussiaNovosibirsk State University, 2 Pirogova Street, Novosibirsk 630090, RussiaInternational Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a Institutskaya Street, Novosibirsk 630090, RussiaA sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with 𝛽-aminopropionic acid (𝛽-alanine = 𝛽-AlaH) has been studied by the 195Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with 𝛽-alanine as well as of the halide complexes of trans-[M(𝛽-AlaH)2Cl2] (M = Pt, Pd) and trans-K2[Pt(𝛽-Ala)2I2] types. The NMR spectroscopy and IR spectroscopy (in the nuclei of 195Pt,13C,1H) and X-ray diffraction analysis have been used to examine the structures of the synthesized compounds.http://dx.doi.org/10.1155/2008/983725 |
| spellingShingle | L. F. Krylova L. M. Kovtunova G. V. Romanenko Pt(II) and Pd(II) Complexes with 𝜷-Alanine Bioinorganic Chemistry and Applications |
| title | Pt(II) and Pd(II) Complexes with 𝜷-Alanine |
| title_full | Pt(II) and Pd(II) Complexes with 𝜷-Alanine |
| title_fullStr | Pt(II) and Pd(II) Complexes with 𝜷-Alanine |
| title_full_unstemmed | Pt(II) and Pd(II) Complexes with 𝜷-Alanine |
| title_short | Pt(II) and Pd(II) Complexes with 𝜷-Alanine |
| title_sort | pt ii and pd ii complexes with 𝜷 alanine |
| url | http://dx.doi.org/10.1155/2008/983725 |
| work_keys_str_mv | AT lfkrylova ptiiandpdiicomplexeswithβalanine AT lmkovtunova ptiiandpdiicomplexeswithβalanine AT gvromanenko ptiiandpdiicomplexeswithβalanine |