Pt(II) and Pd(II) Complexes with 𝜷-Alanine
A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with 𝛽-aminopropionic acid (𝛽-alanine = 𝛽-AlaH) has been studied by the 195Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with 𝛽-alani...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2008-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2008/983725 |
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| Summary: | A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with 𝛽-aminopropionic acid (𝛽-alanine = 𝛽-AlaH) has been studied by the 195Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cis- and trans-bischelates of Pt(II) and Pd(II) with 𝛽-alanine as well as of the halide complexes of trans-[M(𝛽-AlaH)2Cl2] (M = Pt, Pd) and trans-K2[Pt(𝛽-Ala)2I2] types. The NMR spectroscopy and IR spectroscopy (in the nuclei of 195Pt,13C,1H) and X-ray diffraction analysis have been used to examine the structures of the synthesized compounds. |
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| ISSN: | 1565-3633 1687-479X |