Progress in the Chemistry and Physics of the Organic Charge-Transfer Metals «TSeT∙Br0.5» and «TSeT∙Cl0.5»: Very High Electrical Conductivities under Pressure

On improved samples of the tetraselenotetracene derivatives TSeT∙Br0.5 and TSeT∙Cl0.5 we have obtained ρ(4K, 8kbar)/ρ(295K, 1bar) ratios of 1.3∙10-3 and 1.7∙10-3, respectively. This corresponds to a resistivity ρ(4K, 8kbar) of 5∙10-7 Ωcm for TSeT∙Br0.5 and 6.5∙10-7 Ωcm for TSeT∙Cl0.5. These are of...

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Bibliographic Details
Main Authors: Bruno Hilti, Carl W. Mayer, Ernst Minder, Kurt Hauenstein, Jürgen Pfeiffer, Marcel Rudin
Format: Article
Language:deu
Published: Swiss Chemical Society 1986-02-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9718
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Summary:On improved samples of the tetraselenotetracene derivatives TSeT∙Br0.5 and TSeT∙Cl0.5 we have obtained ρ(4K, 8kbar)/ρ(295K, 1bar) ratios of 1.3∙10-3 and 1.7∙10-3, respectively. This corresponds to a resistivity ρ(4K, 8kbar) of 5∙10-7 Ωcm for TSeT∙Br0.5 and 6.5∙10-7 Ωcm for TSeT∙Cl0.5. These are of the lowest non-superconductive resistivities ever observed in organic compounds.
ISSN:0009-4293
2673-2424