A Comparative Study of Copper and Zinc Ion Adsorption on to Activated and Non-activated Date-pits

Date-pits (an agricultural by-product available commercially) were utilized, with and without activation, as an adsorbent for the removal of Zn 2+ and Cu 2+ ions from aqueous solutions. Activated carbons were prepared from date-pits by carbon dioxide activation at 700°C. The effects of contact time,...

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Main Authors: Fawzi Banat, Sameer Al-Asheh, Deaa Al-Rousan
Format: Article
Language:English
Published: SAGE Publishing 2002-05-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/02636170260295515
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author Fawzi Banat
Sameer Al-Asheh
Deaa Al-Rousan
author_facet Fawzi Banat
Sameer Al-Asheh
Deaa Al-Rousan
author_sort Fawzi Banat
collection DOAJ
description Date-pits (an agricultural by-product available commercially) were utilized, with and without activation, as an adsorbent for the removal of Zn 2+ and Cu 2+ ions from aqueous solutions. Activated carbons were prepared from date-pits by carbon dioxide activation at 700°C. The effects of contact time, pH, temperature and the adsorbent concentration on the removal of Zn 2+ and Cu 2+ ions were studied. The Freundlich isotherm model described the equilibrium adsorption data. Non-activated date-pits exhibited higher Zn 2+ and Cu 2+ ion uptake than activated date-pits. The uptake of Cu 2+ ions by both activated and non-activated date-pits was higher than the uptake of Zn 2+ ions. The uptake of both metal ions increased on increasing the pH value of the system from 3.5 to 5.0 as well as on decreasing the temperature from 50°C to 25°C. Adsorption capacities for the non-activated date-pits towards Cu 2+ and Zn 2+ ions as high as 0.15 mmol/g and 0.09 mmol/g, respectively, were observed. This study demonstrated that date-pits without any physical or chemical pretreatment could be used as an effective adsorbent for the treatment of waters containing heavy metal ions such as Zn 2+ and Cu 2+ .
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series Adsorption Science & Technology
spelling doaj-art-11d09e2c38da4a78bc87b7dc2fdfc3722025-01-02T22:37:31ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382002-05-012010.1260/02636170260295515A Comparative Study of Copper and Zinc Ion Adsorption on to Activated and Non-activated Date-pitsFawzi BanatSameer Al-AshehDeaa Al-RousanDate-pits (an agricultural by-product available commercially) were utilized, with and without activation, as an adsorbent for the removal of Zn 2+ and Cu 2+ ions from aqueous solutions. Activated carbons were prepared from date-pits by carbon dioxide activation at 700°C. The effects of contact time, pH, temperature and the adsorbent concentration on the removal of Zn 2+ and Cu 2+ ions were studied. The Freundlich isotherm model described the equilibrium adsorption data. Non-activated date-pits exhibited higher Zn 2+ and Cu 2+ ion uptake than activated date-pits. The uptake of Cu 2+ ions by both activated and non-activated date-pits was higher than the uptake of Zn 2+ ions. The uptake of both metal ions increased on increasing the pH value of the system from 3.5 to 5.0 as well as on decreasing the temperature from 50°C to 25°C. Adsorption capacities for the non-activated date-pits towards Cu 2+ and Zn 2+ ions as high as 0.15 mmol/g and 0.09 mmol/g, respectively, were observed. This study demonstrated that date-pits without any physical or chemical pretreatment could be used as an effective adsorbent for the treatment of waters containing heavy metal ions such as Zn 2+ and Cu 2+ .https://doi.org/10.1260/02636170260295515
spellingShingle Fawzi Banat
Sameer Al-Asheh
Deaa Al-Rousan
A Comparative Study of Copper and Zinc Ion Adsorption on to Activated and Non-activated Date-pits
Adsorption Science & Technology
title A Comparative Study of Copper and Zinc Ion Adsorption on to Activated and Non-activated Date-pits
title_full A Comparative Study of Copper and Zinc Ion Adsorption on to Activated and Non-activated Date-pits
title_fullStr A Comparative Study of Copper and Zinc Ion Adsorption on to Activated and Non-activated Date-pits
title_full_unstemmed A Comparative Study of Copper and Zinc Ion Adsorption on to Activated and Non-activated Date-pits
title_short A Comparative Study of Copper and Zinc Ion Adsorption on to Activated and Non-activated Date-pits
title_sort comparative study of copper and zinc ion adsorption on to activated and non activated date pits
url https://doi.org/10.1260/02636170260295515
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