Utilization of Graphite Nanoparticles as a Hybrid Hole Transport Layer in Non-Fullerene Organic Solar Cells

This study investigates the impact of incorporating graphite nanoparticles (GNPs) into poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as hybrid hole transport layer (HTL) in non-fullerene organic solar cells (NF-OSCs) based on PBDB-T-2F:BTP-4CL. The concentration of GNPs in the...

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Main Authors: Magaly Ramirez-Como, Monica M. Valdez-Mata, Angel Sacramento, Jose L. Casas-Espinola, Luis Resendiz, Lluis F. Marsal
Format: Article
Language:English
Published: IEEE 2024-01-01
Series:IEEE Journal of the Electron Devices Society
Subjects:
Online Access:https://ieeexplore.ieee.org/document/10706788/
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author Magaly Ramirez-Como
Monica M. Valdez-Mata
Angel Sacramento
Jose L. Casas-Espinola
Luis Resendiz
Lluis F. Marsal
author_facet Magaly Ramirez-Como
Monica M. Valdez-Mata
Angel Sacramento
Jose L. Casas-Espinola
Luis Resendiz
Lluis F. Marsal
author_sort Magaly Ramirez-Como
collection DOAJ
description This study investigates the impact of incorporating graphite nanoparticles (GNPs) into poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as hybrid hole transport layer (HTL) in non-fullerene organic solar cells (NF-OSCs) based on PBDB-T-2F:BTP-4CL. The concentration of GNPs in the PEDOT:PSS layer was varied to investigate their impact on the overall device behavior. The PCE initially increased with the GNPs concentration up to 5% v/v, reaching a maximum enhancement of 6.43%, which was attributed to the increased JSC. Current-voltage measurements and Mott-Schottky analysis through capacitance-voltage characteristics were conducted to evaluate the behavior of the charge recombination and built-in potential due to the concentration variation of the GNPs into PEDOT:PSS. This study illustrates the potential of GNPs to improve OSC performance through enhanced light absorption, reduced recombination losses, and improved charge carrier transport, indicating promising prospects for GNPs on interface layers in OSCs.
format Article
id doaj-art-0e06232401e2419e8e6fd7bb5a9b2eed
institution Kabale University
issn 2168-6734
language English
publishDate 2024-01-01
publisher IEEE
record_format Article
series IEEE Journal of the Electron Devices Society
spelling doaj-art-0e06232401e2419e8e6fd7bb5a9b2eed2025-01-01T00:00:50ZengIEEEIEEE Journal of the Electron Devices Society2168-67342024-01-01121044105010.1109/JEDS.2024.347551310706788Utilization of Graphite Nanoparticles as a Hybrid Hole Transport Layer in Non-Fullerene Organic Solar CellsMagaly Ramirez-Como0https://orcid.org/0000-0002-9313-8337Monica M. Valdez-Mata1Angel Sacramento2https://orcid.org/0000-0001-5207-3154Jose L. Casas-Espinola3Luis Resendiz4https://orcid.org/0000-0002-6272-9003Lluis F. Marsal5https://orcid.org/0000-0002-5976-1408Sección de Estudios de Posgrado e Investigación, UPIITA, Instituto Politécnico Nacional, Mexico City, MexicoSección de Estudios de Posgrado e Investigación, UPIITA, Instituto Politécnico Nacional, Mexico City, MexicoDepartamento de Ingeniería Eléctrica, Sección de Electrónica del Estado Sólido, CINVESTAV-IPN, Mexico City, MexicoEscuela Superior de Física y Matemáticas, Instituto Politécnico Nacional, Mexico City, MexicoSección de Estudios de Posgrado e Investigación, UPIITA, Instituto Politécnico Nacional, Mexico City, MexicoDepartament d’Enginyeria Electronica Electrica i Automatica, Rovira i Virgili University, Tarragona, SpainThis study investigates the impact of incorporating graphite nanoparticles (GNPs) into poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as hybrid hole transport layer (HTL) in non-fullerene organic solar cells (NF-OSCs) based on PBDB-T-2F:BTP-4CL. The concentration of GNPs in the PEDOT:PSS layer was varied to investigate their impact on the overall device behavior. The PCE initially increased with the GNPs concentration up to 5% v/v, reaching a maximum enhancement of 6.43%, which was attributed to the increased JSC. Current-voltage measurements and Mott-Schottky analysis through capacitance-voltage characteristics were conducted to evaluate the behavior of the charge recombination and built-in potential due to the concentration variation of the GNPs into PEDOT:PSS. This study illustrates the potential of GNPs to improve OSC performance through enhanced light absorption, reduced recombination losses, and improved charge carrier transport, indicating promising prospects for GNPs on interface layers in OSCs.https://ieeexplore.ieee.org/document/10706788/Carbon dotscharge carrier recombination mechanismgraphite carbon nanoparticleshybrid hole transport layernon-fullerene solar cellsPEDOT:PSS dopants
spellingShingle Magaly Ramirez-Como
Monica M. Valdez-Mata
Angel Sacramento
Jose L. Casas-Espinola
Luis Resendiz
Lluis F. Marsal
Utilization of Graphite Nanoparticles as a Hybrid Hole Transport Layer in Non-Fullerene Organic Solar Cells
IEEE Journal of the Electron Devices Society
Carbon dots
charge carrier recombination mechanism
graphite carbon nanoparticles
hybrid hole transport layer
non-fullerene solar cells
PEDOT:PSS dopants
title Utilization of Graphite Nanoparticles as a Hybrid Hole Transport Layer in Non-Fullerene Organic Solar Cells
title_full Utilization of Graphite Nanoparticles as a Hybrid Hole Transport Layer in Non-Fullerene Organic Solar Cells
title_fullStr Utilization of Graphite Nanoparticles as a Hybrid Hole Transport Layer in Non-Fullerene Organic Solar Cells
title_full_unstemmed Utilization of Graphite Nanoparticles as a Hybrid Hole Transport Layer in Non-Fullerene Organic Solar Cells
title_short Utilization of Graphite Nanoparticles as a Hybrid Hole Transport Layer in Non-Fullerene Organic Solar Cells
title_sort utilization of graphite nanoparticles as a hybrid hole transport layer in non fullerene organic solar cells
topic Carbon dots
charge carrier recombination mechanism
graphite carbon nanoparticles
hybrid hole transport layer
non-fullerene solar cells
PEDOT:PSS dopants
url https://ieeexplore.ieee.org/document/10706788/
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