Modified Granular Activated Carbon: A Carrier for the Recovery of Nickel Ions from Aqueous Wastes

Granular Activated Carbon (GAC) is widely used for the removal and recovery of toxic pollutants including metals because of its low cost and high affinity towards the scavenging of metal ions. Activated carbon derived from bituminous coal is preferred for wastewater treatment due to its considerable...

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Main Authors: D. Satapathy, G.S. Natarajan, Raja Sen
Format: Article
Language:English
Published: SAGE Publishing 2004-05-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263617041514893
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author D. Satapathy
G.S. Natarajan
Raja Sen
author_facet D. Satapathy
G.S. Natarajan
Raja Sen
author_sort D. Satapathy
collection DOAJ
description Granular Activated Carbon (GAC) is widely used for the removal and recovery of toxic pollutants including metals because of its low cost and high affinity towards the scavenging of metal ions. Activated carbon derived from bituminous coal is preferred for wastewater treatment due to its considerable hardness, a characteristic needed to keep down handling losses during re-activation. Commercial grade carbon, viz. Filtrasorb (F-400), was used in the present work. The scavenging of precious metals such as nickel onto GAC was studied and a possible attempt made to recover the adsorbed Ni 2+ ions through the use of some suitable leaching processes. As part of the study, the role of complexing agents on the surface of the carbon was also investigated. The use of organic complexing agents such as oxine and 2-methyloxine in the recovery process was found to be promising. In addition, the surface of the carbon was modified with suitable oxidising agents that proved to be more effective than chelating agents. Several attempts were made to optimise the recovery of metal ions by carrying out experiments with oxidising agents in order to obtain maximum recovery from the minimum quantity of carbon. Experiments with nitric acid indicated that not only was the carbon surface modified but such modification also helped in carbon regeneration.
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spelling doaj-art-0dbc0ff3a10b4d20af713dbd716446c12025-01-02T22:37:09ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382004-05-012210.1260/0263617041514893Modified Granular Activated Carbon: A Carrier for the Recovery of Nickel Ions from Aqueous WastesD. SatapathyG.S. NatarajanRaja SenGranular Activated Carbon (GAC) is widely used for the removal and recovery of toxic pollutants including metals because of its low cost and high affinity towards the scavenging of metal ions. Activated carbon derived from bituminous coal is preferred for wastewater treatment due to its considerable hardness, a characteristic needed to keep down handling losses during re-activation. Commercial grade carbon, viz. Filtrasorb (F-400), was used in the present work. The scavenging of precious metals such as nickel onto GAC was studied and a possible attempt made to recover the adsorbed Ni 2+ ions through the use of some suitable leaching processes. As part of the study, the role of complexing agents on the surface of the carbon was also investigated. The use of organic complexing agents such as oxine and 2-methyloxine in the recovery process was found to be promising. In addition, the surface of the carbon was modified with suitable oxidising agents that proved to be more effective than chelating agents. Several attempts were made to optimise the recovery of metal ions by carrying out experiments with oxidising agents in order to obtain maximum recovery from the minimum quantity of carbon. Experiments with nitric acid indicated that not only was the carbon surface modified but such modification also helped in carbon regeneration.https://doi.org/10.1260/0263617041514893
spellingShingle D. Satapathy
G.S. Natarajan
Raja Sen
Modified Granular Activated Carbon: A Carrier for the Recovery of Nickel Ions from Aqueous Wastes
Adsorption Science & Technology
title Modified Granular Activated Carbon: A Carrier for the Recovery of Nickel Ions from Aqueous Wastes
title_full Modified Granular Activated Carbon: A Carrier for the Recovery of Nickel Ions from Aqueous Wastes
title_fullStr Modified Granular Activated Carbon: A Carrier for the Recovery of Nickel Ions from Aqueous Wastes
title_full_unstemmed Modified Granular Activated Carbon: A Carrier for the Recovery of Nickel Ions from Aqueous Wastes
title_short Modified Granular Activated Carbon: A Carrier for the Recovery of Nickel Ions from Aqueous Wastes
title_sort modified granular activated carbon a carrier for the recovery of nickel ions from aqueous wastes
url https://doi.org/10.1260/0263617041514893
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