Adsorption of As(III) Ions onto Iron-Containing Waste Sludge
The adsorption performance of a low-cost adsorbent (IS), viz. an iron-containing waste sludge arising during a hot-dip galvanizing process, towards the removal of As(III) ions from synthetic aqueous solutions and natural underground water was examined. The adsorption process was best described by th...
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Main Authors: | , , , , , |
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Format: | Article |
Language: | English |
Published: |
SAGE Publishing
2010-07-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/0263-6174.28.6.467 |
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Summary: | The adsorption performance of a low-cost adsorbent (IS), viz. an iron-containing waste sludge arising during a hot-dip galvanizing process, towards the removal of As(III) ions from synthetic aqueous solutions and natural underground water was examined. The adsorption process was best described by the pseudo-second-order kinetic equation. The equilibrium adsorption data were well described by the Langmuir model. The value of the dimensional separation factor, R L , indicated favourable adsorption. The maximum adsorption capacity of IS was 625 μg As(III)/g. The variation in the extent of adsorption with temperature was used to evaluate the thermodynamic parameters for the adsorption process. The values of ΔH 0 and ΔG 0 obtained demonstrated that the adsorption process was exothermic and spontaneous. The studied material exhibited an excellent As(III) ion adsorption performance from both synthetic solutions and a natural water sample. Moreover, no secondary contaminated substances arise if the exhausted adsorbent is recycled (e.g. in glass applications). |
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ISSN: | 0263-6174 2048-4038 |