A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins
The synthesis of new trans A2B2-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by H-N.M.R., C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxid...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2010-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2010/307696 |
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| Summary: | The synthesis of new trans A2B2-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are
described. All of the synthesized products were characterized by H-N.M.R., C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxidations and two reductions. In addition, the X-ray structure of one methoxy-derivative was determined. |
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| ISSN: | 1565-3633 1687-479X |