Local Electric Field-Incorporated In-Situ Copper Ions Eliminating Pathogens and Antibiotic Resistance Genes in Drinking Water

Background/Objectives: Pathogen inactivation and harmful gene destruction from water just before drinking is the last line of defense to protect people from waterborne diseases. However, commonly used disinfection methods, such as chlorination, ultraviolet irradiation, and membrane filtration, exper...

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Main Authors: Ruiqing Li, Haojie Dai, Wei Wang, Rulin Peng, Shenbo Yu, Xueying Zhang, Zheng-Yang Huo, Qingbin Yuan, Yi Luo
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Antibiotics
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Online Access:https://www.mdpi.com/2079-6382/13/12/1161
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author Ruiqing Li
Haojie Dai
Wei Wang
Rulin Peng
Shenbo Yu
Xueying Zhang
Zheng-Yang Huo
Qingbin Yuan
Yi Luo
author_facet Ruiqing Li
Haojie Dai
Wei Wang
Rulin Peng
Shenbo Yu
Xueying Zhang
Zheng-Yang Huo
Qingbin Yuan
Yi Luo
author_sort Ruiqing Li
collection DOAJ
description Background/Objectives: Pathogen inactivation and harmful gene destruction from water just before drinking is the last line of defense to protect people from waterborne diseases. However, commonly used disinfection methods, such as chlorination, ultraviolet irradiation, and membrane filtration, experience several challenges such as continuous chemical dosing, the spread of antibiotic resistance genes (ARGs), and intensive energy consumption. Methods: Here, we perform a simultaneous elimination of pathogens and ARGs in drinking water using local electric fields and in-situ generated trace copper ions (LEF-Cu) without external chemical dosing. A 100-μm thin copper wire placed in the center of a household water pipe can generate local electric fields and trace copper ions near its surface after an external low voltage is applied. Results: The local electric field rapidly damages the outer structure of microorganisms through electroporation, and the trace copper ions can effectively permeate the electroporated microorganisms, successfully damaging their nucleic acids. The LEF-Cu disinfection system achieved complete inactivation (>6 log removal) of <i>Escherichia coli</i> O157:H7, <i>Pseudomonas aeruginosa</i> PAO1, and bacteriophage MS2 in drinking water at 2 V for 2 min, with low energy consumption (10<sup>−2</sup> kWh/m<sup>3</sup>). Meanwhile, the system effectively damages both intracellular (0.54~0.64 log) and extracellular (0.5~1.09 log) ARGs and blocks horizontal gene transfer. Conclusions: LEF-Cu disinfection holds promise for preventing horizontal gene transfer and providing safe drinking water for household applications.
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institution Kabale University
issn 2079-6382
language English
publishDate 2024-12-01
publisher MDPI AG
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series Antibiotics
spelling doaj-art-01c85a775e6e4620a048d0924fdd7fde2024-12-27T14:06:13ZengMDPI AGAntibiotics2079-63822024-12-011312116110.3390/antibiotics13121161Local Electric Field-Incorporated In-Situ Copper Ions Eliminating Pathogens and Antibiotic Resistance Genes in Drinking WaterRuiqing Li0Haojie Dai1Wei Wang2Rulin Peng3Shenbo Yu4Xueying Zhang5Zheng-Yang Huo6Qingbin Yuan7Yi Luo8School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaState Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, ChinaSchool of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaSchool of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaSchool of Environment and Natural Resources, Renmin University of China, Beijing 100872, ChinaSchool of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaSchool of Chemistry and Life Resources, Renmin University of China, Beijing 100872, ChinaSchool of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaSchool of Environment and Natural Resources, Renmin University of China, Beijing 100872, ChinaBackground/Objectives: Pathogen inactivation and harmful gene destruction from water just before drinking is the last line of defense to protect people from waterborne diseases. However, commonly used disinfection methods, such as chlorination, ultraviolet irradiation, and membrane filtration, experience several challenges such as continuous chemical dosing, the spread of antibiotic resistance genes (ARGs), and intensive energy consumption. Methods: Here, we perform a simultaneous elimination of pathogens and ARGs in drinking water using local electric fields and in-situ generated trace copper ions (LEF-Cu) without external chemical dosing. A 100-μm thin copper wire placed in the center of a household water pipe can generate local electric fields and trace copper ions near its surface after an external low voltage is applied. Results: The local electric field rapidly damages the outer structure of microorganisms through electroporation, and the trace copper ions can effectively permeate the electroporated microorganisms, successfully damaging their nucleic acids. The LEF-Cu disinfection system achieved complete inactivation (>6 log removal) of <i>Escherichia coli</i> O157:H7, <i>Pseudomonas aeruginosa</i> PAO1, and bacteriophage MS2 in drinking water at 2 V for 2 min, with low energy consumption (10<sup>−2</sup> kWh/m<sup>3</sup>). Meanwhile, the system effectively damages both intracellular (0.54~0.64 log) and extracellular (0.5~1.09 log) ARGs and blocks horizontal gene transfer. Conclusions: LEF-Cu disinfection holds promise for preventing horizontal gene transfer and providing safe drinking water for household applications.https://www.mdpi.com/2079-6382/13/12/1161electroporationpathogensantibiotic resistance genescopper ions
spellingShingle Ruiqing Li
Haojie Dai
Wei Wang
Rulin Peng
Shenbo Yu
Xueying Zhang
Zheng-Yang Huo
Qingbin Yuan
Yi Luo
Local Electric Field-Incorporated In-Situ Copper Ions Eliminating Pathogens and Antibiotic Resistance Genes in Drinking Water
Antibiotics
electroporation
pathogens
antibiotic resistance genes
copper ions
title Local Electric Field-Incorporated In-Situ Copper Ions Eliminating Pathogens and Antibiotic Resistance Genes in Drinking Water
title_full Local Electric Field-Incorporated In-Situ Copper Ions Eliminating Pathogens and Antibiotic Resistance Genes in Drinking Water
title_fullStr Local Electric Field-Incorporated In-Situ Copper Ions Eliminating Pathogens and Antibiotic Resistance Genes in Drinking Water
title_full_unstemmed Local Electric Field-Incorporated In-Situ Copper Ions Eliminating Pathogens and Antibiotic Resistance Genes in Drinking Water
title_short Local Electric Field-Incorporated In-Situ Copper Ions Eliminating Pathogens and Antibiotic Resistance Genes in Drinking Water
title_sort local electric field incorporated in situ copper ions eliminating pathogens and antibiotic resistance genes in drinking water
topic electroporation
pathogens
antibiotic resistance genes
copper ions
url https://www.mdpi.com/2079-6382/13/12/1161
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