Wood-derived freestanding integrated electrode with robust interface-coupling effect boosted bifunctionality for rechargeable zinc-air batteries
Fabricating non-noble metal-based carbon air electrodes with highly efficient bifunctionality is big challenge owing to the sluggish kinetics of oxygen reduction/evolution reaction (ORR/OER). The efficient cathode catalyst is urgently needed to further improve the performance of rechargeable zinc-ai...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co., Ltd.
2024-12-01
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| Series: | Green Energy & Environment |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2468025723001620 |
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| Summary: | Fabricating non-noble metal-based carbon air electrodes with highly efficient bifunctionality is big challenge owing to the sluggish kinetics of oxygen reduction/evolution reaction (ORR/OER). The efficient cathode catalyst is urgently needed to further improve the performance of rechargeable zinc-air batteries. Herein, an activation-doping assisted interface modification strategy is demonstrated based on freestanding integrated carbon composite (CoNiLDH@NPC) composed of wood-based N and P doped active carbon (NPC) and CoNi layer double hydroxides (CoNiLDH). In the light of its large specific surface area and unique defective structure, CoNiLDH@NPC with strong interface-coupling effect in 2D-3D micro-nanostructure exhibits outstanding bifunctionality. Such carbon composites show half-wave potential of 0.85 V for ORR, overpotential of 320 mV with current density of 10 mA cm−2 for OER, and ultra-low gap of 0.70 V. Furthermore, highly-ordered open channels of wood provide enormous space to form abundant triple-phase boundary for accelerating the catalytic process. Consequently, zinc-air batteries using CoNiLDH@NPC show high power density (aqueous: 263 mW cm−2, quasi-solid-state: 65.8 mW cm−2) and long-term stability (aqueous: 500 h, quasi-solid-state: 120 h). This integrated protocol opens a new avenue for the rational design of efficient freestanding air electrode from biomass resources. |
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| ISSN: | 2468-0257 |